BR9608899A - Processo e o aparelho para redução do conteúdo de nox de um gás de combustão - Google Patents

Processo e o aparelho para redução do conteúdo de nox de um gás de combustão

Info

Publication number
BR9608899A
BR9608899A BR9608899-0A BR9608899A BR9608899A BR 9608899 A BR9608899 A BR 9608899A BR 9608899 A BR9608899 A BR 9608899A BR 9608899 A BR9608899 A BR 9608899A
Authority
BR
Brazil
Prior art keywords
flue gas
gas
liquid
phosphorus
oxidation
Prior art date
Application number
BR9608899-0A
Other languages
English (en)
Inventor
Thomas V Hinke
Rob Triebe
Joseph Hinke
Original Assignee
Thermal Energy Int Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thermal Energy Int Inc filed Critical Thermal Energy Int Inc
Publication of BR9608899A publication Critical patent/BR9608899A/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/346Controlling the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/343Heat recovery
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/50Intercepting solids by cleaning fluids (washers or scrubbers)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/40Sorption with wet devices, e.g. scrubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/10Capture or disposal of greenhouse gases of nitrous oxide (N2O)

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Chimneys And Flues (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Cleaning In General (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

''PROCESSO E O APARELHO PARA REDUçãO DO CONTEúDO DE NO~ x~ DE UM GáS DE COMBUSTãO'', onde uma emulsão de P~ 4~ em água líquido/líquido é injetada no gás de combustão para induzir oxidação acelerada por fósforo de NO no gás de combustão. óxidos de fósforo e NO~ 2~ são subsequentemente removidos da corrente de gás de combustão em uma localização suficientemente corrente abaixo da localização de injeção para que a oxidação de NO no gás de combustão seja substancialmente finalizada antes da remoção de NO~ 2~. Isto melhora significativamente o grau de recuperação de NO~ x ~ do presente sistema e método, em relação aos da anterioridade. O sistema pode ser retro-encaixado à corrente de gás desperdiçado de qualquer fonte de combustão estacionária, independentemente do combustível queimado. O sistema é vantajosamante utilizado em conjunto com um purificador a úmido para remoção de NO~ 2~ e outros componentes de gás de combustão em água. A injeção da emulsão resulta na formação de ozónio por meio de oxidação controlada de fósforo branco. O ozónio reage com óxido de nitrogênio (NO), o qual geralmente é responsável por 90% de NO~ x~ de gás de combustão, produzindo dióxido de nitrogênio. Os produtos da reação (NO~ 2~ e o P~4~O~ 10~) podem ser removidos do gás de combustão juntamente com SO~ 2~ e particulados no purificador a úmido onde são eficazmente transferidos da fase gasosa para o líquido de purificação amortecedor. No purificador, o gradiente da temperatura é preferivelmente estabelecido através do ponto de condensação, para que recupere energia de calor tanto latente quanto sensível do gás de combustão, energia esta a qual pose ser vendida para consumidores residenciais ou comerciais para recuperar pelo menos parte dos custos de capital (compra e operação) associados ao sistema.
BR9608899-0A 1995-05-30 1996-05-29 Processo e o aparelho para redução do conteúdo de nox de um gás de combustão BR9608899A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US45267195A 1995-05-30 1995-05-30
PCT/CA1996/000344 WO1996038218A1 (en) 1995-05-30 1996-05-29 Flue gas scrubbing and waste heat recovery system

Publications (1)

Publication Number Publication Date
BR9608899A true BR9608899A (pt) 1999-12-07

Family

ID=23797428

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9608899-0A BR9608899A (pt) 1995-05-30 1996-05-29 Processo e o aparelho para redução do conteúdo de nox de um gás de combustão

Country Status (27)

Country Link
US (1) US6063348A (pt)
EP (1) EP0828550B1 (pt)
JP (1) JPH11511061A (pt)
KR (1) KR100419314B1 (pt)
CN (1) CN1089623C (pt)
AT (1) ATE190239T1 (pt)
AU (1) AU697034B2 (pt)
BR (1) BR9608899A (pt)
CA (1) CA2220456A1 (pt)
CZ (1) CZ290490B6 (pt)
DE (1) DE69606998T2 (pt)
DK (1) DK0828550T3 (pt)
EA (1) EA000374B1 (pt)
ES (1) ES2146002T3 (pt)
FI (1) FI974330A0 (pt)
GR (1) GR3033623T3 (pt)
HU (1) HU222552B1 (pt)
MX (1) MX9709253A (pt)
NO (1) NO316929B1 (pt)
NZ (1) NZ308045A (pt)
PL (1) PL184600B1 (pt)
PT (1) PT828550E (pt)
RO (1) RO118697B1 (pt)
SK (1) SK282302B6 (pt)
TR (1) TR199701478T1 (pt)
UA (1) UA61885C2 (pt)
WO (1) WO1996038218A1 (pt)

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US7955419B2 (en) * 2007-07-25 2011-06-07 Casella Waste Systems, Inc. System and method for treating landfill gas using landfill leachate
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JP4838870B2 (ja) * 2009-04-28 2011-12-14 三菱重工業株式会社 伝熱管監視装置
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CN105148699B (zh) * 2015-09-02 2018-01-12 北京国电龙源环保工程有限公司 一种单塔氧化脱硫脱硝装置及其脱硫脱硝方法
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Also Published As

Publication number Publication date
WO1996038218A1 (en) 1996-12-05
CN1190907A (zh) 1998-08-19
DK0828550T3 (da) 2000-08-21
NZ308045A (en) 2000-01-28
MX9709253A (es) 1998-10-31
NO316929B1 (no) 2004-06-28
HUP9900070A2 (hu) 1999-05-28
KR19990022115A (ko) 1999-03-25
HU222552B1 (hu) 2003-08-28
SK161797A3 (en) 1998-07-08
EA000374B1 (ru) 1999-06-24
DE69606998T2 (de) 2000-11-02
NO975506L (no) 1997-11-28
HUP9900070A3 (en) 2001-04-28
FI974330A (fi) 1997-11-26
GR3033623T3 (en) 2000-10-31
AU5757396A (en) 1996-12-18
PL184600B1 (pl) 2002-11-29
CA2220456A1 (en) 1996-12-05
DE69606998D1 (de) 2000-04-13
NO975506D0 (no) 1997-11-28
PT828550E (pt) 2000-08-31
RO118697B1 (ro) 2003-09-30
CZ377497A3 (cs) 1998-07-15
ATE190239T1 (de) 2000-03-15
EA199700345A1 (ru) 1998-08-27
JPH11511061A (ja) 1999-09-28
EP0828550B1 (en) 2000-03-08
PL323732A1 (en) 1998-04-14
CZ290490B6 (cs) 2002-08-14
KR100419314B1 (ko) 2004-05-24
ES2146002T3 (es) 2000-07-16
SK282302B6 (sk) 2002-01-07
FI974330A0 (fi) 1997-11-26
EP0828550A1 (en) 1998-03-18
UA61885C2 (en) 2003-12-15
AU697034B2 (en) 1998-09-24
US6063348A (en) 2000-05-16
TR199701478T1 (xx) 1998-03-21
CN1089623C (zh) 2002-08-28

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