BR9705451A - Processo para a preparação de trietileno-diamina usando catalisadores de zeolito desativados de acidez em superfìcie. - Google Patents
Processo para a preparação de trietileno-diamina usando catalisadores de zeolito desativados de acidez em superfìcie.Info
- Publication number
- BR9705451A BR9705451A BR9705451-8A BR9705451A BR9705451A BR 9705451 A BR9705451 A BR 9705451A BR 9705451 A BR9705451 A BR 9705451A BR 9705451 A BR9705451 A BR 9705451A
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- triethylene diamine
- zeolite catalysts
- deactivated zeolite
- amine
- Prior art date
Links
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 title abstract 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 229940031098 ethanolamine Drugs 0.000 abstract 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/08—Bridged systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Processo para a preparação de trietileno-diamina pela passagem de etanol-amina, etileno-amina, piperazina ou morfolina sobre um zeolito do tipo de pentasil em temperatura elevada, caracterizado pelo emprego de um zeolito de ZSM-5 na forma de hidrogênio ou amónio que foi previamente tratado com solução aquosa de um agente de quelação capaz de formar um complexo de quelato-alumínio.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/751,143 US5741906A (en) | 1996-11-15 | 1996-11-15 | Production of triethylenediamine using surface acidity deactivated zeolite catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9705451A true BR9705451A (pt) | 2000-04-11 |
Family
ID=25020678
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9705451-8A BR9705451A (pt) | 1996-11-15 | 1997-11-10 | Processo para a preparação de trietileno-diamina usando catalisadores de zeolito desativados de acidez em superfìcie. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5741906A (pt) |
EP (1) | EP0842936B1 (pt) |
JP (1) | JP3182383B2 (pt) |
KR (1) | KR100286403B1 (pt) |
CN (1) | CN1057529C (pt) |
BR (1) | BR9705451A (pt) |
DE (1) | DE69705805T2 (pt) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6084096A (en) * | 1998-04-09 | 2000-07-04 | Air Products And Chemicals, Inc. | Triethylenediamine and piperazine synthesis using zeolite catalysts modified with a silicon-containing compound |
DE19930736C2 (de) | 1999-07-05 | 2001-07-05 | Performance Chemicals Handels | Verfahren zur Herstellung von Triethylendiamin unter Einsatz von Ethylendiamin |
EP1070717B1 (de) * | 1999-07-23 | 2002-02-27 | Basf Aktiengesellschaft | Verfahren zur Herstellung von reinem Triethylendiamin |
JP4496633B2 (ja) * | 2000-09-29 | 2010-07-07 | 東ソー株式会社 | トリエチレンジアミン製造用成形体触媒とその製造法及びトリエチレンジアミンの製造方法 |
DE10061863A1 (de) * | 2000-12-12 | 2002-06-13 | Basf Ag | Verfahren zur Herstellung von Triethylendiamin (TEDA) |
DE10100943A1 (de) | 2001-01-10 | 2002-07-11 | Basf Ag | Verfahren zur Herstellung von reinem Triethylendiamin(TEDA) |
DE10122502A1 (de) | 2001-05-10 | 2002-11-14 | Basf Ag | Aufarbeitung der bei der Herstellung von hochreinem Triethylendiamin anfallenden Mutterlauge |
DE10132499A1 (de) * | 2001-07-05 | 2003-01-23 | Basf Ag | Verfahren zur selektiven Synthese von Triethylendiamin |
DE10303696A1 (de) * | 2003-01-30 | 2004-08-12 | Basf Ag | Entfärbung und Farbstabilisierung von TEDA-Lösung |
DE10326137A1 (de) * | 2003-06-06 | 2004-12-23 | Basf Ag | Verfahren zur Erhöhung der Schneidhärte eines Formkörpers enthaltend ein kristallines Alumosilikat und Verwendung dieser Formkörper mit erhöhter Schneidhärte in chemischen Syntheseverfahren, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) durch Umsetzung von Ethylendiamin (EDA) und/oder Piperazin (PIP) |
WO2005051324A2 (en) * | 2003-11-25 | 2005-06-09 | 3M Innovative Properties Company | Hydroxylamine and oxime substituted imidazoquinolines, imidazopyridines, and imidazonaphthyridines |
DE10356184A1 (de) * | 2003-12-02 | 2005-07-07 | Basf Ag | Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung |
DE102004024274A1 (de) * | 2004-05-15 | 2005-12-01 | Basf Ag | Verfahren zur Herstellung einer Lösung von reinem Triethylendiamin (TEDA) |
DE102004029544A1 (de) * | 2004-06-18 | 2006-01-05 | Basf Ag | Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) |
DE102009027791B4 (de) | 2009-07-17 | 2013-02-21 | Basf Se | Zusammensetzung enthaltend Triethylendiamin, Monethylenglykol und Borhydrid |
CN103819381B (zh) | 2013-12-18 | 2015-05-13 | 西安近代化学研究所 | 氮丙啶、哌嗪和三乙烯二胺的联合生产方法及装置 |
CZ2018302A3 (cs) * | 2018-06-22 | 2020-01-15 | Unipetrol výzkumně vzdělávací centrum, a.s. | Způsob výroby tvarovaného katalyzátoru s dealuminovaným zeolitem ZSM-5 |
CN108912120B (zh) * | 2018-07-18 | 2021-01-05 | 西安近代化学研究所 | 一种三乙烯二胺联产n-氨乙基哌嗪的制备方法 |
CN112694102B (zh) * | 2019-10-23 | 2023-07-04 | 中国石油化工股份有限公司 | 酸处理分子筛的方法 |
WO2023126846A2 (en) * | 2021-12-30 | 2023-07-06 | Ptt Global Chemical Public Company Limited | Catalyst for cumene hydroperoxide decomposition and process for preparation thereof |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3442795A (en) * | 1963-02-27 | 1969-05-06 | Mobil Oil Corp | Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom |
US3443795A (en) * | 1967-08-15 | 1969-05-13 | Gen Electric | Beater ejector for food mixer |
JPS5337876B2 (pt) * | 1973-07-19 | 1978-10-12 | ||
US4388177A (en) * | 1981-01-13 | 1983-06-14 | Mobil Oil Corporation | Preparation of natural ferrierite hydrocracking catalyst and hydrocarbon conversion with catalyst |
JPS60260574A (ja) * | 1984-04-10 | 1985-12-23 | ユニオン・カ−バイド・コ−ポレ−シヨン | 1−アザビシクロ〔2.2.2〕オクタン又は1,4−ジアザビシクロ〔2.2.2〕オクタンの合成 |
US4701431A (en) * | 1984-12-24 | 1987-10-20 | Exxon Research And Engineering Company | Rare earth stabilized aluminum deficient zeolite |
WO1987003592A1 (en) * | 1985-12-05 | 1987-06-18 | Idemitsu Kosan Company Limited | Process for producing triethylenediamines |
US4918233A (en) * | 1986-07-08 | 1990-04-17 | Air Products And Chemicals, Inc. | Production of ethylenediamine from monoethanolamine and ammonia |
US4804758A (en) * | 1986-10-08 | 1989-02-14 | Basf Aktiengesellschaft | Preparation of 1,4-diazabicyclo[2.2.2]octanes |
JPH0633266B2 (ja) * | 1986-11-10 | 1994-05-02 | 出光興産株式会社 | トリエチレンジアミン類の製造方法 |
DE3715753A1 (de) * | 1987-05-12 | 1988-11-24 | Basf Ag | Verfahren zur herstellung von 1,4-diazabicyclo(2,2,2)-octanen |
US4814303A (en) * | 1987-09-25 | 1989-03-21 | E. I. Du Pont De Nemours And Company | Anorthite-cordierite based ceramics from zeolites |
DE3735214A1 (de) * | 1987-10-17 | 1989-04-27 | Huels Chemische Werke Ag | Verfahren zur herstellung von 1,4-diazabicyclo(2.2.2)-octan aus piperazin |
DE3735212A1 (de) * | 1987-10-17 | 1989-04-27 | Huels Chemische Werke Ag | Verfahren zur herstellung von gemischen aus 1,4-diazabicyclo(2.2.2)-octan und piperazin |
DE3903622A1 (de) * | 1989-02-08 | 1990-08-09 | Basf Ag | Verfahren zur herstellung von 1,4-diazabicyclo-2,2,2-octan |
DE3934459A1 (de) * | 1989-10-14 | 1991-04-18 | Bayer Ag | Verfahren zur herstellung von triethylendiamin und piperazin |
US5242676A (en) * | 1992-05-11 | 1993-09-07 | Mobil Oil Corp. | Selective surface dealumination of zeolites using dicarboxylic acid |
US5304695A (en) * | 1993-02-22 | 1994-04-19 | Mobil Oil Corporation | Double bond isomerization of olefin-containing feeds with minimal oligomerization using permanently surface acidity deactivated zeolite catalysts |
US5567666A (en) * | 1995-05-15 | 1996-10-22 | Mobil Oil Corporation | Selectivated zeolite catalyst treated with a dealuminizing agent |
FR3020374B1 (fr) * | 2014-04-29 | 2017-10-27 | Axens | Procede de production d'essence comprenant une etape d'isomerisation suivie d'au moins deux etapes de separation. |
-
1996
- 1996-11-15 US US08/751,143 patent/US5741906A/en not_active Expired - Fee Related
-
1997
- 1997-11-10 BR BR9705451-8A patent/BR9705451A/pt not_active Application Discontinuation
- 1997-11-12 KR KR1019970059384A patent/KR100286403B1/ko not_active IP Right Cessation
- 1997-11-13 EP EP97119906A patent/EP0842936B1/en not_active Expired - Lifetime
- 1997-11-13 DE DE69705805T patent/DE69705805T2/de not_active Expired - Fee Related
- 1997-11-14 JP JP31303297A patent/JP3182383B2/ja not_active Expired - Fee Related
- 1997-11-14 CN CN97123116A patent/CN1057529C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69705805D1 (de) | 2001-08-30 |
JP3182383B2 (ja) | 2001-07-03 |
KR100286403B1 (ko) | 2001-05-02 |
KR19980042304A (ko) | 1998-08-17 |
JPH10182562A (ja) | 1998-07-07 |
EP0842936B1 (en) | 2001-07-25 |
CN1057529C (zh) | 2000-10-18 |
MX9708790A (es) | 1998-08-30 |
MX201564B (pt) | 2001-04-26 |
US5741906A (en) | 1998-04-21 |
CN1182744A (zh) | 1998-05-27 |
EP0842936A1 (en) | 1998-05-20 |
DE69705805T2 (de) | 2001-12-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PRESENTE PEDIDO DE PATENTE DE ACORDO COM ART. 36O DA LPI |