BR112019002791A2 - método para converter um álcool inicial - Google Patents
método para converter um álcool inicialInfo
- Publication number
- BR112019002791A2 BR112019002791A2 BR112019002791-2A BR112019002791A BR112019002791A2 BR 112019002791 A2 BR112019002791 A2 BR 112019002791A2 BR 112019002791 A BR112019002791 A BR 112019002791A BR 112019002791 A2 BR112019002791 A2 BR 112019002791A2
- Authority
- BR
- Brazil
- Prior art keywords
- alcohols
- enals
- enones
- linear
- convert
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/02—Reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B33/00—Oxidation in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/04—Dehydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
- C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/86—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
- C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
as modalidades neste documento dizem respeito à conversão ecologicamente correta de álcoois simples em alcenos funcionalizados lineares ou ramificados por catálise integrada. os álcoois são, primeiramente, oxidados quimica ou enzimaticamente aos aldeídos ou cetonas correspondentes, seguidos de condensações aldólicas usando um catalisador para se obter os enais ou enonas correspondentes. os enais ou enonas são hidrogenados subsequente e seletivamente usando um catalizador metálico heterogêneo reciclável, organocatalizador ou uma enzima para prover alcenos funcionalizados lineares ou ramificados com uma funcionalidade de aldeído, ceto ou álcool. o processo também é iterativo e pode adicionalmente ser estendido ao repetir a catálise integrada acima para produzir alcanos funcionalizados de cadeia longa a partir de álcoois simples.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662375805P | 2016-08-16 | 2016-08-16 | |
US62/375,805 | 2016-08-16 | ||
PCT/SE2017/050826 WO2018034609A1 (en) | 2016-08-16 | 2017-08-16 | Conversion of alcohols to linear and branched functionalized alkanes |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112019002791A2 true BR112019002791A2 (pt) | 2019-05-21 |
BR112019002791B1 BR112019002791B1 (pt) | 2022-07-05 |
Family
ID=61197366
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112019002791-2A BR112019002791B1 (pt) | 2016-08-16 | 2017-08-16 | Método para converter álcoois em alcanos lineares e ramificados funcionalizados |
Country Status (14)
Country | Link |
---|---|
US (1) | US10611702B2 (pt) |
EP (1) | EP3500547B1 (pt) |
JP (1) | JP6927533B2 (pt) |
KR (1) | KR102277351B1 (pt) |
CN (1) | CN109563015B (pt) |
AU (1) | AU2017313636B2 (pt) |
BR (1) | BR112019002791B1 (pt) |
CA (1) | CA3032789C (pt) |
MX (1) | MX2019001959A (pt) |
NZ (1) | NZ751399A (pt) |
RU (1) | RU2732124C1 (pt) |
SG (1) | SG11201901309RA (pt) |
WO (1) | WO2018034609A1 (pt) |
ZA (1) | ZA201901628B (pt) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107930647B (zh) * | 2017-12-06 | 2021-03-09 | 万华化学集团股份有限公司 | 一种催化剂、其制备方法以及2-乙基己醛的制备方法 |
US11851392B2 (en) | 2018-11-13 | 2023-12-26 | Eastman Chemical Company | Self-condensation of aldehydes |
WO2023061971A1 (en) | 2021-10-11 | 2023-04-20 | Organofuel Sweden Ab | A new fuel composition comprising a symmetric branched c12-c18 ether, or 3-(((2-ethylhexyl)oxy)methyl)heptane |
CN115304463A (zh) * | 2022-08-11 | 2022-11-08 | 中国农业科学院植物保护研究所 | 一种苹果蠹蛾信息素的制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6825384B1 (en) * | 2004-01-29 | 2004-11-30 | The Nutrasweet Company | Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant |
ES2347576T3 (es) * | 2004-02-26 | 2010-11-02 | Nutrasweet Property Holdings, Inc. | Sistema catalizador para la oxidacion aerobica de alcoholes primarios y secundarios. |
EP2072491A1 (en) * | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain |
US8232433B2 (en) | 2009-08-17 | 2012-07-31 | Kabushiki Kaisha Sangi | Catalyst and alcohol synthesis method |
-
2017
- 2017-08-16 KR KR1020197007111A patent/KR102277351B1/ko active IP Right Grant
- 2017-08-16 WO PCT/SE2017/050826 patent/WO2018034609A1/en active Search and Examination
- 2017-08-16 JP JP2019505216A patent/JP6927533B2/ja active Active
- 2017-08-16 CA CA3032789A patent/CA3032789C/en active Active
- 2017-08-16 CN CN201780050122.3A patent/CN109563015B/zh active Active
- 2017-08-16 BR BR112019002791-2A patent/BR112019002791B1/pt active IP Right Grant
- 2017-08-16 RU RU2019105049A patent/RU2732124C1/ru active
- 2017-08-16 AU AU2017313636A patent/AU2017313636B2/en active Active
- 2017-08-16 US US16/325,676 patent/US10611702B2/en active Active
- 2017-08-16 NZ NZ751399A patent/NZ751399A/en unknown
- 2017-08-16 SG SG11201901309RA patent/SG11201901309RA/en unknown
- 2017-08-16 EP EP17841760.6A patent/EP3500547B1/en active Active
- 2017-08-16 MX MX2019001959A patent/MX2019001959A/es unknown
-
2019
- 2019-03-15 ZA ZA2019/01628A patent/ZA201901628B/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR20190042026A (ko) | 2019-04-23 |
CN109563015B (zh) | 2022-06-24 |
CA3032789A1 (en) | 2018-02-22 |
NZ751399A (en) | 2020-07-31 |
EP3500547A1 (en) | 2019-06-26 |
EP3500547A4 (en) | 2020-01-15 |
JP2019531265A (ja) | 2019-10-31 |
EP3500547B1 (en) | 2023-10-11 |
CN109563015A (zh) | 2019-04-02 |
WO2018034609A1 (en) | 2018-02-22 |
AU2017313636B2 (en) | 2020-07-09 |
MX2019001959A (es) | 2019-09-04 |
US20190210940A1 (en) | 2019-07-11 |
CA3032789C (en) | 2021-07-13 |
AU2017313636A1 (en) | 2019-03-14 |
RU2732124C1 (ru) | 2020-09-11 |
US10611702B2 (en) | 2020-04-07 |
EP3500547C0 (en) | 2023-10-11 |
BR112019002791B1 (pt) | 2022-07-05 |
ZA201901628B (en) | 2021-06-30 |
JP6927533B2 (ja) | 2021-09-01 |
SG11201901309RA (en) | 2019-03-28 |
KR102277351B1 (ko) | 2021-07-13 |
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B350 | Update of information on the portal [chapter 15.35 patent gazette] | ||
B06W | Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/08/2017, OBSERVADAS AS CONDICOES LEGAIS |