BRPI0515213A - método de oxidação de um cicloalcano e método para a decomposição de um hidroperóxido de cicloalquila - Google Patents

método de oxidação de um cicloalcano e método para a decomposição de um hidroperóxido de cicloalquila

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Publication number
BRPI0515213A
BRPI0515213A BRPI0515213-5A BRPI0515213A BRPI0515213A BR PI0515213 A BRPI0515213 A BR PI0515213A BR PI0515213 A BRPI0515213 A BR PI0515213A BR PI0515213 A BRPI0515213 A BR PI0515213A
Authority
BR
Brazil
Prior art keywords
cycloalkane
decomposition
oxidation
cycloalkyl
cycloalkyl hydroperoxide
Prior art date
Application number
BRPI0515213-5A
Other languages
English (en)
Inventor
Lansa Pirutko
Alexander S Kharitonov
Mikhail L Khramov
Anthony K Uriarte
Original Assignee
Solutia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solutia Inc filed Critical Solutia Inc
Publication of BRPI0515213A publication Critical patent/BRPI0515213A/pt

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/86—Borosilicates; Aluminoborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C07C35/14—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings with more than one hydroxy group bound to the ring
    • C07C35/16—Inositols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

MéTODO DE OXIDAçãO DE UM CICLOALCANO E MéTODO PARA A DECOMPOSIçãO DE UM HIDROPERóXIDO DE CICLOALQUILA Uma mistura cíclica de cetona/álcool é preparada através da oxidação catalítica do cicloalcano correspondente ou da decomposição catalítica do hidraperóxido de cicloalquila correspondente. O ouro suportado em um silicato cristalino poroso que contém menos do que cerca de 2% em peso de alumínio ou um fosfato cristalino é usado como um catalisador, O material de suporte contém opcionalmente um ou mais heteroátomos.
BRPI0515213-5A 2004-08-17 2005-08-09 método de oxidação de um cicloalcano e método para a decomposição de um hidroperóxido de cicloalquila BRPI0515213A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/920,021 US7081552B2 (en) 2004-08-17 2004-08-17 Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
PCT/US2005/028302 WO2006023333A1 (en) 2004-08-17 2005-08-09 Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide

Publications (1)

Publication Number Publication Date
BRPI0515213A true BRPI0515213A (pt) 2008-07-08

Family

ID=35910539

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0515213-5A BRPI0515213A (pt) 2004-08-17 2005-08-09 método de oxidação de um cicloalcano e método para a decomposição de um hidroperóxido de cicloalquila

Country Status (10)

Country Link
US (1) US7081552B2 (pt)
JP (1) JP4977836B2 (pt)
KR (1) KR101208102B1 (pt)
CN (1) CN101039892A (pt)
BR (1) BRPI0515213A (pt)
GB (1) GB2433899B (pt)
MX (1) MX2007002077A (pt)
TW (1) TW200613057A (pt)
UA (1) UA86644C2 (pt)
WO (1) WO2006023333A1 (pt)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7868201B2 (en) * 2005-07-01 2011-01-11 Exxonmobil Research And Engineering Company Process and catalyst for oxidation of hydrocarbons
CN100435944C (zh) * 2007-03-13 2008-11-26 浙江大学 一种负载型纳米金催化剂及制备方法
US20090159502A1 (en) * 2007-12-19 2009-06-25 Nemeth Laszlo T Decomposition of peroxides using iron-containing acidic zeolites
PT104862A (pt) 2009-12-07 2011-06-07 Univ Tras Os Montes E Alto Douro Catalisadores híbridos de vanádio e sua utilização em processos de oxidação selectiva de cicloalcanos
JP6004528B2 (ja) * 2011-08-29 2016-10-12 地方独立行政法人東京都立産業技術研究センター 多孔質シリカ内包粒子の製造方法および多孔質シリカ
UA111907C2 (uk) * 2012-07-26 2016-06-24 Родіа Оперейшнз Спосіб окиснення циклоалкану з одержанням спиртів та кетонів
WO2016102343A1 (en) * 2014-12-22 2016-06-30 Rhodia Operations Cycloalkane oxidation catalysts and method to produce alcohols and ketones
JP6544118B2 (ja) * 2015-07-29 2019-07-17 住友化学株式会社 ゼオライトの製造方法及びε−カプロラクタムの製造方法
ES2821103T3 (es) 2015-10-01 2021-04-23 Advansix Resins & Chemicals Llc Catalizadores de nanopartículas para la conversión del ciclohexanol en ciclohexanona
CN108329190B (zh) * 2018-01-28 2020-03-27 江西科因润滑材料有限公司 一种环己基过氧化氢催化分解的方法
JP2021512944A (ja) * 2018-01-30 2021-05-20 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ シクロアルカンの酸化方法

Family Cites Families (12)

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Publication number Priority date Publication date Assignee Title
NL9201756A (nl) * 1992-10-09 1994-05-02 Univ Delft Tech Werkwijze voor de gekatalyseerde ontleding van organische hydroperoxiden.
BE1007904A3 (nl) 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
JP2615432B2 (ja) * 1994-10-28 1997-05-28 工業技術院長 金−酸化チタン含有触媒による炭化水素の部分酸化方法
US5827406A (en) * 1995-01-31 1998-10-27 The Regents Of The University Of California Selective photooxidation of hydrocarbons in zeolites by oxygen
US5914013A (en) 1995-01-31 1999-06-22 The Regents Of The University Of California Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen
IN192732B (pt) 1995-09-29 2004-05-15 Council Scient Ind Res
KR100449421B1 (ko) 1996-07-01 2005-01-24 다우 글로벌 테크놀로지스 인크. 올레핀옥사이드의제조방법및촉매조성물
CA2279493A1 (en) 1997-02-11 1998-08-13 E.I. Du Pont De Nemours And Company Hydroperoxide decomposition process
JP4016121B2 (ja) * 1997-09-05 2007-12-05 独立行政法人産業技術総合研究所 炭化水素部分酸化用触媒及び含酸素有機化合物の製造方法
US6160183A (en) 1998-02-10 2000-12-12 E. I. Du Pont De Nemours And Company Direct oxidation of cycloalkanes
CZ20013106A3 (cs) * 1999-03-10 2002-05-15 E. I. Du Pont De Nemours And Company Rozkladný proces hydroperoxidů
DE60023358T2 (de) * 2000-08-18 2006-07-13 Invista Technologies S.A.R.L., Wilmington Verbesserter hydroperoxid zersetzungskatalysator

Also Published As

Publication number Publication date
JP2008510002A (ja) 2008-04-03
KR101208102B1 (ko) 2012-12-04
TW200613057A (en) 2006-05-01
KR20070059094A (ko) 2007-06-11
GB0703142D0 (en) 2007-03-28
MX2007002077A (es) 2007-04-23
US7081552B2 (en) 2006-07-25
JP4977836B2 (ja) 2012-07-18
UA86644C2 (ru) 2009-05-12
GB2433899B (en) 2008-05-14
US20060041172A1 (en) 2006-02-23
GB2433899A (en) 2007-07-11
CN101039892A (zh) 2007-09-19
WO2006023333A1 (en) 2006-03-02

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