BR9814232A - Benzilidenopirazolona, composição, processos para a preparação de composições herbicidamente ativas, para controlar vegetação indesejada e para a preparação de benzilidenopirazolonas, e, benzoilpirazol. - Google Patents

Benzilidenopirazolona, composição, processos para a preparação de composições herbicidamente ativas, para controlar vegetação indesejada e para a preparação de benzilidenopirazolonas, e, benzoilpirazol.

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Publication number
BR9814232A
BR9814232A BR9814232-1A BR9814232A BR9814232A BR 9814232 A BR9814232 A BR 9814232A BR 9814232 A BR9814232 A BR 9814232A BR 9814232 A BR9814232 A BR 9814232A
Authority
BR
Brazil
Prior art keywords
optionally substituted
alkyl
preparation
hydrogen
benzylidenopyrazolones
Prior art date
Application number
BR9814232-1A
Other languages
English (en)
Inventor
Joachim Rheinheimer
Matthias Witschel
Stefan Engel
Ernst Baumann
Wolfgang Van Deyn
Regina Luise Hill
Guido Mayer
Ulf Misslitz
Oliver Wagner
Martina Otten
Karl-Otto Westphalen
Helmut Walter
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BR9814232A publication Critical patent/BR9814232A/pt

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/06Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/781,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D207/00Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16Halogen atoms or nitro radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18One oxygen or sulfur atom
    • C07D231/20One oxygen atom attached in position 3 or 5
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D261/00Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/08Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D263/00Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/30Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D263/32Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D275/00Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
    • C07D275/02Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D277/00Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/22Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D403/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/10Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D405/00Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/10Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/10Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D417/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/10Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

"BENZILIDENOPIRAZOLONA, COMPOSIçãO, PROCESSOS PARA A PREPARAçãO DE COMPOSIçõES HERBICIDAMENTE ATIVAS, PARA CONTROLAR VEGETAçãO INDESEJADA E PARA A PREPARAçãO DE BENZILIDENOPIRAZOLONAS, E, BENZOILPIRAZOL". Benzilidenopirazolonas de fórmula (I): em que os substituintes e o índice n têm os seguintes significados: R¹ é C~ 1~-C~ 6~-alquila opcionalmente substituído; R² é C~ 1~-C~ 6~-alquila opcionalmente substituído, C~ 1~-C~ 6~-alcóxi opcionalmente substituído, halogênio, nitro, ciano; R³ é hidrogênio, halogênio, nitro, ciano, um grupo NR^ 5^R^ 6^, OCOR^ 5^, NR^ 5^COR^ 6^, CO~ 2~R^ 5^, -COSR^ 5^, -CONR^ 5^R^ 6^, C~ 1~-C~ 4~-alcoxiiminoalquila, C~ 1~-C~ 6~-alquilcarbonila, C~ 1~-C~ 6~-alquila opcionalmente substituído, C~ 1~-C~ 6~-alcóxi opcionalmente substituído, C~ 1~-C~ 6~-alquiltio opcionalmente substituído, C~ 2~-C~ 6~-alquenila opcionalmente substituído, C~ 2~-C~ 6~-alquinila opcionalmente substituído, fenila opcionalmente substituído, fenóxi opcionalmente substituído, um heterociclo saturado ou insaturado com 5 ou 6 membros, opcionalmente substituído, que pode conter até 4 átomos de nitrogênio e/ou até 2 átomos de oxigênio ou de enxofre como membros do anel; R^ 4^ é C~ 1~-C~ 6~-alquila, C~ 1~-C~ 4~-haloalquila; ou R³, R^ 4^ formam uma ponte opcionalmente substituída, saturada ou insaturada, com 2 ou 3 membros, que pode conter um átomo de enxofre que pode ser oxidado ao sulfóxido ou sulfona; R^ 5^ é hidrogênio ou C~ 1~-C~ 6~-alquila opcionalmente substituído; R^ 6^ é C~ 1~-C~ 6~-alquila opcionalmente substituído; R^ 7^ é hidrogênio, C~ 1~-C~ 6~-alquila ou C~ 1~-C~ 4~-haloalquila; n é 0, 1 ou 2; X é hidrogênio, cloro ou bromo; sendo que os compostos reivindicados podem estar presentes tanto na forma trans como também na forma cis, ou como uma mistura destes isómeros.
BR9814232-1A 1997-11-21 1998-11-06 Benzilidenopirazolona, composição, processos para a preparação de composições herbicidamente ativas, para controlar vegetação indesejada e para a preparação de benzilidenopirazolonas, e, benzoilpirazol. BR9814232A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19751722 1997-11-21
PCT/EP1998/007099 WO1999026930A2 (de) 1997-11-21 1998-11-06 Benzylidenpyrazolone als herbizide

Publications (1)

Publication Number Publication Date
BR9814232A true BR9814232A (pt) 2000-10-03

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Family Applications (1)

Application Number Title Priority Date Filing Date
BR9814232-1A BR9814232A (pt) 1997-11-21 1998-11-06 Benzilidenopirazolona, composição, processos para a preparação de composições herbicidamente ativas, para controlar vegetação indesejada e para a preparação de benzilidenopirazolonas, e, benzoilpirazol.

Country Status (18)

Country Link
US (2) US6271179B1 (pt)
EP (1) EP1044191A2 (pt)
JP (1) JP2001524471A (pt)
KR (1) KR20010032321A (pt)
CN (1) CN1283191A (pt)
AR (1) AR013776A1 (pt)
AU (1) AU757752C (pt)
BG (1) BG104471A (pt)
BR (1) BR9814232A (pt)
CA (1) CA2310087A1 (pt)
EA (1) EA200000560A1 (pt)
HU (1) HUP0100011A3 (pt)
IL (1) IL136111A0 (pt)
NZ (1) NZ505142A (pt)
PL (1) PL341679A1 (pt)
SK (1) SK6952000A3 (pt)
WO (1) WO1999026930A2 (pt)
ZA (1) ZA9810625B (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6514910B1 (en) * 1999-03-05 2003-02-04 Basf Aktiengesellschaft Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative and an adjuvant
EP1242412A2 (de) * 1999-12-02 2002-09-25 Basf Aktiengesellschaft 3-(4,5-dihydroisoxazol-3-yl)-substituierte benzoylpyrazole als herbizide
DE50014393D1 (de) 1999-12-02 2007-07-19 Basf Ag Cyclopropyl-anellierte 3-(4,5-dihydroisoxazol-3-yl)-substituierte benzoylpyrazole als herbizide
US6465395B2 (en) 2000-03-01 2002-10-15 Basf Aktiengesellschaft Substituted methylene pyrazolinones and the herbicidal use thereof
WO2006106954A1 (ja) * 2005-03-31 2006-10-12 Ishihara Sangyo Kaisha, Ltd. ベンゾイルピラゾール系化合物、それらの製造方法及びそれらを含有する除草剤
US20100331315A1 (en) * 2009-06-18 2010-12-30 Mustapha Haddach Rhodanines and related heterocycles as kinase inhibitors
CN102408428B (zh) * 2011-07-26 2014-01-15 中国农业大学 1,2-氮杂环辛烷并吡唑烷酮类化合物及其制备方法与应用
JP2017075161A (ja) * 2015-11-26 2017-04-20 住友化学株式会社 有害生物防除組成物およびその用途
EP3424905B1 (en) 2016-02-29 2021-08-04 Sumitomo Chemical Company, Limited Heterocyclic compound

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5436648B2 (pt) * 1974-03-28 1979-11-10
US4382948A (en) * 1982-03-25 1983-05-10 Chevron Research Company 1,3,4-Trisubstituted-2-pyrazolin-5-one fungicides
JPS5955872A (ja) * 1982-09-22 1984-03-31 Otsuka Chem Co Ltd 4,4−(α−メチルベンジリデン)−2−ピラゾ−ル−5−オン誘導体
JPS61268670A (ja) * 1985-05-22 1986-11-28 Hodogaya Chem Co Ltd ピラゾ−ル系化合物およびこれを含有する除草剤
US4885022A (en) 1987-03-17 1989-12-05 Nissan Chemical Industries Ltd. Herbicidal pyrazole derivatives
IL85659A (en) 1987-03-17 1992-03-29 Nissan Chemical Ind Ltd 4-benzoylpyrazole derivatives,method for their preparation and herbicidal compositions containing them
GB2224208A (en) * 1988-10-20 1990-05-02 Shell Int Research Fungicidal pyrazolyl aryl ketones
JPH0429129A (ja) * 1990-05-24 1992-01-31 Konica Corp ハロゲン化銀写真感光材料
JPH04253039A (ja) * 1991-01-30 1992-09-08 Toshiba Corp 有機非線形光学材料
UA61052C2 (en) 1995-02-24 2003-11-17 Basf Ag Pyrazol-4-yl-benzoyl derivatives and herbicidal agent based thereon

Also Published As

Publication number Publication date
AU757752C (en) 2003-09-11
IL136111A0 (en) 2001-05-20
ZA9810625B (en) 2000-05-22
AU757752B2 (en) 2003-03-06
HUP0100011A2 (hu) 2001-05-28
AU1667099A (en) 1999-06-15
WO1999026930A2 (de) 1999-06-03
CN1283191A (zh) 2001-02-07
CA2310087A1 (en) 1999-06-03
JP2001524471A (ja) 2001-12-04
WO1999026930A3 (de) 1999-08-19
BG104471A (en) 2001-08-31
EA200000560A1 (ru) 2000-12-25
KR20010032321A (ko) 2001-04-16
PL341679A1 (en) 2001-04-23
EP1044191A2 (de) 2000-10-18
HUP0100011A3 (en) 2003-03-28
US6271179B1 (en) 2001-08-07
NZ505142A (en) 2003-03-28
AR013776A1 (es) 2001-01-10
SK6952000A3 (en) 2001-02-12
US6500950B1 (en) 2002-12-31

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