GB1119180A - Forming deposits within porous material - Google Patents
Forming deposits within porous materialInfo
- Publication number
- GB1119180A GB1119180A GB14694/66A GB1469466A GB1119180A GB 1119180 A GB1119180 A GB 1119180A GB 14694/66 A GB14694/66 A GB 14694/66A GB 1469466 A GB1469466 A GB 1469466A GB 1119180 A GB1119180 A GB 1119180A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxide
- metal
- ammonia
- substance
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011148 porous material Substances 0.000 title abstract 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 16
- 229910021529 ammonia Inorganic materials 0.000 abstract 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 8
- 229910052751 metal Inorganic materials 0.000 abstract 8
- 239000002184 metal Substances 0.000 abstract 8
- 150000003839 salts Chemical class 0.000 abstract 8
- 239000000126 substance Substances 0.000 abstract 8
- 239000000243 solution Substances 0.000 abstract 6
- 229920000742 Cotton Polymers 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 4
- 239000000919 ceramic Substances 0.000 abstract 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 4
- 150000004692 metal hydroxides Chemical class 0.000 abstract 4
- -1 pelladium Chemical compound 0.000 abstract 4
- 239000000835 fiber Substances 0.000 abstract 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- 229910052779 Neodymium Inorganic materials 0.000 abstract 2
- 229910052777 Praseodymium Inorganic materials 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 2
- 229910052772 Samarium Inorganic materials 0.000 abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052776 Thorium Inorganic materials 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052770 Uranium Inorganic materials 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 2
- 108010046334 Urease Proteins 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
- DZHMRSPXDUUJER-UHFFFAOYSA-N [amino(hydroxy)methylidene]azanium;dihydrogen phosphate Chemical compound NC(N)=O.OP(O)(O)=O DZHMRSPXDUUJER-UHFFFAOYSA-N 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052790 beryllium Inorganic materials 0.000 abstract 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052793 cadmium Inorganic materials 0.000 abstract 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 239000004202 carbamide Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 239000007859 condensation product Substances 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 abstract 2
- 239000004312 hexamethylene tetramine Substances 0.000 abstract 2
- 230000000977 initiatory effect Effects 0.000 abstract 2
- 229910052741 iridium Inorganic materials 0.000 abstract 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052746 lanthanum Inorganic materials 0.000 abstract 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052753 mercury Inorganic materials 0.000 abstract 2
- 229960004011 methenamine Drugs 0.000 abstract 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 abstract 2
- 238000001556 precipitation Methods 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052707 ruthenium Inorganic materials 0.000 abstract 2
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 239000004332 silver Substances 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract 2
- 229910052727 yttrium Inorganic materials 0.000 abstract 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- 239000011449 brick Substances 0.000 abstract 1
- 239000003575 carbonaceous material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
- C23C18/1208—Oxides, e.g. ceramics
- C23C18/1216—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/48—Oxides or hydroxides of chromium, molybdenum or tungsten; Chromates; Dichromates; Molybdates; Tungstates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/48—Oxides or hydroxides of chromium, molybdenum or tungsten; Chromates; Dichromates; Molybdates; Tungstates
- D06M11/485—Oxides or hydroxides of manganese; Manganates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Catalysts (AREA)
Abstract
Metal hydroxides are deposited on the interior surfaces of porous materials, e.g. woven cotton fabrics, sponges, bricks and ceramic fibre blankets, by contacting without precipitation of hydroxide the interior surfaces with (a) an aqueous solution of at least one metal salt from which the corresponding hydroxide may be precipitated at a pH of 1.7-12.5 and (b) a substance capable of decomposing at the pH of the solution to give ammonia with a consequent rise of the pH, and initiating the decomposition of the substance thereby raising the pH of the solution to a value such that the corresponding hydroxide of the metal is precipitated on the interior surfaces. The salt may be of copper, silver, beryllium, magnesium, calcium, zinc, cadmium, mercury, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, zirconium, thorium, tin, lead, chromium, uranium, manganese, iron, cobalt, nickel, ruthenium, rhodium, pelladium, iridium, or aluminium, aluminium oxychloride being preferred, and the substance decomposing to give ammonia may be hexamethylene tetramine, urea preferably in admixture with urease, urea orthophosphate and condensation products of aldehydes and ammonia. The aqueous solution of the metal salt and the ammonia producing substance may be mixed and the resulting solution adjusted to the desired pH and applied to the porous material which is then heated. The porous material may subsequently be heated to convert the precipitated hydroxide to the corresponding oxide or to a salt of the metal and if it is a carbonaceous material e.g. a cotton material or sponge, to burn away the substrate to form a material suitable for use as a catalyst. In the case of a ceramic blanket the metal hydroxide is deposited as discrete nodules around the fibres especially at the points of intersection of two or more fibres thus locking them together.ALSO:Metal hydroxides are deposited on the interior surfaces of porous materials, e.g. woven cotton fabrics and ceramic fibre blankets, by contacting without precipitation of hydroxide the interior surfaces with (a) an aqueous solution of at least one metal salt from which the corresponding hydroxide may be precipitated at a pH of 1.7-12.5 and (b) a substance capable of decomposing at the pH of the solution to give ammonia with a consequent rise of the pH, and initiating the decomposition of the substance thereby raising the pH of the solution to a value such that the corresponding hydroxide of the metal is precipitated on the interior surfaces. The salt may be of copper, silver, beryllium, magnesium, calcium, zinc, cadmium, mercury, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, zirconium, thorium, tin, lead, chromium, uranium, manganese, iron, cobalt, nickel, ruthenium, rhodium, pelladium, iridium, or aluminium, aluminium oxychloride being preferred. and the substance decomposing to give ammonia may be hexamethylene tetramine, urea preferably in admixture with urease, urea orthophosphate and condensation products of aldehydes and ammonia. The aqueous solution of the metal salt and the ammonia producing substance may be mixed and the resulting solution adjusted to the desired pH and applied to the porous material which is then heated. The porous material may subsequently be heated to convert the precipitated hydroxide to the corresponding oxide or to a salt of the metal and if it is a cotton material or sponge to burn away the substrate to form a material suitable for use as a catalyst. In the case of a ceramic fibre blanket the metal hydroxide is deposited as discrete nodules around the fibres especially at the points of intersection of two or more fibres thus locking them together.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB14694/66A GB1119180A (en) | 1966-04-01 | 1966-04-01 | Forming deposits within porous material |
| LU53313D LU53313A1 (en) | 1966-04-01 | 1967-03-29 | |
| DE19671646731 DE1646731A1 (en) | 1966-04-01 | 1967-03-30 | Process for forming deposits in porous material |
| NL6704573A NL6704573A (en) | 1966-04-01 | 1967-03-30 | |
| ES338751A ES338751A1 (en) | 1966-04-01 | 1967-03-31 | Forming deposits within porous material |
| FR101103A FR1517389A (en) | 1966-04-01 | 1967-03-31 | Method of forming deposits on the internal surfaces of porous materials |
| AT311067A AT281665B (en) | 1966-04-01 | 1967-03-31 | Process for the production of deposits of metal hydroxides or oxides on a material |
| CH457167A CH476119A (en) | 1966-04-01 | 1967-03-31 | Method of forming deposits inside a porous material |
| BE696527D BE696527A (en) | 1966-04-01 | 1967-04-03 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB14694/66A GB1119180A (en) | 1966-04-01 | 1966-04-01 | Forming deposits within porous material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1119180A true GB1119180A (en) | 1968-07-10 |
Family
ID=10045904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14694/66A Expired GB1119180A (en) | 1966-04-01 | 1966-04-01 | Forming deposits within porous material |
Country Status (9)
| Country | Link |
|---|---|
| AT (1) | AT281665B (en) |
| BE (1) | BE696527A (en) |
| CH (1) | CH476119A (en) |
| DE (1) | DE1646731A1 (en) |
| ES (1) | ES338751A1 (en) |
| FR (1) | FR1517389A (en) |
| GB (1) | GB1119180A (en) |
| LU (1) | LU53313A1 (en) |
| NL (1) | NL6704573A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0179589A2 (en) * | 1984-10-09 | 1986-04-30 | The Babcock & Wilcox Company | Densification of ceramic materials |
| EP0195877A1 (en) * | 1985-03-26 | 1986-10-01 | Fritz Wegmueller | Process for depositing a uniform metal hydroxide layer on substrates and for extracting metals in solution |
| US7381681B2 (en) | 2004-04-21 | 2008-06-03 | Dow Global Technologies Inc. | Method for increasing the strength of porous ceramic bodies and bodies made therefrom |
| US7438739B2 (en) | 2004-07-26 | 2008-10-21 | Dow Global Technologies Inc. | Catalyzed soot filter |
| US7772151B2 (en) | 2006-07-21 | 2010-08-10 | Dow Global Technologies Inc. | Zone catalyzed soot filter |
| US7928032B2 (en) | 2007-12-21 | 2011-04-19 | Dow Global Technologies Llc | Catalyzed soot filter and method(s) to make these |
| US7947102B2 (en) | 2006-12-21 | 2011-05-24 | Dow Global Technologies Llc | Soot filter |
| US8092579B2 (en) | 2007-10-12 | 2012-01-10 | Dow Global Technologies Llc | Thermal shock resistant soot filter |
| US8661794B2 (en) | 2003-08-29 | 2014-03-04 | Dow Global Technologies Llc | Diesel exhaust filter |
| CN108435160A (en) * | 2018-03-21 | 2018-08-24 | 中国科学院生态环境研究中心 | It is a kind of width temperature and high-speed under ozone decomposition cerium Mn catalyst, Preparation method and use |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1075220B (en) * | 1960-02-11 | LICENTIA Patent Verwaltungs GmbH Frankfurt/M | Double socket for tubular discharge lamps with U-shape, especially fluorescent lamps | |
| US4066387A (en) * | 1975-03-26 | 1978-01-03 | The State Of Israel Ministry Of Commerce And Industry | Method of improving the sorption capacity of polymers |
| FR2550953B1 (en) * | 1977-04-12 | 1987-02-20 | Commissariat Energie Atomique | PROCESS FOR PRODUCING PERMEABLE MINERAL MEMBRANES |
| FR2575396B2 (en) * | 1977-04-12 | 1987-04-30 | Commissariat Energie Atomique | PROCESS FOR PRODUCING POROUS AND PERMEABLE MINERAL MEMBRANES |
| DE3305375C2 (en) * | 1983-02-17 | 1985-01-03 | Degussa Ag, 6000 Frankfurt | Process for the production of binder-free thermal insulation moldings |
| FR2575459B1 (en) * | 1984-12-28 | 1991-10-04 | Commissariat Energie Atomique | PROCESS FOR THE MANUFACTURE OF POROUS AND PERMEABLE MINERAL MEMBRANES |
| FR2604920B1 (en) * | 1986-10-10 | 1988-12-02 | Ceraver | CERAMIC FILTRATION MEMBRANE AND MANUFACTURING METHOD |
| EP0332789B1 (en) * | 1988-03-17 | 1994-02-23 | Societe Des Ceramiques Techniques | Filter membrane and process for its preparation |
| FR2628749B1 (en) * | 1988-03-17 | 1993-10-22 | Cgee Alsthom | PROCESS FOR THE TREATMENT OF POLLUTED WATER EMULSIONS OR MICROEMULSIONS |
| EP0332788B1 (en) * | 1988-03-17 | 1992-07-22 | Societe Des Ceramiques Techniques | Process for treating polluted oil-in-water emulsions or microemulsions |
-
1966
- 1966-04-01 GB GB14694/66A patent/GB1119180A/en not_active Expired
-
1967
- 1967-03-29 LU LU53313D patent/LU53313A1/xx unknown
- 1967-03-30 DE DE19671646731 patent/DE1646731A1/en active Pending
- 1967-03-30 NL NL6704573A patent/NL6704573A/xx unknown
- 1967-03-31 CH CH457167A patent/CH476119A/en not_active IP Right Cessation
- 1967-03-31 ES ES338751A patent/ES338751A1/en not_active Expired
- 1967-03-31 AT AT311067A patent/AT281665B/en not_active IP Right Cessation
- 1967-03-31 FR FR101103A patent/FR1517389A/en not_active Expired
- 1967-04-03 BE BE696527D patent/BE696527A/xx unknown
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0179589A3 (en) * | 1984-10-09 | 1987-10-07 | The Babcock & Wilcox Company | Densification of ceramic materials |
| EP0179589A2 (en) * | 1984-10-09 | 1986-04-30 | The Babcock & Wilcox Company | Densification of ceramic materials |
| EP0195877A1 (en) * | 1985-03-26 | 1986-10-01 | Fritz Wegmueller | Process for depositing a uniform metal hydroxide layer on substrates and for extracting metals in solution |
| WO1986005822A1 (en) * | 1985-03-26 | 1986-10-09 | Fritz Wegmueller | Method of deposition of uniform, substrate-independent metal layers on solid and liquid material surfaces, and/or metal depletion of solutions |
| US8661794B2 (en) | 2003-08-29 | 2014-03-04 | Dow Global Technologies Llc | Diesel exhaust filter |
| US7381681B2 (en) | 2004-04-21 | 2008-06-03 | Dow Global Technologies Inc. | Method for increasing the strength of porous ceramic bodies and bodies made therefrom |
| EP2253603A1 (en) | 2004-04-21 | 2010-11-24 | Dow Global Technologies Inc. | Porous ceramic bodies |
| US7381680B2 (en) | 2004-04-21 | 2008-06-03 | Dow Global Technologies Inc. | Method for increasing the strength of porous ceramic bodies and bodies made therefrom |
| US7438739B2 (en) | 2004-07-26 | 2008-10-21 | Dow Global Technologies Inc. | Catalyzed soot filter |
| US7772151B2 (en) | 2006-07-21 | 2010-08-10 | Dow Global Technologies Inc. | Zone catalyzed soot filter |
| US7947102B2 (en) | 2006-12-21 | 2011-05-24 | Dow Global Technologies Llc | Soot filter |
| US8092579B2 (en) | 2007-10-12 | 2012-01-10 | Dow Global Technologies Llc | Thermal shock resistant soot filter |
| US7928032B2 (en) | 2007-12-21 | 2011-04-19 | Dow Global Technologies Llc | Catalyzed soot filter and method(s) to make these |
| CN108435160A (en) * | 2018-03-21 | 2018-08-24 | 中国科学院生态环境研究中心 | It is a kind of width temperature and high-speed under ozone decomposition cerium Mn catalyst, Preparation method and use |
| CN108435160B (en) * | 2018-03-21 | 2020-11-13 | 中国科学院生态环境研究中心 | Cerium-manganese catalyst for decomposing ozone at wide temperature and high airspeed, preparation method and application |
| US11684908B2 (en) | 2018-03-21 | 2023-06-27 | Research Center For Eco-Environmental Sciences, Chinese Academy Of Sciences | Cerium manganese catalyst, preparation method therefor and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| LU53313A1 (en) | 1967-05-29 |
| FR1517389A (en) | 1968-03-15 |
| DE1646731A1 (en) | 1971-08-26 |
| BE696527A (en) | 1967-10-03 |
| ES338751A1 (en) | 1968-04-01 |
| NL6704573A (en) | 1967-10-02 |
| CH476119A (en) | 1969-07-31 |
| AT281665B (en) | 1970-05-25 |
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