BRPI0619716B1 - Composição elastomérica de poliolefina com base em propileno e mistura - Google Patents
Composição elastomérica de poliolefina com base em propileno e mistura Download PDFInfo
- Publication number
- BRPI0619716B1 BRPI0619716B1 BRPI0619716-7A BRPI0619716A BRPI0619716B1 BR PI0619716 B1 BRPI0619716 B1 BR PI0619716B1 BR PI0619716 A BRPI0619716 A BR PI0619716A BR PI0619716 B1 BRPI0619716 B1 BR PI0619716B1
- Authority
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- Brazil
- Prior art keywords
- propylene
- ethylene
- weight
- based elastomer
- alpha
- Prior art date
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- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
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- 239000004033 plastic Substances 0.000 description 1
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- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- 238000010926 purge Methods 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
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- 238000011084 recovery Methods 0.000 description 1
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- 238000005070 sampling Methods 0.000 description 1
- 238000000974 shear rheometry Methods 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
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- 230000003595 spectral effect Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
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- 239000008117 stearic acid Substances 0.000 description 1
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- 230000003797 telogen phase Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
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- 229950011008 tetrachloroethylene Drugs 0.000 description 1
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/08—Polymer mixtures characterised by way of preparation prepared by late transition metal, i.e. Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru or Os, single site catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
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| US73188505P | 2005-10-31 | 2005-10-31 | |
| US60/731,885 | 2005-10-31 | ||
| PCT/US2006/042447 WO2007053603A1 (en) | 2005-10-31 | 2006-10-31 | Propylene-based elastomeric composition |
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| BRPI0619716A2 BRPI0619716A2 (pt) | 2011-10-11 |
| BRPI0619716B1 true BRPI0619716B1 (pt) | 2019-07-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| BRPI0619716-7A BRPI0619716B1 (pt) | 2005-10-31 | 2006-10-31 | Composição elastomérica de poliolefina com base em propileno e mistura |
Country Status (10)
| Country | Link |
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| US (2) | US7893161B2 (enExample) |
| EP (1) | EP1943308B1 (enExample) |
| JP (1) | JP5106407B2 (enExample) |
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| RU (1) | RU2008121721A (enExample) |
| WO (1) | WO2007053603A1 (enExample) |
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| KR101353124B1 (ko) * | 2005-10-31 | 2014-01-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 프로필렌계 엘라스토머 조성물 |
| US20080003332A1 (en) * | 2006-05-12 | 2008-01-03 | Dimitrios Ginossatis | Multilayer heat shrinkable cook-in film |
| EP1985443B1 (en) | 2007-04-26 | 2011-11-02 | Flexopack S.A. Plastics Industry | Stack sealable heat shrinkable film |
| JP2009073960A (ja) * | 2007-09-21 | 2009-04-09 | Sumitomo Chemical Co Ltd | 光学用フィルム |
| WO2009067337A1 (en) * | 2007-11-19 | 2009-05-28 | Dow Global Technologies Inc. | Long chain branched propylene-alpha-olefin copolymers |
| ATE552304T1 (de) | 2008-01-02 | 2012-04-15 | Flexopack Sa | Pvdc-formulierung und wärmeschrumpfbare folie |
| AU2008264215A1 (en) * | 2008-01-03 | 2009-07-23 | Flexopack S.A. | Thermoforming film |
| DE202009014170U1 (de) * | 2008-01-29 | 2010-02-25 | Flexopack S.A. | Dünner Film für Abfallverpackungskassetten |
| CN101981111A (zh) * | 2008-03-31 | 2011-02-23 | 三井化学株式会社 | 树脂组合物和熔融袋 |
| EP2111979B1 (en) * | 2008-04-21 | 2012-01-18 | Flexopack S.A. Plastics Industry | Stack sealable heat shrinkable film |
| PL2147783T3 (pl) * | 2008-07-23 | 2018-10-31 | Flexopack S.A. | Folia termokurczliwa do zgrzewania w stosie |
| GB2475961B (en) * | 2009-12-02 | 2015-07-08 | Flexopack Sa | Thin film for waste packing cassettes |
| US8900719B2 (en) | 2010-04-14 | 2014-12-02 | Avery Dennison Corporation | Blends of ethylene copolymers and propylene based plastomers in multilayer films for low noise and RF welding |
| EP2520518B1 (en) | 2011-05-03 | 2020-09-23 | Flexopack S.A. | Waste packaging device |
| DE202011110797U1 (de) | 2011-06-16 | 2016-08-10 | Flexopack S.A. | Abfallverpackungssystem und Folie |
| US8426521B2 (en) | 2011-07-20 | 2013-04-23 | The Procter & Gamble Company | Polymer composition |
| EP2918408A1 (en) | 2011-12-22 | 2015-09-16 | Avery Dennison Corporation | Flexible Barrier Films Containing Cyclic Olefins |
| US9604430B2 (en) | 2012-02-08 | 2017-03-28 | Flexopack S.A. | Thin film for waste packing cassettes |
| CN103361767B (zh) * | 2012-03-29 | 2016-09-28 | 彭宏 | 一种低成本的聚烯烃弹性纤维及其制造方法 |
| MX348309B (es) | 2012-09-25 | 2017-06-06 | Dow Global Technologies Llc | Composiciones de polímero modificado a base de etileno y métodos para su producción. |
| AU2014203227B2 (en) | 2013-06-14 | 2018-01-04 | Flexopack S.A. | Heat shrinkable film |
| CN106414591A (zh) | 2014-06-05 | 2017-02-15 | 宝洁公司 | 包含聚烯烃弹性体的弹性体组合物 |
| US10245347B2 (en) | 2014-06-05 | 2019-04-02 | The Procter & Gamble Company | Elastomer composition comprising polyolefin elastomers |
| US9834667B2 (en) | 2014-06-05 | 2017-12-05 | The Procter & Gamble Company | Elastomer composition comprising polyolefin elastomers |
| US10118372B2 (en) | 2014-06-05 | 2018-11-06 | The Procter & Gamble Company | Laminate comprising polyolefin elastic film layer |
| AU2015258191B2 (en) | 2014-11-19 | 2020-02-27 | Flexopack S.A. | Oven skin packaging process |
| WO2017076412A1 (en) | 2015-11-03 | 2017-05-11 | National Oilwell Varco Denmark I/S | An unbonded flexible pipe |
| KR102009615B1 (ko) * | 2016-04-22 | 2019-08-09 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 3d프린터용 프로필렌계의 필라멘트 |
| KR102086056B1 (ko) * | 2016-09-23 | 2020-03-06 | 주식회사 엘지화학 | 폴리프로필렌계 수지 조성물 |
| EP3501822A1 (en) | 2017-12-22 | 2019-06-26 | Flexopack S.A. | Fibc liner film |
| WO2020060746A1 (en) * | 2018-09-17 | 2020-03-26 | Exxonmobil Chemical Patents Inc. | Nonwoven compositions containing propylene-based elastomers and propylene polymers |
| CN112980096A (zh) * | 2019-12-02 | 2021-06-18 | 中国石油天然气股份有限公司 | 可溶性膜组合物、可溶性膜及其制备方法和应用 |
| JP7239791B1 (ja) * | 2021-08-25 | 2023-03-14 | デンカ株式会社 | 半導体封止プロセス用熱可塑性離型フィルム、及びこれを用いた電子部品の製造方法 |
| JP2025503452A (ja) * | 2021-12-17 | 2025-02-04 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 幅広のcd及びmwdを有するプロピレン系コポリマーの製造プロセス |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU601381B2 (en) * | 1985-11-29 | 1990-09-13 | American National Can Company | Blends of polypropylene and sheet structures made from the blends |
| US5008204A (en) * | 1988-02-02 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for determining the compositional distribution of a crystalline copolymer |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| US5143978A (en) * | 1990-08-28 | 1992-09-01 | Himont Incorporated | Dynamically partially crosslinked thermoplastic elastomer containing polybutene-1 |
| US5324630A (en) | 1991-06-28 | 1994-06-28 | The Regents Of The University Of California | Methods and compositions for diagnosing lyme disease |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| EP1209165B1 (en) * | 1993-06-07 | 2006-04-19 | Mitsui Chemicals, Inc. | Propylene elastomer |
| US5616664A (en) * | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
| CA2164461C (en) | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
| JP3506538B2 (ja) * | 1995-05-19 | 2004-03-15 | 日本ポリオレフィン株式会社 | ポリプロピレン系樹脂シート |
| ID16442A (id) * | 1996-01-22 | 1997-10-02 | Dow Chemical Co | Polimer etilena berat molekul ultra rendah |
| GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
| US6319998B1 (en) * | 1998-03-04 | 2001-11-20 | Exxon Mobil Chemical Patents Inc. | Method for making polymer blends by using series reactors |
| EP1091984A1 (en) | 1998-07-02 | 2001-04-18 | Exxon Chemical Patents Inc. | Propylene olefin copolymers |
| JP2000129004A (ja) * | 1998-10-21 | 2000-05-09 | Mitsubishi Chem Mkv Co | 軟質ポリプロピレン系樹脂フィルム |
| US6395321B1 (en) * | 1999-06-01 | 2002-05-28 | Schreiber Foods, Inc | Process for sealing food products such as processed cheese slices |
| GB0008690D0 (en) * | 2000-04-07 | 2000-05-31 | Borealis Polymers Oy | Process |
| US7030196B2 (en) * | 2000-05-19 | 2006-04-18 | Ciba Specialty Chemicals Corporation | Process for reducing the molecular weight of polypropylene |
| JP2003096251A (ja) * | 2001-09-20 | 2003-04-03 | Grand Polymer Co Ltd | プロピレン系重合体組成物、フィルムおよびその用途 |
| EP1444276A1 (en) | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| AU2002356914A1 (en) * | 2001-11-06 | 2003-05-19 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
| DE60335459D1 (de) * | 2002-04-24 | 2011-02-03 | Symyx Solutions Inc | Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere |
| DE60315683T2 (de) * | 2002-09-17 | 2008-06-05 | Basell Poliolefine Italia S.R.L. | Weiche polyolefinzusammensetzungen mit hohem füllstoffanteil |
| US6953764B2 (en) * | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
| WO2006044149A1 (en) | 2004-10-13 | 2006-04-27 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
| KR101353124B1 (ko) * | 2005-10-31 | 2014-01-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 프로필렌계 엘라스토머 조성물 |
| US7927695B2 (en) * | 2006-05-31 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Composite roofing and methods of producing composite roofing |
-
2006
- 2006-10-31 KR KR1020087010258A patent/KR101353124B1/ko active Active
- 2006-10-31 AT AT06827155T patent/ATE471964T1/de not_active IP Right Cessation
- 2006-10-31 DE DE602006015081T patent/DE602006015081D1/de active Active
- 2006-10-31 BR BRPI0619716-7A patent/BRPI0619716B1/pt active IP Right Grant
- 2006-10-31 JP JP2008538103A patent/JP5106407B2/ja active Active
- 2006-10-31 RU RU2008121721/04A patent/RU2008121721A/ru not_active Application Discontinuation
- 2006-10-31 CN CN2006800401848A patent/CN101296987B/zh active Active
- 2006-10-31 WO PCT/US2006/042447 patent/WO2007053603A1/en not_active Ceased
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- 2006-10-31 EP EP06827155A patent/EP1943308B1/en active Active
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2011
- 2011-01-20 US US13/010,558 patent/US8022144B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20110118418A1 (en) | 2011-05-19 |
| KR20080070637A (ko) | 2008-07-30 |
| DE602006015081D1 (de) | 2010-08-05 |
| BRPI0619716A2 (pt) | 2011-10-11 |
| EP1943308A1 (en) | 2008-07-16 |
| CN101296987B (zh) | 2010-12-15 |
| ATE471964T1 (de) | 2010-07-15 |
| JP2009513803A (ja) | 2009-04-02 |
| RU2008121721A (ru) | 2009-12-10 |
| JP5106407B2 (ja) | 2012-12-26 |
| EP1943308B1 (en) | 2010-06-23 |
| CN101296987A (zh) | 2008-10-29 |
| WO2007053603A1 (en) | 2007-05-10 |
| KR101353124B1 (ko) | 2014-01-17 |
| US20080255311A1 (en) | 2008-10-16 |
| US8022144B2 (en) | 2011-09-20 |
| US7893161B2 (en) | 2011-02-22 |
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