BRPI1010428A2 - policarbonato com propriedades tÉrmicas e mecÂnicas melhoradas, bem como coeficiente de dilataÇço tÉrmica reduzido - Google Patents
policarbonato com propriedades tÉrmicas e mecÂnicas melhoradas, bem como coeficiente de dilataÇço tÉrmica reduzido Download PDFInfo
- Publication number
- BRPI1010428A2 BRPI1010428A2 BRPI1010428-3A BRPI1010428A BRPI1010428A2 BR PI1010428 A2 BRPI1010428 A2 BR PI1010428A2 BR PI1010428 A BRPI1010428 A BR PI1010428A BR PI1010428 A2 BRPI1010428 A2 BR PI1010428A2
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- BR
- Brazil
- Prior art keywords
- formula
- polycarbonate
- diphenols
- alkyl
- polycarbonates
- Prior art date
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- 239000004417 polycarbonate Substances 0.000 title claims abstract description 70
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 68
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 238000000034 method Methods 0.000 claims abstract description 40
- 230000008569 process Effects 0.000 claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 31
- 229930185605 Bisphenol Natural products 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 19
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 17
- 239000010410 layer Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 239000000654 additive Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 12
- 238000001746 injection moulding Methods 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical group C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 9
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 238000005809 transesterification reaction Methods 0.000 claims description 7
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims description 5
- 239000011241 protective layer Substances 0.000 claims description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- TUQLLQQWSNWKCF-UHFFFAOYSA-N trimethoxymethylsilane Chemical compound COC([SiH3])(OC)OC TUQLLQQWSNWKCF-UHFFFAOYSA-N 0.000 claims description 2
- UHUUYVZLXJHWDV-UHFFFAOYSA-N trimethyl(methylsilyloxy)silane Chemical compound C[SiH2]O[Si](C)(C)C UHUUYVZLXJHWDV-UHFFFAOYSA-N 0.000 claims description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 238000004090 dissolution Methods 0.000 claims 1
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 15
- 238000000465 moulding Methods 0.000 abstract description 10
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 4
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 28
- -1 polybutylene terephthalate Polymers 0.000 description 27
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 14
- 239000004412 Bulk moulding compound Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 10
- 239000010408 film Substances 0.000 description 10
- 230000003287 optical effect Effects 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000004650 carbonic acid diesters Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 239000012963 UV stabilizer Substances 0.000 description 6
- 150000001565 benzotriazoles Chemical class 0.000 description 6
- 230000004927 fusion Effects 0.000 description 6
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 6
- 239000011814 protection agent Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 229920000965 Duroplast Polymers 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 239000012670 alkaline solution Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229920002492 poly(sulfone) Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- ZEKCYPANSOJWDH-UHFFFAOYSA-N 3,3-bis(4-hydroxy-3-methylphenyl)-1H-indol-2-one Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3NC2=O)C=2C=C(C)C(O)=CC=2)=C1 ZEKCYPANSOJWDH-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000001465 metallisation Methods 0.000 description 4
- 150000003018 phosphorus compounds Chemical class 0.000 description 4
- 229920001601 polyetherimide Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 3
- RPJFWRZEEKJTGN-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=CC(O)=CC=2)=C1 RPJFWRZEEKJTGN-UHFFFAOYSA-N 0.000 description 3
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000005915 C6-C14 aryl group Chemical group 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000004697 Polyetherimide Substances 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000009264 composting Methods 0.000 description 3
- 230000010339 dilation Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920002312 polyamide-imide Polymers 0.000 description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 description 3
- 229920006393 polyether sulfone Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000012552 review Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 150000003918 triazines Chemical class 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 2
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- YQEMORVAKMFKLG-UHFFFAOYSA-N 2-stearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 2
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 2
- SSADPHQCUURWSW-UHFFFAOYSA-N 3,9-bis(2,6-ditert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C)=CC(C(C)(C)C)=C1OP1OCC2(COP(OC=3C(=CC(C)=CC=3C(C)(C)C)C(C)(C)C)OC2)CO1 SSADPHQCUURWSW-UHFFFAOYSA-N 0.000 description 2
- PVFQHGDIOXNKIC-UHFFFAOYSA-N 4-[2-[3-[2-(4-hydroxyphenyl)propan-2-yl]phenyl]propan-2-yl]phenol Chemical compound C=1C=CC(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PVFQHGDIOXNKIC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- HTLZVHNRZJPSMI-UHFFFAOYSA-N N-ethylpiperidine Chemical compound CCN1CCCCC1 HTLZVHNRZJPSMI-UHFFFAOYSA-N 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 2
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000012455 biphasic mixture Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- 229920002842 oligophosphate Polymers 0.000 description 2
- 150000004714 phosphonium salts Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 229920001230 polyarylate Polymers 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 150000003457 sulfones Chemical class 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Polymers OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- YFVPSVILXHJMEY-UHFFFAOYSA-N (2-ethyl-4-methyl-3,5-diphenylphenyl) dihydrogen phosphate Chemical compound CCC1=C(OP(O)(O)=O)C=C(C=2C=CC=CC=2)C(C)=C1C1=CC=CC=C1 YFVPSVILXHJMEY-UHFFFAOYSA-N 0.000 description 1
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
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- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000412 polyarylene Polymers 0.000 description 1
- 229920006260 polyaryletherketone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical compound [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 1
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- ZLLNYWQSSYUXJM-UHFFFAOYSA-M tetraphenylphosphanium;phenoxide Chemical compound [O-]C1=CC=CC=C1.C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 ZLLNYWQSSYUXJM-UHFFFAOYSA-M 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- RKBCYCFRFCNLTO-UHFFFAOYSA-N triisopropylamine Chemical compound CC(C)N(C(C)C)C(C)C RKBCYCFRFCNLTO-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
- FSLSJTZWDATVTK-UHFFFAOYSA-N tris(6-methylheptyl) phosphate Chemical compound CC(C)CCCCCOP(=O)(OCCCCCC(C)C)OCCCCCC(C)C FSLSJTZWDATVTK-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/46—Iso-indoles; Hydrogenated iso-indoles with an oxygen atom in position 1
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/04—Aromatic polycarbonates
- C08G64/06—Aromatic polycarbonates not containing aliphatic unsaturation
- C08G64/08—Aromatic polycarbonates not containing aliphatic unsaturation containing atoms other than carbon, hydrogen or oxygen
- C08G64/12—Aromatic polycarbonates not containing aliphatic unsaturation containing atoms other than carbon, hydrogen or oxygen containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/123—Treatment by wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009059771A DE102009059771A1 (de) | 2009-12-21 | 2009-12-21 | Polycarbonat mit verbesserten thermischen und mechanischen Eigenschaften sowie reduziertem thermischen Ausdehnungskoeffizienten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI1010428A2 true BRPI1010428A2 (pt) | 2012-12-25 |
Family
ID=43585573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI1010428-3A BRPI1010428A2 (pt) | 2009-12-21 | 2010-12-21 | policarbonato com propriedades tÉrmicas e mecÂnicas melhoradas, bem como coeficiente de dilataÇço tÉrmica reduzido |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9676716B2 (enExample) |
| EP (1) | EP2338880B1 (enExample) |
| JP (1) | JP6000510B2 (enExample) |
| KR (1) | KR101809268B1 (enExample) |
| CN (1) | CN102101839B (enExample) |
| AU (1) | AU2010246337A1 (enExample) |
| BR (1) | BRPI1010428A2 (enExample) |
| DE (1) | DE102009059771A1 (enExample) |
| ES (1) | ES2485293T3 (enExample) |
| RU (1) | RU2010152001A (enExample) |
| SG (1) | SG172574A1 (enExample) |
| TW (1) | TWI486374B (enExample) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9290618B2 (en) | 2011-08-05 | 2016-03-22 | Sabic Global Technologies B.V. | Polycarbonate compositions having enhanced optical properties, methods of making and articles comprising the polycarbonate compositions |
| US8962117B2 (en) | 2011-10-27 | 2015-02-24 | Sabic Global Technologies B.V. | Process for producing bisphenol A with reduced sulfur content, polycarbonate made from the bisphenol A, and containers formed from the polycarbonate |
| EP2810309A1 (en) | 2012-02-03 | 2014-12-10 | SABIC Innovative Plastics IP B.V. | Light emitting diode device and method for production thereof containing conversion material chemistry |
| EP3284802A1 (en) | 2012-02-29 | 2018-02-21 | SABIC Global Technologies B.V. | Polycarbonate compositions containing conversion material chemistry and having enhanced optical properties, methods of making and articles comprising the same |
| WO2013130606A2 (en) | 2012-02-29 | 2013-09-06 | Sabic Innovative Plastics Ip B.V. | Polycarbonate made from low sulfur bisphenol a and containing converions material chemistry, and articles made therefrom |
| US9346949B2 (en) | 2013-02-12 | 2016-05-24 | Sabic Global Technologies B.V. | High reflectance polycarbonate |
| WO2013173615A1 (en) | 2012-05-16 | 2013-11-21 | Sabic Innovative Plastics Ip B.V. | Compositions and articles of manufacture containing branched polycarbonate |
| WO2014031730A1 (en) * | 2012-08-21 | 2014-02-27 | Sabic Innovative Plastics Ip B.V. | Transparent plastic article |
| CN104918992B9 (zh) | 2012-10-25 | 2017-05-24 | 沙特基础全球技术有限公司 | 发光二极管装置、制造方法、其应用 |
| JP6457948B2 (ja) * | 2012-12-20 | 2019-01-23 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ | 有機着色剤および良好な加工特性を有する着色ポリマー組成物 |
| CN104981341B (zh) | 2012-12-28 | 2021-09-14 | 旭硝子化学美国有限公司 | 用于软管组装件的层状管道 |
| US9127119B2 (en) | 2013-01-11 | 2015-09-08 | Sabic Global Technologies B.V. | Polycarbonate compositions having improved thermal dimensional stability and high refractive index |
| JP6629720B2 (ja) * | 2013-05-10 | 2020-01-15 | エージーシー ケミカルズ アメリカズ，インコーポレイテッド | 層状化されたチューブおよびその中での使用のための層 |
| US9553244B2 (en) | 2013-05-16 | 2017-01-24 | Sabic Global Technologies B.V. | Branched polycarbonate compositions having conversion material chemistry and articles thereof |
| US9772086B2 (en) | 2013-05-29 | 2017-09-26 | Sabic Innovative Plastics Ip B.V. | Illuminating devices with color stable thermoplastic light transmitting articles |
| CN105408408B (zh) | 2013-05-29 | 2018-05-04 | 沙特基础全球技术有限公司 | 颜色稳定的热塑性组合物 |
| US9567445B2 (en) * | 2013-08-28 | 2017-02-14 | Sabic Global Technologies B.V. | Polycarbonate films for capacitors, methods of manufacture, and articles manufactured therefrom |
| CN103881352A (zh) * | 2014-03-27 | 2014-06-25 | 苏州益群模具有限公司 | 汽车前灯材料的加工方法 |
| CN103881354A (zh) * | 2014-03-27 | 2014-06-25 | 苏州益群模具有限公司 | 汽车前灯罩注塑材料 |
| US10435368B2 (en) | 2014-07-22 | 2019-10-08 | Sabic Global Technologies B.V. | High heat monomers and methods of use thereof |
| CN104324395B (zh) * | 2014-10-24 | 2017-01-25 | 深圳莱特光电股份有限公司 | 一种led紫外光杀菌灯 |
| JP6804446B2 (ja) * | 2014-12-01 | 2020-12-23 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ | 改善した流動性および高剛性を有する充填ポリカーボネート組成物 |
| EP3227374B1 (de) * | 2014-12-01 | 2022-06-01 | Covestro Intellectual Property GmbH & Co. KG | Copolycarbonat-zusammensetzungen mit verbesserten rheologischen und optischen eigenschaften enthaltend diglycerolester |
| EP3227373B1 (de) | 2014-12-01 | 2020-01-01 | Covestro Deutschland AG | Verbesserung der fliessfähigkeit von polycarbonatzusammensetzungen |
| US10189941B2 (en) | 2014-12-04 | 2019-01-29 | Covestro Deutschland Ag | Polycarbonate compositions containing polyethylene wax |
| KR20170091675A (ko) * | 2014-12-04 | 2017-08-09 | 코베스트로 도이칠란트 아게 | Pe-왁스를 함유하는, 개선된 가공 거동을 갖는 코폴리카르보네이트 조성물 |
| WO2016113760A1 (en) * | 2015-01-15 | 2016-07-21 | Council Of Scientific & Industrial Research | Bisphenols containing pendant clickable maleimide group and polymers therefrom |
| GB201513760D0 (en) * | 2015-08-04 | 2015-09-16 | Teer Coatings Ltd | Improved coatings and method of applying the same |
| EP3390051A1 (en) | 2015-12-15 | 2018-10-24 | AGC Chemicals Americas Inc. | A layered tube and layer for use in same |
| EP3443020B1 (en) * | 2016-04-15 | 2020-11-11 | SABIC Global Technologies B.V. | Polyisoindolinones, methods of manufacture, and compositions and articles formed therefrom |
| CN108884223A (zh) * | 2016-04-15 | 2018-11-23 | 沙特基础工业全球技术有限公司 | 聚异吲哚啉酮组合物、制备方法及由其形成的组合物和制品 |
| EP3448934B1 (en) | 2016-04-28 | 2020-05-20 | SABIC Global Technologies B.V. | Compatibilized compositions, articles formed therefrom, and methods of manufacture |
| CN109153848B (zh) | 2016-05-27 | 2021-01-08 | 沙特基础工业全球技术有限公司 | 具有增强的光学性能的高热共聚碳酸酯组合物、由其形成的制品、和制造方法 |
| CN109196048B (zh) | 2016-05-27 | 2021-09-21 | 高新特殊工程塑料全球技术有限公司 | 具有增强的光学性质的共聚碳酸酯组合物、由其形成的制品和制造方法 |
| US10787568B2 (en) | 2016-07-25 | 2020-09-29 | Sabic Global Technologies B.V. | Polycarbonate compositions having enhanced optical properties, articles formed therefrom, and methods of manufacture |
| DE102016115921B9 (de) * | 2016-08-26 | 2024-02-15 | OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung | Optoelektronisches Bauelement und Verfahren zur Herstellung eines optoelektronischen Bauelements |
| DE102017111963A1 (de) * | 2017-05-31 | 2018-12-06 | Automotive Lighting Reutlingen Gmbh | Kunststoff-Reflektor eines Lichtmoduls und Verfahren zu dessen Herstellung |
| EP3510078B1 (en) | 2017-11-01 | 2020-06-03 | SABIC Global Technologies B.V. | Phthalimidine copolycarbonate optical articles, articles formed therefrom, and methods of manufacture |
| CN108032484A (zh) * | 2017-12-14 | 2018-05-15 | 上海小糸车灯有限公司 | 一种汽车用led反射镜及其制备方法 |
| EP3587495B1 (en) * | 2018-06-29 | 2021-03-31 | SHPP Global Technologies B.V. | Copolycarbonate compositions including 2-hydrocarbyl-3-(dihydroxyfluoresceinyl)phthalimidine unit, and articles derived therefrom |
| EP3660074B1 (en) | 2018-11-30 | 2021-05-26 | SHPP Global Technologies B.V. | Sulfur-stabilized copolycarbonates and articles formed therefrom |
| CN116490549B (zh) * | 2020-11-30 | 2025-11-04 | 科思创德国股份有限公司 | 适合用作反射器的多层结构 |
| WO2022144921A1 (en) * | 2020-12-30 | 2022-07-07 | Council Of Scientific & Industrial Research | New bisphenols bearing pendant clickable norbornenyl group and polymers therefrom |
| DE102021116975A1 (de) | 2021-07-01 | 2023-01-05 | R. Stahl Schaltgeräte GmbH | Kunststoffteil und Verfahren zu seiner Herstellung |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE1031512B (de) | 1955-12-21 | 1958-06-04 | Bayer Ag | Verfahren zur Herstellung von hochmolekularen faser- und filmbildenden Polycarbonaten |
| FR2622197B1 (fr) | 1987-10-21 | 1990-03-09 | Atochem | Polyamides transparents, leur procede de fabrication |
| NL8802346A (nl) | 1988-09-22 | 1990-04-17 | Gen Electric | Polymeermengsel met aromatisch polycarbonaat, styreen bevattend copolymeer en/of entpolymeer en een vlamvertragend middel, daaruit gevormde voorwerpen. |
| FR2685702B1 (fr) | 1991-12-31 | 1994-04-01 | Atochem | Nouvelles compositions polyamides amorphes transparentes a tenue aux agents chimiques elevee. |
| JPH0665500A (ja) | 1992-08-21 | 1994-03-08 | Mitsubishi Gas Chem Co Inc | ポリアミド樹脂組成物 |
| US5344910A (en) * | 1993-03-23 | 1994-09-06 | General Electric Company | Heat-resistant polycarbonate resins containing 2-alkyl-3,3-bis(p-hydroxyphenyl)phthalimide |
| DE4328656A1 (de) | 1993-08-26 | 1995-03-02 | Bayer Ag | Flammwidrige, spannungsrißbeständige Polycarbonat-ABS-Formmassen |
| CH688624A5 (de) | 1995-02-01 | 1997-12-15 | Inventa Ag | Amorphe Polyamid-Formmassen und -Formteile. |
| US6617381B1 (en) | 1997-03-07 | 2003-09-09 | Toray Industries, Inc. | Polyamide resin composition and forming from the same |
| EP0913421B1 (en) | 1997-10-27 | 2003-03-26 | Teijin Limited | Biaxially oriented film and magnetic recording medium comprising the same as a base film |
| JP4390882B2 (ja) * | 1997-12-10 | 2009-12-24 | 大日本印刷株式会社 | 透明バリアフィルム、それを使用した積層材および包装用容器 |
| MY119540A (en) | 1998-04-24 | 2005-06-30 | Ciba Spacialty Chemicals Holding Inc | Increasing the molecular weight of polyesters |
| US6355723B1 (en) | 2000-06-22 | 2002-03-12 | General Electric Co. | Dark colored thermoplastic compositions, articles molded therefrom, and article preparation methods |
| EP1312647B1 (en) | 2001-11-16 | 2008-01-09 | Mitsubishi Engineering-Plastics Corporation | Polyamide moulding compositions and thick-wall molded products therefrom |
| US7329720B2 (en) * | 2005-11-29 | 2008-02-12 | General Electric Company | Methods for increasing the mean particle size of 2-hydrocarbyl-3,3-bis(hydroxyaryl)phthalimidines |
| US7358321B2 (en) | 2005-11-29 | 2008-04-15 | General Electric Company | High glass transition temperature copolycarbonates, methods of manufacture, and uses thereof |
| US7491788B1 (en) * | 2006-05-19 | 2009-02-17 | Sabic Innovative Plastics Ip B.V. | High heat polycarbonate compositions, methods for the preparation thereof, and articles derived therefrom |
| DE102006046330A1 (de) * | 2006-09-28 | 2008-04-03 | Bayer Materialscience Ag | Polycarbonate und Copolycarbonate mit verbesserter Metallhaftung |
| US7514524B2 (en) * | 2007-03-30 | 2009-04-07 | Sabic Innovative Plastics Ip B.V. | Methods for producing and purifying 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine monomers and polycarbonates derived therefrom |
| US20080274360A1 (en) * | 2007-05-04 | 2008-11-06 | General Electric Company | Polyaryl ether ketone - polycarbonate copolymer blends |
-
2009
- 2009-12-21 DE DE102009059771A patent/DE102009059771A1/de not_active Withdrawn
-
2010
- 2010-11-19 AU AU2010246337A patent/AU2010246337A1/en not_active Abandoned
- 2010-11-30 TW TW099141325A patent/TWI486374B/zh not_active IP Right Cessation
- 2010-12-17 EP EP20100195558 patent/EP2338880B1/de not_active Not-in-force
- 2010-12-17 ES ES10195558.1T patent/ES2485293T3/es active Active
- 2010-12-17 SG SG2010093763A patent/SG172574A1/en unknown
- 2010-12-20 KR KR1020100130573A patent/KR101809268B1/ko not_active Expired - Fee Related
- 2010-12-20 RU RU2010152001/04A patent/RU2010152001A/ru not_active Application Discontinuation
- 2010-12-20 US US12/973,060 patent/US9676716B2/en not_active Expired - Fee Related
- 2010-12-21 JP JP2010284647A patent/JP6000510B2/ja not_active Expired - Fee Related
- 2010-12-21 CN CN201010598015.4A patent/CN102101839B/zh not_active Expired - Fee Related
- 2010-12-21 BR BRPI1010428-3A patent/BRPI1010428A2/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| KR101809268B1 (ko) | 2017-12-14 |
| EP2338880A3 (de) | 2011-10-05 |
| CN102101839A (zh) | 2011-06-22 |
| SG172574A1 (en) | 2011-07-28 |
| TWI486374B (zh) | 2015-06-01 |
| EP2338880B1 (de) | 2014-06-04 |
| JP6000510B2 (ja) | 2016-09-28 |
| EP2338880A2 (de) | 2011-06-29 |
| US9676716B2 (en) | 2017-06-13 |
| KR20110073301A (ko) | 2011-06-29 |
| JP2011137156A (ja) | 2011-07-14 |
| AU2010246337A1 (en) | 2011-07-07 |
| US20110151262A1 (en) | 2011-06-23 |
| TW201139513A (en) | 2011-11-16 |
| DE102009059771A1 (de) | 2011-06-22 |
| RU2010152001A (ru) | 2012-06-27 |
| ES2485293T3 (es) | 2014-08-13 |
| CN102101839B (zh) | 2014-12-24 |
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