BRPI0412966A - elemento filtrante de escapamento de diesel melhorado e processo para depositar ìons metálicos precipitados nas superfìcies de uma parede porosa rìgida - Google Patents

elemento filtrante de escapamento de diesel melhorado e processo para depositar ìons metálicos precipitados nas superfìcies de uma parede porosa rìgida

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Publication number
BRPI0412966A
BRPI0412966A BRPI0412966-0A BRPI0412966A BRPI0412966A BR PI0412966 A BRPI0412966 A BR PI0412966A BR PI0412966 A BRPI0412966 A BR PI0412966A BR PI0412966 A BRPI0412966 A BR PI0412966A
Authority
BR
Brazil
Prior art keywords
porous wall
rigid porous
metal ions
exhaust gas
precipitated metal
Prior art date
Application number
BRPI0412966-0A
Other languages
English (en)
Inventor
Cheng G Li
Robin P Ziebarth
Martin C Cornell
Steven B Swartzmiller
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of BRPI0412966A publication Critical patent/BRPI0412966A/pt

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9463Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick
    • B01D53/9468Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick in different layers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/464Rhodium
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    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
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    • B01J37/02Impregnation, coating or precipitation
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    • B01J37/02Impregnation, coating or precipitation
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
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    • C04B41/51Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
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    • CCHEMISTRY; METALLURGY
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
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    • F01N3/023Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • F01N3/0231Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using special exhaust apparatus upstream of the filter for producing nitrogen dioxide, e.g. for continuous filter regeneration systems [CRT]
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    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
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    • F01N3/033Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
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    • F01N3/2828Ceramic multi-channel monoliths, e.g. honeycombs
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Toxicology (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Catalysts (AREA)
  • Filtering Materials (AREA)

Abstract

"ELEMENTO FILTRANTE DE ESCAPAMENTO DE DIESEL MELHORADO E PROCESSO PARA DEPOSITAR ìONS METáLICOS PRECIPITADOS NAS SUPERFìCIES DE UMA PAREDE POROSA RìGIDA". Elemento filtrante de escapamento de Diesel melhorado do tipo tendo uma porção de parede porosa rígida formada de uma cerâmica acicular (tal como mulita acicular) a porção de parede porosa tendo um primeiro lado e um segundo lado, a porção de parede porosa sendo revestida com um catalisador de metal precioso e um absorvente de NO~ x~, tal que quando o gás de escapamento de um motor Diesel atravessa a parede porosa rígida do primeiro lado para o segundo lado, o gás de escapamento contendo oxigênio em excesso, NO~ x~, e fuligem, a fuligem no gás de escapamento é aprisionada dentro da parede porosa rígida e oxidada cataliticamente a dióxido de carbono, o NO é oxidado cataliticamente a NO~ 2~, o qual é depois absorvido pelo absorvente de NO~ x~, e tal que quando o gás de escapamento contém monóxido de carbono e hidrocarboneto em excesso, então o absorvente de NO~ x~ é regenerado e, o hidrocarboneto e monóxido de carbono remanescente são convertidos cataliticamente a nitrogênio e dióxido de carbono. Além disso, um processo para depositar íons metálicos precipitados nas superfícies de tal parede porosa rígida.
BRPI0412966-0A 2003-08-29 2004-08-27 elemento filtrante de escapamento de diesel melhorado e processo para depositar ìons metálicos precipitados nas superfìcies de uma parede porosa rìgida BRPI0412966A (pt)

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WO2005021138A3 (en) 2005-05-19
CA2533697C (en) 2013-02-12
PL1677896T3 (pl) 2013-08-30
JP2007503983A (ja) 2007-03-01
CN1845780A (zh) 2006-10-11
KR20060083450A (ko) 2006-07-20
RU2006110029A (ru) 2006-08-10
RU2350379C2 (ru) 2009-03-27
US8661794B2 (en) 2014-03-04
JP5782085B2 (ja) 2015-09-24
KR101117039B1 (ko) 2012-03-15
KR20110091818A (ko) 2011-08-12
ZA200600757B (en) 2007-05-30
CA2794531A1 (en) 2005-03-10
KR101141875B1 (ko) 2012-05-08
WO2005021138A2 (en) 2005-03-10
EP1677896A2 (en) 2006-07-12
CA2533697A1 (en) 2005-03-10
EP1677896B1 (en) 2013-04-17
US20060193757A1 (en) 2006-08-31
CN1845780B (zh) 2010-06-16
JP2014079755A (ja) 2014-05-08

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