BR9807723A - Sìlica géis modificadas por organossilicato hidrofóbico - Google Patents
Sìlica géis modificadas por organossilicato hidrofóbicoInfo
- Publication number
- BR9807723A BR9807723A BR9807723-6A BR9807723A BR9807723A BR 9807723 A BR9807723 A BR 9807723A BR 9807723 A BR9807723 A BR 9807723A BR 9807723 A BR9807723 A BR 9807723A
- Authority
- BR
- Brazil
- Prior art keywords
- modified
- organosilicate
- silica
- hydrophobic
- hydrogel
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/16—Preparation of silica xerogels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicon Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
Patente de Invenção:<B>"SìLICA GéIS MODIFICADAS POR ORGANOSSILICATO HIDROFóBICO"<D>. A presente invenção refere-se à sílica géis modificadas por organossilicatos hidrofóbicos e a método para sua preparação. O método compreende duas etapas, onde na primeira etapa para sílica hidrossol modificada por organossilicato é tratada termicamente na presença de um ácido mineral forte sob um pH menor que pH 1, para formar uma sílica hidrogel modificada por organossilicato. Na segunda etapa, a sílica hidrogel modificada por organossilicato é contactada com um composto de organossilício na presença de uma quantidade catalítica de um ácido forte para realizar operação de hidrofobia da sílica hidrogel modificada por organossilicato, desse modo formando uma sílica hidrogel modificada por organossilicato hidrofóbico a qual tem uma área superficial em uma faixa de 100 m²/g a 750 m²/g como medida no estado seco. Em um método preferido, a sílica gel modificada por organossilicato hidrofóbico é contactada com uma quantidade suficiente de um solvente orgânico imiscível em água para converter a sílica hidrogel modificada por organossilicato hidrofóbico em uma sílica organogel modificada por organossilicato hidrofóbico.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/805,102 US5750610A (en) | 1997-02-24 | 1997-02-24 | Hydrophobic organosilicate-modified silica gels |
PCT/US1998/003123 WO1998037015A1 (en) | 1997-02-24 | 1998-02-18 | Hydrophobic organosilicate-modified silica gels |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9807723A true BR9807723A (pt) | 2000-02-15 |
Family
ID=25190678
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9807723-6A BR9807723A (pt) | 1997-02-24 | 1998-02-18 | Sìlica géis modificadas por organossilicato hidrofóbico |
Country Status (12)
Country | Link |
---|---|
US (1) | US5750610A (pt) |
EP (1) | EP0963344B1 (pt) |
JP (1) | JP3319763B2 (pt) |
KR (1) | KR100503529B1 (pt) |
CN (1) | CN1248225A (pt) |
AU (1) | AU6280998A (pt) |
BR (1) | BR9807723A (pt) |
CA (1) | CA2279296C (pt) |
DE (1) | DE69823173T2 (pt) |
MY (1) | MY133856A (pt) |
TW (1) | TW381065B (pt) |
WO (1) | WO1998037015A1 (pt) |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19648798C2 (de) * | 1996-11-26 | 1998-11-19 | Hoechst Ag | Verfahren zur Herstellung von organisch modifizierten Aerogelen durch Oberflächenmodifikation des wäßrigen Gels (ohne vorherigen Lösungsmitteltausch) und anschließender Trocknung |
DE19718740A1 (de) | 1997-05-02 | 1998-11-05 | Hoechst Ag | Verfahren zur Granulierung von Aerogelen |
DE19718741A1 (de) | 1997-05-02 | 1998-11-05 | Hoechst Ag | Verfahren zur Kompaktierung von Aerogelen |
DE19756633A1 (de) | 1997-12-19 | 1999-06-24 | Hoechst Ag | Verfahren zur unterkritischen Trocknung von Lyogelen zu Aerogelen |
DE19801004A1 (de) * | 1998-01-14 | 1999-07-15 | Cabot Corp | Verfahren zur Herstellung von im wesentlichen kugelförmigen Lyogelen in wasserunlöslichen Silylierungsmitteln |
AU753228B2 (en) * | 1998-02-09 | 2002-10-10 | Industrial Science & Technology Network, Inc. | Ion separation using a surface-treated xerogel |
EP1089872A1 (en) * | 1998-05-21 | 2001-04-11 | Bio-Seal Ltd. | Multi-action particle for structuring biological media |
DE59811774D1 (de) * | 1998-06-05 | 2004-09-09 | Cabot Corp | Nanoporöse interpenetrierende organisch-anorganische netzwerke |
US6210570B1 (en) | 1998-08-21 | 2001-04-03 | Agilent Technologies, Inc. | Monolithic silica column |
US6013187A (en) * | 1998-08-31 | 2000-01-11 | Dow Corning Corporation | Method for removing metal contaminants from solution using mercapto-functional silica xerogels |
US6184408B1 (en) | 1999-04-28 | 2001-02-06 | Dow Corning Corporation | Method for preparation of hydrophobic precipitated silica |
EP1103524A3 (en) * | 1999-11-29 | 2002-07-31 | Matsushita Electric Industrial Co., Ltd. | Method of drying wet silica gel |
US6573324B1 (en) * | 2000-04-04 | 2003-06-03 | The Goodyear Tire & Rubber Company | Tire with component comprised of rubber composition containing pre-hydrophobated silica aggregates |
KR100797202B1 (ko) * | 2000-06-23 | 2008-01-23 | 허니웰 인터내셔널 인코포레이티드 | 손상된 실리카 유전 필름에 소수성을 부여하는 방법 및 손상된 실리카 유전 필름 처리 방법 |
US6528592B1 (en) | 2000-09-14 | 2003-03-04 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition which contains non-silane coupling agent and article of manufacture, including a tire, having at least one component comprised of such rubber composition |
US6458882B1 (en) | 2000-09-14 | 2002-10-01 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition which contains non-silane coupling agent and article of manufacture, including a tire, having at least one component comprised of such rubber composition |
US6555609B1 (en) | 2000-09-14 | 2003-04-29 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition which contains thioglycerol coupling agent and benzothiazyl disulfide and article of manufacture, including a tire, having at least one component comprised of such rubber composition |
US6713549B1 (en) | 2000-09-14 | 2004-03-30 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition prepared with pre-treated silica article of manufacture, including a tire, having at least one component comprised of such rubber composition |
EP1199336B1 (de) * | 2000-10-21 | 2014-01-15 | Evonik Degussa GmbH | Funktionalisierte, strukturmodifizierte Kieselsäuren |
US6534584B2 (en) | 2001-01-08 | 2003-03-18 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition which contains carbon black supported thioglycerol coupling agent and article of manufacture, including a tire, having at least one component comprised of such rubber composition |
US6465581B1 (en) | 2001-01-24 | 2002-10-15 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition which contains stabilized unsymmetrical coupling agents and article of manufacture, including a tire, having at least one component comprised of such rubber composition |
US6525128B2 (en) | 2001-02-01 | 2003-02-25 | The Goodyear Tire & Rubber Company | Composition of organophosphite, isobutylene copolymer and silica and tire thereof |
US6515063B2 (en) | 2001-02-01 | 2003-02-04 | The Goodyear Tire & Rubber Company | Tire having colored tread |
US6561243B2 (en) | 2001-02-01 | 2003-05-13 | The Goodyear Tire & Rubber Company | Tire having tread with colored sidewall in connection with a plurality of colored tread grooves |
US6583210B2 (en) | 2001-02-01 | 2003-06-24 | The Goodyear Tire & Rubber Company | Tire having tread with co-extruded non-black colored overlay |
US6561244B2 (en) | 2001-02-01 | 2003-05-13 | The Goodyear Tire & Rubber Company | Tire having tread with colored groove configuration |
US6476115B1 (en) | 2001-08-31 | 2002-11-05 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition which contains oleylammonium bromide and/or mercaptoimidazolium bromide coupling agents to enhance electrical conductivity and article of manufacture, including a tire, having at least one component comprised of such rubber composition |
US20030096900A1 (en) * | 2001-11-16 | 2003-05-22 | Holden Brian David | Organic plant derived precipitated silica aggregates, elastomers reinforced therewith and articles such as tires with component thereof |
FR2849444B1 (fr) * | 2002-12-30 | 2006-07-28 | Rhodia Chimie Sa | Procede de preparation d'un suspension de silice dans une matiere silicone eventuellement reticulable |
FR2849441B1 (fr) * | 2002-12-30 | 2006-07-28 | Rhodia Chimie Sa | Procede de preparation d'une suspension de silice dans une matiere silicone eventuellement reticulable |
US7709371B2 (en) * | 2003-01-25 | 2010-05-04 | Honeywell International Inc. | Repairing damage to low-k dielectric materials using silylating agents |
WO2004068555A2 (en) * | 2003-01-25 | 2004-08-12 | Honeywell International Inc | Repair and restoration of damaged dielectric materials and films |
US7214731B2 (en) * | 2003-03-17 | 2007-05-08 | The Goodyear Tire & Rubber Company | Tire with low hydrocarbon emission rubber combination of tread and sidewall components with compositional limitations |
US20050009955A1 (en) * | 2003-06-25 | 2005-01-13 | Cohen Martin Paul | Composite of silica reacted with blocked mercaptoalkoxysilane and alkyl silane, rubber composition with said composite, and article having component thereof |
US8475666B2 (en) * | 2004-09-15 | 2013-07-02 | Honeywell International Inc. | Method for making toughening agent materials |
DE102004029069A1 (de) * | 2004-06-16 | 2005-12-29 | Degussa Ag | Oberflächenmodifizierte Silicagele |
US7262254B2 (en) * | 2004-09-23 | 2007-08-28 | The Goodyear Tire & Rubber Company | Tire with low volatile alcohol emission rubber tread with compositional limitations |
US7678712B2 (en) * | 2005-03-22 | 2010-03-16 | Honeywell International, Inc. | Vapor phase treatment of dielectric materials |
EP1871824B1 (en) | 2005-03-24 | 2017-03-01 | Bridgestone Corporation | Compounding silica-reinforced rubber with low volatile organic compound (voc) emission |
DE602006000607T2 (de) | 2005-04-11 | 2009-04-02 | The Goodyear Tire & Rubber Co., Akron | Luftreifen enthaltend mit fluoriniertem Silan vorbehandeltes Silicagel |
US7507480B2 (en) * | 2005-05-31 | 2009-03-24 | Brookhaven Science Associates, Llc | Corrosion-resistant metal surfaces |
US8501895B2 (en) * | 2007-05-23 | 2013-08-06 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes |
US7915368B2 (en) * | 2007-05-23 | 2011-03-29 | Bridgestone Corporation | Method for making alkoxy-modified silsesquioxanes |
US20090026924A1 (en) * | 2007-07-23 | 2009-01-29 | Leung Roger Y | Methods of making low-refractive index and/or low-k organosilicate coatings |
KR100910256B1 (ko) | 2007-12-24 | 2009-07-31 | 금호석유화학 주식회사 | 유기화 실리카가 충진된 타이어용 유기실리카 마스터 배치탄성체 및 이의 제조방법 |
US8962746B2 (en) * | 2007-12-27 | 2015-02-24 | Bridgestone Corporation | Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds |
US8794282B2 (en) | 2007-12-31 | 2014-08-05 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
US8513371B2 (en) * | 2007-12-31 | 2013-08-20 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxanes and method of preparation |
US8642691B2 (en) | 2009-12-28 | 2014-02-04 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber |
CN102958990B (zh) | 2010-09-13 | 2014-01-29 | 横滨橡胶株式会社 | 轮胎用橡胶组合物和充气轮胎 |
KR101240602B1 (ko) | 2010-12-24 | 2013-03-06 | 금호석유화학 주식회사 | 유기 실리카 함유 마스터 배치 탄성체 및 그 제조방법 |
WO2016109625A1 (en) | 2014-12-31 | 2016-07-07 | Bridgestone Corporation | Amino alkoxy-modified silsesquioxane adhesives for adhering steel alloy to rubber |
EP3418255A4 (en) * | 2016-02-15 | 2019-02-27 | Panasonic Intellectual Property Management Co., Ltd. | Water-repellent treatment method and method for producing a leaf-shaped element therewith |
KR102230854B1 (ko) | 2018-10-02 | 2021-03-24 | 금호석유화학 주식회사 | 유기 실리카 함유 마스터 배치 탄성체 조성물 |
US11441019B2 (en) | 2019-06-21 | 2022-09-13 | The Goodyear Tire & Rubber Company | Ply coat rubber composition and a tire comprising a ply coat rubber composition |
US11459447B2 (en) | 2019-06-21 | 2022-10-04 | The Goodyear Tire & Rubber Company | Wire coat rubber composition for a tire and a tire comprising a wire coat rubber composition |
EP3835350A3 (en) | 2019-12-12 | 2021-07-14 | The Goodyear Tire & Rubber Company | A rubber composition and a tire |
Family Cites Families (11)
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US3015645A (en) * | 1954-10-06 | 1962-01-02 | Dow Corning | Silica powders |
GB783868A (en) * | 1954-10-06 | 1957-10-02 | Midland Silicones Ltd | A process of preparing hydrophobic organo-silicon powders |
US2892797A (en) * | 1956-02-17 | 1959-06-30 | Du Pont | Process for modifying the properties of a silica sol and product thereof |
US3122520A (en) * | 1959-10-05 | 1964-02-25 | Dow Corning | Method of making silicone rubber fillers |
US3024126A (en) * | 1960-06-15 | 1962-03-06 | Dow Corning | Method of treating reinforcing silica |
SU369131A1 (pt) * | 1969-11-12 | 1973-02-08 | ||
DE1963439A1 (de) * | 1969-12-18 | 1971-06-24 | Dynamit Nobel Ag | Verfahren zur Herstellung poroeser Kieselsaeure |
US4006175A (en) * | 1969-12-18 | 1977-02-01 | Dynamit Nobel Aktiengesellschaft | Porous silicic acid and its production |
DE2015402A1 (de) * | 1970-04-01 | 1971-10-21 | Bayer | Verfahren zur Verbesserung des Vulkani sationsverhaltens und zur Hitzestabili sierung von Polyorganosiloxanelastomeren |
US3979546A (en) * | 1971-12-30 | 1976-09-07 | Sws Silicones Corporation | Alkoxysiloxanol modified surfaces |
DE3005137A1 (de) * | 1980-02-12 | 1981-08-20 | Degussa Ag, 6000 Frankfurt | Cerhaltige faellungskieselsaeure, verfahren zu deren herstellung, sowie zu elastomeren haertbare massen, die die cerhaltige faellungskieselsaeure enthalten |
-
1997
- 1997-02-24 US US08/805,102 patent/US5750610A/en not_active Expired - Lifetime
-
1998
- 1998-02-18 BR BR9807723-6A patent/BR9807723A/pt unknown
- 1998-02-18 AU AU62809/98A patent/AU6280998A/en not_active Abandoned
- 1998-02-18 WO PCT/US1998/003123 patent/WO1998037015A1/en active IP Right Grant
- 1998-02-18 DE DE69823173T patent/DE69823173T2/de not_active Expired - Lifetime
- 1998-02-18 EP EP98905111A patent/EP0963344B1/en not_active Expired - Lifetime
- 1998-02-18 CN CN98802754A patent/CN1248225A/zh active Pending
- 1998-02-18 JP JP53682898A patent/JP3319763B2/ja not_active Expired - Lifetime
- 1998-02-18 KR KR10-1999-7007675A patent/KR100503529B1/ko not_active IP Right Cessation
- 1998-02-18 CA CA002279296A patent/CA2279296C/en not_active Expired - Lifetime
- 1998-02-19 MY MYPI98000702A patent/MY133856A/en unknown
- 1998-02-20 TW TW087102454A patent/TW381065B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE69823173T2 (de) | 2004-11-11 |
CN1248225A (zh) | 2000-03-22 |
AU6280998A (en) | 1998-09-09 |
MY133856A (en) | 2007-11-30 |
DE69823173D1 (de) | 2004-05-19 |
CA2279296C (en) | 2007-10-30 |
KR100503529B1 (ko) | 2005-07-25 |
EP0963344A1 (en) | 1999-12-15 |
CA2279296A1 (en) | 1998-08-27 |
JP2000512972A (ja) | 2000-10-03 |
JP3319763B2 (ja) | 2002-09-03 |
EP0963344B1 (en) | 2004-04-14 |
TW381065B (en) | 2000-02-01 |
WO1998037015A1 (en) | 1998-08-27 |
US5750610A (en) | 1998-05-12 |
KR20000075614A (ko) | 2000-12-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |