BRPI0514558A - processo para a preparação de ácido fórmico por decomposição térmica de formiatos de amÈnio de aminas terciárias - Google Patents
processo para a preparação de ácido fórmico por decomposição térmica de formiatos de amÈnio de aminas terciáriasInfo
- Publication number
- BRPI0514558A BRPI0514558A BRPI0514558-9A BRPI0514558A BRPI0514558A BR PI0514558 A BRPI0514558 A BR PI0514558A BR PI0514558 A BRPI0514558 A BR PI0514558A BR PI0514558 A BRPI0514558 A BR PI0514558A
- Authority
- BR
- Brazil
- Prior art keywords
- tertiary amine
- preparation
- formic acid
- thermal decomposition
- ammonium formates
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/02—Formic acid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCESSO PARA A PREPARAçãO DE áCIDO FóRMICO POR DECOMPOSIçãO TéRMICA DE FORMIATOS DE AMÈNIO DE AMINAS TERCIáRIAS A invenção refere-se a um processo para a preparação de ácido fórmico pela decomposição térmica de formiatos de amónio de uma amina terciária (A), caracterizado pelo fato de que a amina terciária (A) na qual é baseado o formiato de amónio tem um ponto de ebulição à pressão normal na faixa de 105 até 175<198>C.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004040789A DE102004040789A1 (de) | 2004-08-23 | 2004-08-23 | Verfahren zur Herstellung von Ameisensäure |
DE102004040789.4 | 2004-08-23 | ||
PCT/EP2005/009066 WO2006021411A1 (de) | 2004-08-23 | 2005-08-22 | Verfahren zur herstellung von ameisensäure |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0514558A true BRPI0514558A (pt) | 2008-06-17 |
BRPI0514558B1 BRPI0514558B1 (pt) | 2014-12-30 |
Family
ID=35116049
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0514558-9B1A BRPI0514558B1 (pt) | 2004-08-23 | 2005-08-22 | Processo para a preparação de ácido fórmico por decomposição térmica de formiatos de amônio de aminas terciárias |
Country Status (13)
Country | Link |
---|---|
US (1) | US7420088B2 (pt) |
EP (1) | EP1784375B1 (pt) |
JP (1) | JP4621739B2 (pt) |
KR (1) | KR101210196B1 (pt) |
CN (1) | CN101006038B (pt) |
AR (1) | AR050706A1 (pt) |
AT (1) | ATE468314T1 (pt) |
BR (1) | BRPI0514558B1 (pt) |
DE (2) | DE102004040789A1 (pt) |
MY (1) | MY142297A (pt) |
NO (1) | NO20071045L (pt) |
PL (1) | PL1784375T3 (pt) |
WO (1) | WO2006021411A1 (pt) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102574762B (zh) * | 2009-06-26 | 2014-08-13 | 巴斯夫欧洲公司 | 生产甲酸的方法 |
UA104324C2 (ru) * | 2009-06-26 | 2014-01-27 | Басф Се | Способ получения муравьиной кислоты |
US9566574B2 (en) | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
US20110237830A1 (en) | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
US9790161B2 (en) | 2010-03-26 | 2017-10-17 | Dioxide Materials, Inc | Process for the sustainable production of acrylic acid |
US9957624B2 (en) | 2010-03-26 | 2018-05-01 | Dioxide Materials, Inc. | Electrochemical devices comprising novel catalyst mixtures |
US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
US9815021B2 (en) | 2010-03-26 | 2017-11-14 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
US9012345B2 (en) | 2010-03-26 | 2015-04-21 | Dioxide Materials, Inc. | Electrocatalysts for carbon dioxide conversion |
US10173169B2 (en) | 2010-03-26 | 2019-01-08 | Dioxide Materials, Inc | Devices for electrocatalytic conversion of carbon dioxide |
US8901350B2 (en) | 2010-06-29 | 2014-12-02 | Basf Se | Process for the preparation of formic acid |
WO2012000823A1 (de) | 2010-06-29 | 2012-01-05 | Basf Se | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
CA2801580A1 (en) | 2010-06-29 | 2012-01-05 | Basf Se | Process for the preparation of formic acid |
CN102596878B (zh) | 2010-06-29 | 2014-07-09 | 巴斯夫欧洲公司 | 通过二氧化碳与氢气反应制备甲酸的方法 |
US8791297B2 (en) | 2010-06-29 | 2014-07-29 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
US8877965B2 (en) | 2010-06-29 | 2014-11-04 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
SG191102A1 (en) * | 2010-12-21 | 2013-07-31 | Basf Se | Method for producing formic acid by reacting carbon dioxide with hydrogen |
US8742171B2 (en) | 2011-06-09 | 2014-06-03 | Basf Se | Process for preparing formic acid |
EP2718256A1 (en) | 2011-06-09 | 2014-04-16 | Basf Se | Process for preparing formic acid |
EP2729438A1 (de) * | 2011-07-07 | 2014-05-14 | Basf Se | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
DE102012016959A1 (de) | 2011-09-09 | 2013-03-14 | Basf Se | Verfahren zur Herstellung von Ameisensäure durch Umsetzung von Kohlendioxid mit Wasserstoff |
JP2014530216A (ja) | 2011-10-07 | 2014-11-17 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 二酸化炭素を水素と反応させることによるギ酸の製造法 |
DE102012021568A1 (de) | 2011-11-10 | 2013-05-16 | Basf Se | Eisenkomplexverbindungen enthaltend Eisen und mindestens einen Phosphanliganden mit mindestens einem organischen Rest mit mindestens 12 Kohlenstoffatomen, Verfahren zur Herstellung von Ameisensäure und Verwendung der Eisenkomplexverbindungen als Katalysatoren für die Hydrierung von Kohlendioxid |
WO2013068389A1 (de) | 2011-11-10 | 2013-05-16 | Basf Se | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
US8946462B2 (en) | 2011-11-10 | 2015-02-03 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
US8889905B2 (en) | 2011-12-20 | 2014-11-18 | Basf Se | Process for preparing formic acid |
BR112014015187A8 (pt) | 2011-12-20 | 2017-07-04 | Basf Se | processo para à obtenção de ácido fórmico |
JP2015501848A (ja) | 2011-12-20 | 2015-01-19 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | ギ酸の製造方法 |
US8835683B2 (en) | 2011-12-20 | 2014-09-16 | Basf Se | Process for preparing formic acid |
DE102012112404A1 (de) | 2011-12-22 | 2013-06-27 | Basf Se | Verfahren zur kombinierten Herstellung von Ameisensäure, Methylformiat, Formamidverbindungen und Metallformiaten |
EP2858970A1 (en) | 2012-06-11 | 2015-04-15 | Basf Se | Process for preparing formic acid |
WO2014047661A2 (en) | 2012-09-24 | 2014-03-27 | Dioxide Materials, Inc. | Devices and processes for carbon dioxide conversion into useful fuels and chemicals |
WO2014082845A1 (de) | 2012-11-27 | 2014-06-05 | Basf Se | Verfahren zur herstellung von ameisensäure |
US9428438B2 (en) | 2012-11-27 | 2016-08-30 | Basf Se | Process for preparing formic acid |
US10647652B2 (en) | 2013-02-24 | 2020-05-12 | Dioxide Materials, Inc. | Process for the sustainable production of acrylic acid |
US10774431B2 (en) | 2014-10-21 | 2020-09-15 | Dioxide Materials, Inc. | Ion-conducting membranes |
US10975480B2 (en) | 2015-02-03 | 2021-04-13 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
DE102015208706A1 (de) | 2015-05-11 | 2016-11-17 | Basf Se | Verfahren zur Herstellung von Ameisensäure |
DE102015208708A1 (de) | 2015-05-11 | 2016-11-17 | Basf Se | Verfahren zur Herstellung von Ameisensäure |
WO2017100104A1 (en) | 2015-12-08 | 2017-06-15 | Firestone Building Products Co., LLC | Process for producing isocyanate-based foam construction boards |
US10870987B1 (en) * | 2017-12-04 | 2020-12-22 | Firestone Building Products Company, Llc | Isocyanate-based foam construction boards |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1919850A (en) * | 1933-07-25 | Emil luscher | ||
US2511198A (en) * | 1948-01-02 | 1950-06-13 | Allied Chem & Dye Corp | Preparation of concentrated formic acid |
DE1233398B (de) | 1964-03-14 | 1967-02-02 | Bayer Ag | Herstellung von aus Ameisensaeure und tertiaeren organischen Basen bestehenden Additionsverbindungen |
DE2744313A1 (de) | 1977-10-01 | 1979-04-12 | Basf Ag | Verfahren zur herstellung von ameisensaeure |
CA1220222A (en) | 1982-05-22 | 1987-04-07 | David J. Drury | Production of formate salts |
GB8401005D0 (en) | 1984-01-14 | 1984-02-15 | Bp Chem Int Ltd | Formate salts |
DE3428319A1 (de) | 1984-08-01 | 1986-02-13 | Hüls AG, 4370 Marl | Verfahren zur gewinnung wasserfreier bzw. weitgehendwasserfreier ameisensaeure |
JPS62174036A (ja) * | 1986-01-24 | 1987-07-30 | Mitsubishi Gas Chem Co Inc | 第四級アンモニウム有機カルボン酸塩の製造方法 |
NZ227890A (en) * | 1988-02-17 | 1992-02-25 | Bp Chemical Ltd | Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen |
DE68920933T2 (de) | 1988-08-20 | 1995-05-24 | Bp Chem Int Ltd | Produktion von Formiat-Salzen von Stickstoffbasen. |
DE4211141A1 (de) * | 1992-04-03 | 1993-10-07 | Basf Ag | Verfahren zur Herstellung von Ameisensäure durch thermische Spaltung von quartären Ammoniumformiaten |
-
2004
- 2004-08-23 DE DE102004040789A patent/DE102004040789A1/de not_active Withdrawn
-
2005
- 2005-08-22 CN CN2005800280603A patent/CN101006038B/zh not_active Expired - Fee Related
- 2005-08-22 PL PL05782941T patent/PL1784375T3/pl unknown
- 2005-08-22 JP JP2007528722A patent/JP4621739B2/ja not_active Expired - Fee Related
- 2005-08-22 AT AT05782941T patent/ATE468314T1/de not_active IP Right Cessation
- 2005-08-22 EP EP05782941A patent/EP1784375B1/de not_active Not-in-force
- 2005-08-22 BR BRPI0514558-9B1A patent/BRPI0514558B1/pt not_active IP Right Cessation
- 2005-08-22 US US11/574,069 patent/US7420088B2/en not_active Expired - Fee Related
- 2005-08-22 DE DE502005009604T patent/DE502005009604D1/de active Active
- 2005-08-22 KR KR1020077004225A patent/KR101210196B1/ko not_active IP Right Cessation
- 2005-08-22 AR ARP050103511A patent/AR050706A1/es active IP Right Grant
- 2005-08-22 WO PCT/EP2005/009066 patent/WO2006021411A1/de active Application Filing
- 2005-08-23 MY MYPI20053952A patent/MY142297A/en unknown
-
2007
- 2007-02-23 NO NO20071045A patent/NO20071045L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
ATE468314T1 (de) | 2010-06-15 |
EP1784375A1 (de) | 2007-05-16 |
CN101006038A (zh) | 2007-07-25 |
DE102004040789A1 (de) | 2006-03-02 |
US7420088B2 (en) | 2008-09-02 |
KR101210196B1 (ko) | 2012-12-07 |
US20080097126A1 (en) | 2008-04-24 |
CN101006038B (zh) | 2010-05-26 |
EP1784375B1 (de) | 2010-05-19 |
JP2008510757A (ja) | 2008-04-10 |
WO2006021411A1 (de) | 2006-03-02 |
NO20071045L (no) | 2007-03-22 |
JP4621739B2 (ja) | 2011-01-26 |
AR050706A1 (es) | 2006-11-15 |
KR20070045277A (ko) | 2007-05-02 |
BRPI0514558B1 (pt) | 2014-12-30 |
DE502005009604D1 (de) | 2010-07-01 |
PL1784375T3 (pl) | 2010-10-29 |
MY142297A (en) | 2010-11-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/08/2005, OBSERVADAS AS CONDICOES LEGAIS. |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 11A ANUIDADE. |
|
B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |