BRPI0709415A2 - processo de formação de fibras - Google Patents
processo de formação de fibras Download PDFInfo
- Publication number
- BRPI0709415A2 BRPI0709415A2 BRPI0709415-9A BRPI0709415A BRPI0709415A2 BR PI0709415 A2 BRPI0709415 A2 BR PI0709415A2 BR PI0709415 A BRPI0709415 A BR PI0709415A BR PI0709415 A2 BRPI0709415 A2 BR PI0709415A2
- Authority
- BR
- Brazil
- Prior art keywords
- process according
- spinning solution
- nozzle
- polymers
- collector
- Prior art date
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 78
- 238000000034 method Methods 0.000 title claims abstract description 48
- 230000015572 biosynthetic process Effects 0.000 title description 2
- 238000009987 spinning Methods 0.000 claims abstract description 46
- 229920000642 polymer Polymers 0.000 claims description 28
- 230000005684 electric field Effects 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 17
- 239000012530 fluid Substances 0.000 claims description 11
- 239000007921 spray Substances 0.000 claims description 9
- 239000004952 Polyamide Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 229920001634 Copolyester Polymers 0.000 claims description 3
- 229920000106 Liquid crystal polymer Polymers 0.000 claims description 3
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 229920013724 bio-based polymer Polymers 0.000 claims description 3
- 229920002988 biodegradable polymer Polymers 0.000 claims description 3
- 239000004621 biodegradable polymer Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229920002313 fluoropolymer Polymers 0.000 claims description 3
- 239000004811 fluoropolymer Substances 0.000 claims description 3
- 229920005615 natural polymer Polymers 0.000 claims description 3
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 3
- 229920001281 polyalkylene Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 229920006163 vinyl copolymer Polymers 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims 1
- 230000004888 barrier function Effects 0.000 abstract description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000002121 nanofiber Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000007380 fibre production Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- GOZDTZWAMGHLDY-UHFFFAOYSA-L sodium picosulfate Chemical compound [Na+].[Na+].C1=CC(OS(=O)(=O)[O-])=CC=C1C(C=1N=CC=CC=1)C1=CC=C(OS([O-])(=O)=O)C=C1 GOZDTZWAMGHLDY-UHFFFAOYSA-L 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/18—Formation of filaments, threads, or the like by means of rotating spinnerets
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/11—Flash-spinning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/05—Filamentary, e.g. strands
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78663206P | 2006-03-28 | 2006-03-28 | |
| US60/786,632 | 2006-03-28 | ||
| PCT/US2007/007131 WO2007126674A1 (en) | 2006-03-28 | 2007-03-22 | Solution spun fiber process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0709415A2 true BRPI0709415A2 (pt) | 2011-07-12 |
Family
ID=38430422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0709415-9A BRPI0709415A2 (pt) | 2006-03-28 | 2007-03-22 | processo de formação de fibras |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US8303874B2 (https=) |
| EP (1) | EP1999304B2 (https=) |
| JP (1) | JP5096455B2 (https=) |
| KR (1) | KR101417142B1 (https=) |
| CN (1) | CN101405441B (https=) |
| BR (1) | BRPI0709415A2 (https=) |
| DE (1) | DE602007011580D1 (https=) |
| WO (1) | WO2007126674A1 (https=) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8303874B2 (en) | 2006-03-28 | 2012-11-06 | E I Du Pont De Nemours And Company | Solution spun fiber process |
| US20080199698A1 (en) * | 2007-02-16 | 2008-08-21 | Sumitomo Chemical Company, Limited | Method for producing liquid crystalline polyester fiber |
| US8277711B2 (en) | 2007-03-29 | 2012-10-02 | E I Du Pont De Nemours And Company | Production of nanofibers by melt spinning |
| US20090326128A1 (en) * | 2007-05-08 | 2009-12-31 | Javier Macossay-Torres | Fibers and methods relating thereto |
| KR20100088141A (ko) * | 2007-10-23 | 2010-08-06 | 피피지 인더스트리즈 오하이오 인코포레이티드 | 전기-기계적 방사에 의한 섬유의 제조 |
| US9834865B2 (en) * | 2007-12-17 | 2017-12-05 | E I Du Pont De Nemours And Company | Centrifugal solution spun nanofiber process |
| WO2010008621A1 (en) * | 2008-03-17 | 2010-01-21 | The Board Of Regents Of The University Of Texas System | Superfine fiber creating spinneret and uses thereof |
| CN102282301B (zh) | 2009-01-16 | 2014-07-30 | Zeus工业品公司 | 利用高粘度材料对ptfe进行电纺丝 |
| US20130268062A1 (en) | 2012-04-05 | 2013-10-10 | Zeus Industrial Products, Inc. | Composite prosthetic devices |
| US8685424B2 (en) | 2010-10-14 | 2014-04-01 | Zeus Industrial Products, Inc. | Antimicrobial substrate |
| JP2010180499A (ja) * | 2009-02-04 | 2010-08-19 | Panasonic Corp | ナノファイバ製造装置、ナノファイバ製造方法 |
| JP5305960B2 (ja) * | 2009-02-13 | 2013-10-02 | 日本バイリーン株式会社 | 極細繊維不織布の製造方法、及びその製造装置 |
| JP5305961B2 (ja) * | 2009-02-13 | 2013-10-02 | 日本バイリーン株式会社 | 極細繊維不織布 |
| JP5226558B2 (ja) * | 2009-02-16 | 2013-07-03 | パナソニック株式会社 | ナノファイバ製造装置、ナノファイバ製造方法 |
| JP2013501539A (ja) | 2009-08-07 | 2013-01-17 | ゼウス インダストリアル プロダクツ インコーポレイテッド | 静電紡糸繊維層を備える補綴具及びその製造方法 |
| KR20110059541A (ko) * | 2009-11-27 | 2011-06-02 | 니혼바이린 가부시기가이샤 | 방사 장치, 부직포 제조 장치, 부직포의 제조 방법 및 부직포 |
| US9243347B2 (en) * | 2010-02-15 | 2016-01-26 | Cornell University | Process of making nanofibers |
| US10653511B2 (en) | 2011-01-28 | 2020-05-19 | Merit Medical Systems, Inc. | Electrospun PTFE coated stent and method of use |
| US8647541B2 (en) | 2011-02-07 | 2014-02-11 | Fiberio Technology Corporation | Apparatuses and methods for the simultaneous production of microfibers and nanofibers |
| CA2829612C (en) * | 2011-03-09 | 2020-08-11 | Board Of Regents Of The University Of Texas System | Apparatuses and methods for the production of fibers |
| JP6300732B2 (ja) | 2012-01-16 | 2018-03-28 | メリット・メディカル・システムズ・インコーポレイテッドMerit Medical Systems,Inc. | 回転スパン材料で被覆した医療器具及びその製造方法 |
| US20150176141A1 (en) * | 2012-06-27 | 2015-06-25 | Koninklijke Philips. N.V. | Apparatus and method of preparing a solution containing cations and anions |
| EP2900852B1 (en) * | 2012-08-06 | 2020-10-07 | Parker-Hannificn Corporation | Devices and methods for the production of microfibers and nanofibers |
| US11541154B2 (en) | 2012-09-19 | 2023-01-03 | Merit Medical Systems, Inc. | Electrospun material covered medical appliances and methods of manufacture |
| US9198999B2 (en) | 2012-09-21 | 2015-12-01 | Merit Medical Systems, Inc. | Drug-eluting rotational spun coatings and methods of use |
| JP5719421B2 (ja) * | 2012-10-11 | 2015-05-20 | 花王株式会社 | 電界紡糸装置及びそれを備えたナノファイバ製造装置 |
| WO2014159710A1 (en) | 2013-03-13 | 2014-10-02 | Merit Medical Systems, Inc. | Serially deposited fiber materials and associated devices and methods |
| US9827703B2 (en) | 2013-03-13 | 2017-11-28 | Merit Medical Systems, Inc. | Methods, systems, and apparatuses for manufacturing rotational spun appliances |
| EP2969151A1 (en) | 2013-03-14 | 2016-01-20 | E. I. du Pont de Nemours and Company | Process for using a cross-flow filter membrane to remove particles from a liquid stream |
| WO2014169239A1 (en) * | 2013-04-12 | 2014-10-16 | Donaldson Company, Inc. | Centrifugal electrospinning process |
| KR101494160B1 (ko) * | 2013-04-29 | 2015-02-17 | 한국생산기술연구원 | 은 나노 섬유 제조용 전기방사 용액 조성물 |
| HK1223067A1 (zh) * | 2013-07-05 | 2017-07-21 | 北面服饰公司 | 纤维和长丝的力纺丝 |
| JP5948370B2 (ja) | 2013-08-08 | 2016-07-06 | 花王株式会社 | ナノファイバ製造装置、ナノファイバの製造方法及びナノファイバ成型体 |
| CN105658851A (zh) * | 2013-10-22 | 2016-06-08 | 纳幕尔杜邦公司 | 用于聚合物纳米纤维生产的设备 |
| CN103628149B (zh) * | 2013-11-25 | 2015-10-14 | 北京化工大学 | 一种高压气流辅助喷头自旋转静电纺丝装置 |
| DE102014013354A1 (de) | 2014-09-08 | 2016-03-10 | Rainer Busch | Die Erfindung betrifft eine Vorrichtung und Verfahren zur Herstellung von mikroverkapselten Paraffinpartikel durch ein elektrostatisches Rotationsdüsen-Absprühverfahren sowie die Verwendung dieses Verfahren. Die so verkapselten Paraffinpartikel können für |
| DK3261589T3 (da) | 2015-02-26 | 2020-12-14 | Merit Medical Systems Inc | Lagdelte medicinske indretninger |
| CN121272601A (zh) | 2016-02-12 | 2026-01-06 | 金珂生物医疗公司 | 壳聚糖超细纤维系统 |
| CN106626767B (zh) * | 2016-12-09 | 2018-02-27 | 华中科技大学 | 一种集成有接地电极的气流辅助电喷印喷头 |
| KR102486322B1 (ko) | 2017-03-09 | 2023-01-06 | 어드밴식스 레진즈 앤드 케미컬즈 엘엘씨 | 폴리아미드의 겔 방적을 위한 조성물 및 방법 |
| US11376534B2 (en) | 2017-06-08 | 2022-07-05 | Ascend Performance Materials Operations Llc | Polyamide nanofiber nonwovens for filters |
| KR102502382B1 (ko) | 2017-06-08 | 2023-02-21 | 어센드 퍼포먼스 머티리얼즈 오퍼레이션즈 엘엘씨 | 폴리아미드 나노섬유 부직포 |
| WO2019049085A1 (en) | 2017-09-08 | 2019-03-14 | Board Of Regents Of The University Of Texas System | MECHANOLUMINESCENT POLYMER DOPED FABRICS AND METHODS |
| CN108866661B (zh) * | 2017-11-16 | 2020-06-05 | 武汉纺织大学 | 一种转动式喷制纳米纤维的装置 |
| US11427937B2 (en) | 2019-02-20 | 2022-08-30 | The Board Of Regents Of The University Of Texas System | Handheld/portable apparatus for the production of microfibers, submicron fibers and nanofibers |
| EP4297813A4 (en) | 2021-02-26 | 2025-01-15 | Merit Medical Systems, Inc. | FIBER CONSTRUCTS WITH PARTICLES OF THERAPEUTIC MATERIAL |
| CA3210262A1 (en) | 2021-03-02 | 2022-09-09 | Karen Lozano | Handheld/portable apparatus for the production of fine fibers |
| US12550916B2 (en) | 2022-06-28 | 2026-02-17 | Board Of Regents, The University Of Texas System | Nanofiber systems as meat substitute |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3085749A (en) | 1957-07-23 | 1963-04-16 | Schweitzer Electrostatic Compa | Electrostatic spray heads |
| US3097085A (en) | 1959-07-02 | 1963-07-09 | Wallsten Hans | Method and means for the manufacture of fibres of thermoplastic material |
| US3565979A (en) | 1968-09-18 | 1971-02-23 | Du Pont | Flash spinning |
| US4211736A (en) | 1972-10-27 | 1980-07-08 | Albert L. Jeffers | Process for forming and twisting fibers |
| JPS49110924A (https=) * | 1973-03-07 | 1974-10-22 | ||
| SE397772B (sv) | 1975-07-29 | 1977-11-21 | Niro Atomizer As | Sett och anordning for uppdelning av en flytande suspension av fasta partiklar i fraktioner med olika genomsnittliga egenskaper |
| DE3001209C2 (de) | 1980-01-15 | 1985-07-25 | Behr, Hans, 7000 Stuttgart | Vorrichtung zum Vernebeln flüssiger Farbe, insbesondere Lackzerstäuber |
| GB2096586A (en) | 1981-04-03 | 1982-10-20 | Ici Ltd | Inorganic fibres |
| GB2102985A (en) † | 1981-07-31 | 1983-02-09 | Philips Electronic Associated | Drum speed control system for a washing machine |
| US4919333A (en) | 1986-06-26 | 1990-04-24 | The Devilbiss Company | Rotary paint atomizing device |
| JPS6372367A (ja) | 1986-09-16 | 1988-04-02 | Toyota Central Res & Dev Lab Inc | 回転霧化式塗装装置 |
| US4861653A (en) | 1987-09-02 | 1989-08-29 | E. I. Du Pont De Nemours And Company | Pitch carbon fibers and batts |
| DE3801080A1 (de) | 1988-01-16 | 1989-07-27 | Bayer Ag | Verfahren zur herstellung von feinstpolymerfasern |
| DE4011883A1 (de) | 1990-04-12 | 1991-10-17 | Bayer Ag | Verfahren zur herstellung von feinstfaservliesen aus thermoplastischen polymeren |
| ES2090334T3 (es) | 1991-05-10 | 1996-10-16 | Du Pont | Aparato para formar una lamina fibrosa no tejida. |
| CA2109622A1 (en) | 1991-05-17 | 1992-11-26 | Richard C. Fuisz | New thermoplastic polymeric material and process for making same |
| DE4315609A1 (de) * | 1993-05-11 | 1994-11-17 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von Fasern nach einem Zentrifugalspinnverfahren |
| CN2249660Y (zh) * | 1995-09-08 | 1997-03-19 | 汕头市金园区金明五金机械厂 | 一种用于生产塑料无结网的热旋转模头 |
| US5934574A (en) | 1995-12-05 | 1999-08-10 | Van Der Steur; Gunnar | Rotary atomizer |
| JPH09192545A (ja) | 1996-01-23 | 1997-07-29 | Nissan Motor Co Ltd | 回転霧化静電塗装装置 |
| US5693280A (en) * | 1996-07-31 | 1997-12-02 | Owens-Corning Fiberglas Technology, Inc. | Method of producing organic fibers from a rotary process |
| DE19800297C1 (de) | 1998-01-07 | 1999-07-01 | Microfaser Repro Gmbh | Verfahren und Vorrichtung zur Herstellung von Faserstoffen aus thermoplastischen Kunststoffen |
| US6189804B1 (en) * | 1998-03-27 | 2001-02-20 | Behr Systems, Inc. | Rotary atomizer for particulate paints |
| DE19836260A1 (de) * | 1998-08-11 | 2000-02-24 | Wacker Chemie Gmbh | Lineare Polyether-Polysiloxan-Copolymere, deren Herstellung und Verwendung |
| JP3562361B2 (ja) * | 1999-01-18 | 2004-09-08 | 日産自動車株式会社 | 回転霧化塗装装置 |
| US6641773B2 (en) | 2001-01-10 | 2003-11-04 | The United States Of America As Represented By The Secretary Of The Army | Electro spinning of submicron diameter polymer filaments |
| DE10112089B4 (de) | 2001-03-12 | 2004-03-04 | Microfaser Produktionsgesellschaft Mbh | Vorrichtung zur Herstellung von synthetischen Faserstoffen |
| GB0127327D0 (en) * | 2001-11-14 | 2002-01-02 | Univ Leeds | Centrifugal spinning process |
| KR100549140B1 (ko) * | 2002-03-26 | 2006-02-03 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 일렉트로-브로운 방사법에 의한 초극세 나노섬유 웹제조방법 |
| JP2004290877A (ja) | 2003-03-27 | 2004-10-21 | Toyota Motor Corp | 回転霧化塗装装置 |
| DE602004028487D1 (de) * | 2003-04-03 | 2010-09-16 | Du Pont | Drehverfahren zur herstellung eines einheitlichen materials |
| JP2007516360A (ja) | 2003-12-18 | 2007-06-21 | ザ プロクター アンド ギャンブル カンパニー | ヒドロキシルポリマー含有繊維を形成するための回転紡績加工 |
| US7134857B2 (en) | 2004-04-08 | 2006-11-14 | Research Triangle Institute | Electrospinning of fibers using a rotatable spray head |
| TWI245085B (en) | 2004-07-29 | 2005-12-11 | Taiwan Textile Res Inst | Apparatus and method for manufacturing polymeric fibrils |
| US20070038290A1 (en) * | 2005-08-15 | 2007-02-15 | Bin Huang | Fiber reinforced composite stents |
| PL1998798T3 (pl) | 2006-03-28 | 2013-08-30 | Lnk Chemsolutions Llc | Sposób wytwarzania włóknistych bandaży hemostatycznych |
| US8303874B2 (en) | 2006-03-28 | 2012-11-06 | E I Du Pont De Nemours And Company | Solution spun fiber process |
-
2006
- 2006-11-07 US US11/593,959 patent/US8303874B2/en active Active
-
2007
- 2007-03-22 DE DE602007011580T patent/DE602007011580D1/de active Active
- 2007-03-22 BR BRPI0709415-9A patent/BRPI0709415A2/pt not_active IP Right Cessation
- 2007-03-22 JP JP2009502870A patent/JP5096455B2/ja active Active
- 2007-03-22 CN CN2007800097128A patent/CN101405441B/zh active Active
- 2007-03-22 KR KR1020087026204A patent/KR101417142B1/ko active Active
- 2007-03-22 WO PCT/US2007/007131 patent/WO2007126674A1/en not_active Ceased
- 2007-03-22 EP EP07753736.3A patent/EP1999304B2/en active Active
-
2009
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Also Published As
| Publication number | Publication date |
|---|---|
| JP5096455B2 (ja) | 2012-12-12 |
| EP1999304B2 (en) | 2017-05-24 |
| US20080029617A1 (en) | 2008-02-07 |
| EP1999304B1 (en) | 2010-12-29 |
| US8747723B2 (en) | 2014-06-10 |
| KR20080111103A (ko) | 2008-12-22 |
| DE602007011580D1 (de) | 2011-02-10 |
| WO2007126674A1 (en) | 2007-11-08 |
| JP2009531561A (ja) | 2009-09-03 |
| US8303874B2 (en) | 2012-11-06 |
| KR101417142B1 (ko) | 2014-07-08 |
| CN101405441A (zh) | 2009-04-08 |
| EP1999304A1 (en) | 2008-12-10 |
| CN101405441B (zh) | 2011-05-18 |
| US20100032872A1 (en) | 2010-02-11 |
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