BRPI0508887A - catalisador de polimerização compreendendo um ligante amidina - Google Patents
catalisador de polimerização compreendendo um ligante amidinaInfo
- Publication number
- BRPI0508887A BRPI0508887A BRPI0508887-9A BRPI0508887A BRPI0508887A BR PI0508887 A BRPI0508887 A BR PI0508887A BR PI0508887 A BRPI0508887 A BR PI0508887A BR PI0508887 A BRPI0508887 A BR PI0508887A
- Authority
- BR
- Brazil
- Prior art keywords
- binder
- integer
- amidine
- observer
- formula
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/20—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
CATALISADOR DE POLIMERIZAçãO COMPREENDENDO UM LIGANTE AMIDINA A invenção se refere a um processo para preparação de um polímero compreendendo pelo menos uma olefina C2-20 hidrocarbila alifática ou aromática, em presença de um catalisador iónico compreendendo um composto organometálico e um ativador e, opcionalmente um limpador, caracterizad pelo fato de que o composto organometálico é um composto de acordo com a fórmula (1) onde: M é um metal do grupo 3,4,5, 6 ou 7, ou a série de lantanídeo e p é a valência do metal M, A representa um ligante observador neutro ou aniónico, cuja valência v é 0, 1 ou 2, e q é um inteiro indicando o número de ligantes observadores A, z é uma fração de ponte opcional, n é o número inteiro de frações de ponte paralela z, Y é um ligante observador contendo amidina, representado pela fórmula (2): onde o ligante contendo amidina é covalentemente ligado ao metal M através do átomo de nitrogênio imina, Sub1 é um substituinte, que compreende um grupo de 14 átomos através do qual Sub1 é ligado ao átomo de carbono imina. Sub2 é um substituinte que compreende um heteroátomo do grupo 15-16, através do qual Sub2 é ligado ao átomo de carbono de imina, r é um inteiro > 0, L é um ligante básico de Lewis neutro, opcional, e j é um inteiro indicado o número de ligantes neutros L e X é um ligante aniónico. A invenção também se refere a um composto organometálico, de acordo com a fórmula (1) e a um processo para preparação desse composto, bem como a um UHMWPE possuindo um peso molecular médio em peso de pelo menos 4.000 kg/mol e uma distribuição de peso molecular Mw/Mn inferior a 2,6.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04075854 | 2004-03-17 | ||
EP04075854.2 | 2004-03-17 | ||
US55605704P | 2004-03-25 | 2004-03-25 | |
US60/556.057 | 2004-03-25 | ||
PCT/EP2005/002812 WO2005090418A1 (en) | 2004-03-17 | 2005-03-14 | Polimerization catalyst comprising an amidine ligand |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0508887A true BRPI0508887A (pt) | 2007-09-11 |
BRPI0508887B1 BRPI0508887B1 (pt) | 2015-08-11 |
Family
ID=34928113
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0508887-9A BRPI0508887B1 (pt) | 2004-03-17 | 2005-03-14 | Processo para preparação de um polímero, catalisador iônico compreendendo um composto organometálico, catalisador suportado e processo para produção de um composto organometálico |
Country Status (8)
Country | Link |
---|---|
US (1) | US7956140B2 (pt) |
EP (1) | EP1730205B1 (pt) |
JP (2) | JP4904450B2 (pt) |
KR (1) | KR101289564B1 (pt) |
CN (1) | CN1934145B (pt) |
BR (1) | BRPI0508887B1 (pt) |
CA (1) | CA2557796C (pt) |
WO (1) | WO2005090418A1 (pt) |
Families Citing this family (50)
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JP2007063409A (ja) * | 2005-08-31 | 2007-03-15 | Asahi Kasei Chemicals Corp | 環状オレフィン系共重合体の製造方法 |
EP1764379A1 (en) * | 2005-09-19 | 2007-03-21 | DSM IP Assets B.V. | Polymerization catalyst comprising an amidine ligand |
EP1806369A1 (en) * | 2005-12-22 | 2007-07-11 | DSMIP Assets B.V. | Zwitterionic amidine catalyst |
ATE531738T1 (de) * | 2007-02-08 | 2011-11-15 | Lanxess Elastomers Bv | Elastomerverbindung |
US8372431B2 (en) | 2007-10-26 | 2013-02-12 | Bial-Portela & C.A., S.A. | Pharmaceutical composition comprising licarbazepine acetate |
WO2009063084A2 (en) * | 2007-11-15 | 2009-05-22 | Dsm Ip Assets Bv | Process for the preparation of ultra high molecular weight polyethylene |
EP2319874A1 (en) * | 2009-11-06 | 2011-05-11 | DSM IP Assets B.V. | Catalyst component for the polymerization of olefins having a guanidinate ligand |
EP2336204A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | Borane activated ti catalyst system comprising amidine and diene ligand |
EP2336205A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand |
ES2691727T3 (es) * | 2010-02-19 | 2018-11-28 | Dow Global Technologies Llc | Complejos metal-ligando y catalizadores |
CN103827152B (zh) * | 2011-10-13 | 2016-08-17 | 三井化学株式会社 | 乙烯系共聚物、包含该共聚物的组合物及由乙烯系共聚物或组合物形成的成型品以及膜或片材 |
CN102603935B (zh) * | 2012-02-24 | 2013-06-05 | 山西大学 | 金属桥联双脒基锆催化剂及其制备方法和应用 |
JP2013227539A (ja) * | 2012-03-26 | 2013-11-07 | Japan Polyethylene Corp | 耐摩耗性樹脂成形体製造用エチレン系重合体、耐摩耗性樹脂成形体製造用エチレン系樹脂組成物、耐摩耗性樹脂成形体およびその製造方法 |
WO2014060252A1 (en) | 2012-10-16 | 2014-04-24 | Teijin Aramid B.V. | Process for the synthesis of disentangled uhmw-pe using a cr or ti catalyst |
EP2801579B1 (en) | 2013-05-08 | 2016-10-19 | Arlanxeo Netherlands B.V. | Metal complex with a Lewis base ligand |
EP2801578B1 (en) | 2013-05-08 | 2017-01-04 | Arlanxeo Netherlands B.V. | Metal complex with a bridged cyclopentadienyl amidine ligand |
EP2816050B1 (en) * | 2013-06-18 | 2016-04-27 | Lanxess Elastomers B.V. | Bimetallic complex comprising cyclopentadienyl and amidine ligands |
EP2837634A1 (en) | 2013-08-12 | 2015-02-18 | Saudi Basic Industries Corporation | Catalyst system for polymerisation of an olefin |
BR112016002870B1 (pt) | 2013-08-12 | 2020-11-24 | Saudi Basic Industries Corporation | Sistema catalisador para polimerizacao de uma olefina, seu processo de preparação, processo para preparar uma poliolefina, poliolefina obtenivel do mesmo, artigo moldado e uso |
KR101727701B1 (ko) | 2013-09-09 | 2017-04-18 | 주식회사 엘지화학 | 이핵 메탈로센 화합물, 및 이의 제조방법 |
KR102329527B1 (ko) | 2013-10-25 | 2021-11-22 | 디에스엠 아이피 어셋츠 비.브이. | 초고분자량 폴리에틸렌의 제조 |
CN105940022B (zh) | 2013-12-20 | 2018-07-31 | 沙特基础工业公司 | 用于烯烃聚合的催化剂体系 |
CN104744613A (zh) * | 2013-12-27 | 2015-07-01 | 苏州亚培克生物科技有限公司 | 含氟苯脒单茂金属催化剂、制备方法及其应用 |
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JP6355815B2 (ja) | 2014-03-21 | 2018-07-11 | エクソンモービル・ケミカル・パテンツ・インク | エチレンプロピレンコポリマーを製造する方法 |
KR102506178B1 (ko) * | 2014-09-18 | 2023-03-07 | 아란세오 네덜란즈 비.브이. | 아미딘 및 치환된 시클로펜타디에닐 리간드를 포함하는 금속 착물 |
CN107108804B (zh) * | 2014-12-31 | 2020-07-24 | 陶氏环球技术有限责任公司 | 聚烯烃组合物和其生产方法 |
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JP6691208B2 (ja) * | 2015-08-14 | 2020-04-28 | アランセオ・ネザーランズ・ベー・フェー | 触媒系 |
US10800865B2 (en) | 2015-09-14 | 2020-10-13 | Exxonmobil Chemical Patents Inc. | Process for making branched EPDM and the EPDM therefrom |
KR101938585B1 (ko) * | 2015-12-24 | 2019-01-16 | 주식회사 엘지화학 | 폴리올레핀의 제조방법 |
CA3024655A1 (en) | 2016-05-20 | 2017-11-23 | Arlanxeo Netherlands B.V. | Rubber composition |
CN106008777B (zh) * | 2016-06-20 | 2018-12-11 | 安徽欧凯密封件有限公司 | 一种稀土催化体系制备三元乙丙橡胶的方法 |
EP3272761A1 (en) | 2016-07-22 | 2018-01-24 | Arlanxeo Netherlands B.V. | Metall complex comprising amidine and substituted cyclopentadienyl ligands |
EP3409697A1 (en) | 2017-05-28 | 2018-12-05 | SABIC Global Technologies B.V. | Preparation of polymer dispersions |
CN111032772B (zh) | 2017-06-14 | 2022-07-15 | 埃克森美孚化学专利公司 | 用于交联应用的乙烯共聚物共混物 |
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JP7175692B2 (ja) * | 2018-03-26 | 2022-11-21 | 三井化学株式会社 | オレフィン重合用触媒、およびオレフィン重合体の製造方法 |
CN109092361B (zh) * | 2018-07-18 | 2021-08-13 | 嘉兴学院 | 基于查尔酮类二羧酸配体的稀土金属有机配合物及其制备方法和应用 |
SG11202100944XA (en) | 2018-09-18 | 2021-04-29 | Arlanxeo Netherlands Bv | Catalyst mixture |
JP2023518732A (ja) * | 2020-03-16 | 2023-05-08 | アランセオ・ネザーランズ・ベー・フェー | エチレンコポリマー、及びエチレンコポリマーを製造するための触媒組成物 |
EP3882283A1 (en) | 2020-03-17 | 2021-09-22 | Arlanxeo Netherlands B.V. | Ethylene-copolymers and catalyst mixture for making ethylene copolymers |
JP2023524448A (ja) | 2020-05-15 | 2023-06-12 | アランセオ・ネザーランズ・ベー・フェー | エチレン-コポリマーゴム |
JP7257595B2 (ja) * | 2020-10-02 | 2023-04-13 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法 |
WO2022207551A1 (en) | 2021-03-29 | 2022-10-06 | Arlanxeo Netherlands B.V. | Process for producing polymers |
JP2024515258A (ja) | 2021-04-09 | 2024-04-08 | アランセオ・ネザーランズ・ベー・フェー | スルフィルイミン型リガンドとの金属錯体及び重合触媒としてのその使用 |
KR20240001147A (ko) | 2021-04-30 | 2024-01-03 | 아란세오 네덜란즈 비.브이. | 올레핀 중합을 위한 금속 착물 촉매 |
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JPH11236409A (ja) | 1998-02-20 | 1999-08-31 | Nippon Polyolefin Kk | オレフィン重合用触媒成分、オレフィン重合用触媒及びポリオレフィンの製造方法 |
JPH11236410A (ja) | 1998-02-20 | 1999-08-31 | Nippon Polyolefin Kk | 超高分子量エチレン系重合体の製造方法 |
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2005
- 2005-03-14 CN CN2005800085579A patent/CN1934145B/zh active Active
- 2005-03-14 KR KR1020067018954A patent/KR101289564B1/ko active IP Right Grant
- 2005-03-14 WO PCT/EP2005/002812 patent/WO2005090418A1/en active Application Filing
- 2005-03-14 EP EP05716129A patent/EP1730205B1/en active Active
- 2005-03-14 JP JP2007503287A patent/JP4904450B2/ja active Active
- 2005-03-14 BR BRPI0508887-9A patent/BRPI0508887B1/pt active IP Right Grant
- 2005-03-14 CA CA2557796A patent/CA2557796C/en active Active
- 2005-03-14 US US10/592,861 patent/US7956140B2/en active Active
-
2011
- 2011-08-12 JP JP2011177201A patent/JP5577306B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
CN1934145B (zh) | 2011-01-19 |
EP1730205B1 (en) | 2012-09-26 |
JP2007529584A (ja) | 2007-10-25 |
CA2557796A1 (en) | 2005-09-29 |
KR20070015385A (ko) | 2007-02-02 |
WO2005090418A1 (en) | 2005-09-29 |
JP5577306B2 (ja) | 2014-08-20 |
JP2012007171A (ja) | 2012-01-12 |
US7956140B2 (en) | 2011-06-07 |
CA2557796C (en) | 2012-10-23 |
CN1934145A (zh) | 2007-03-21 |
KR101289564B1 (ko) | 2013-07-24 |
US20090012246A1 (en) | 2009-01-08 |
EP1730205A1 (en) | 2006-12-13 |
BRPI0508887B1 (pt) | 2015-08-11 |
JP4904450B2 (ja) | 2012-03-28 |
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