BR112019002791A2 - método para converter um álcool inicial - Google Patents

método para converter um álcool inicial

Info

Publication number
BR112019002791A2
BR112019002791A2 BR112019002791-2A BR112019002791A BR112019002791A2 BR 112019002791 A2 BR112019002791 A2 BR 112019002791A2 BR 112019002791 A BR112019002791 A BR 112019002791A BR 112019002791 A2 BR112019002791 A2 BR 112019002791A2
Authority
BR
Brazil
Prior art keywords
alcohols
enals
enones
linear
convert
Prior art date
Application number
BR112019002791-2A
Other languages
English (en)
Other versions
BR112019002791B1 (pt
Inventor
Cordova Armando
Afewerki Samson
Original Assignee
Organofuel Sweden Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Organofuel Sweden Ab filed Critical Organofuel Sweden Ab
Publication of BR112019002791A2 publication Critical patent/BR112019002791A2/pt
Publication of BR112019002791B1 publication Critical patent/BR112019002791B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
    • C07B35/02—Reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B33/00—Oxidation in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
    • C07B35/04—Dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/86—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
    • C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

as modalidades neste documento dizem respeito à conversão ecologicamente correta de álcoois simples em alcenos funcionalizados lineares ou ramificados por catálise integrada. os álcoois são, primeiramente, oxidados quimica ou enzimaticamente aos aldeídos ou cetonas correspondentes, seguidos de condensações aldólicas usando um catalisador para se obter os enais ou enonas correspondentes. os enais ou enonas são hidrogenados subsequente e seletivamente usando um catalizador metálico heterogêneo reciclável, organocatalizador ou uma enzima para prover alcenos funcionalizados lineares ou ramificados com uma funcionalidade de aldeído, ceto ou álcool. o processo também é iterativo e pode adicionalmente ser estendido ao repetir a catálise integrada acima para produzir alcanos funcionalizados de cadeia longa a partir de álcoois simples.
BR112019002791-2A 2016-08-16 2017-08-16 Método para converter álcoois em alcanos lineares e ramificados funcionalizados BR112019002791B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662375805P 2016-08-16 2016-08-16
US62/375,805 2016-08-16
PCT/SE2017/050826 WO2018034609A1 (en) 2016-08-16 2017-08-16 Conversion of alcohols to linear and branched functionalized alkanes

Publications (2)

Publication Number Publication Date
BR112019002791A2 true BR112019002791A2 (pt) 2019-05-21
BR112019002791B1 BR112019002791B1 (pt) 2022-07-05

Family

ID=61197366

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112019002791-2A BR112019002791B1 (pt) 2016-08-16 2017-08-16 Método para converter álcoois em alcanos lineares e ramificados funcionalizados

Country Status (14)

Country Link
US (1) US10611702B2 (pt)
EP (1) EP3500547B1 (pt)
JP (1) JP6927533B2 (pt)
KR (1) KR102277351B1 (pt)
CN (1) CN109563015B (pt)
AU (1) AU2017313636B2 (pt)
BR (1) BR112019002791B1 (pt)
CA (1) CA3032789C (pt)
MX (1) MX2019001959A (pt)
NZ (1) NZ751399A (pt)
RU (1) RU2732124C1 (pt)
SG (1) SG11201901309RA (pt)
WO (1) WO2018034609A1 (pt)
ZA (1) ZA201901628B (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107930647B (zh) * 2017-12-06 2021-03-09 万华化学集团股份有限公司 一种催化剂、其制备方法以及2-乙基己醛的制备方法
US11851392B2 (en) 2018-11-13 2023-12-26 Eastman Chemical Company Self-condensation of aldehydes
WO2023061971A1 (en) 2021-10-11 2023-04-20 Organofuel Sweden Ab A new fuel composition comprising a symmetric branched c12-c18 ether, or 3-(((2-ethylhexyl)oxy)methyl)heptane
CN115304463A (zh) * 2022-08-11 2022-11-08 中国农业科学院植物保护研究所 一种苹果蠹蛾信息素的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6825384B1 (en) * 2004-01-29 2004-11-30 The Nutrasweet Company Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant
ES2347576T3 (es) * 2004-02-26 2010-11-02 Nutrasweet Property Holdings, Inc. Sistema catalizador para la oxidacion aerobica de alcoholes primarios y secundarios.
EP2072491A1 (en) * 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain
US8232433B2 (en) 2009-08-17 2012-07-31 Kabushiki Kaisha Sangi Catalyst and alcohol synthesis method

Also Published As

Publication number Publication date
KR20190042026A (ko) 2019-04-23
CN109563015B (zh) 2022-06-24
CA3032789A1 (en) 2018-02-22
NZ751399A (en) 2020-07-31
EP3500547A1 (en) 2019-06-26
EP3500547A4 (en) 2020-01-15
JP2019531265A (ja) 2019-10-31
EP3500547B1 (en) 2023-10-11
CN109563015A (zh) 2019-04-02
WO2018034609A1 (en) 2018-02-22
AU2017313636B2 (en) 2020-07-09
MX2019001959A (es) 2019-09-04
US20190210940A1 (en) 2019-07-11
CA3032789C (en) 2021-07-13
AU2017313636A1 (en) 2019-03-14
RU2732124C1 (ru) 2020-09-11
US10611702B2 (en) 2020-04-07
EP3500547C0 (en) 2023-10-11
BR112019002791B1 (pt) 2022-07-05
ZA201901628B (en) 2021-06-30
JP6927533B2 (ja) 2021-09-01
SG11201901309RA (en) 2019-03-28
KR102277351B1 (ko) 2021-07-13

Similar Documents

Publication Publication Date Title
BR112019002791A2 (pt) método para converter um álcool inicial
BR112018074904A2 (pt) processo contínuo e de alta seletividade para converter, em etileno glicol, aldo-hexose em um alimento que contém carboidrato que produz aldo-hexose, e, composições produtoras aquosas
AR094464A1 (es) PRODUCCIÓN DE ÁCIDOS w-AMINO GRASOS
MX2018015111A (es) Produccion semi-biosintetica de alcoholes grasos y aldehidos grasos.
DK2159465T3 (da) Trykslange til et vandførende system, især til tilslutning af bevægelige sanitære armaturer eller til forbindelse af dele af det vandførende system
AR080231A1 (es) Soporte basado en fibra de celulosa, metodo para producirlo y uso del soporte
BR112014015584A2 (pt) catalisadores de hidrogenação com suportes modificados com cobalto
BR112014015580A8 (pt) catalisador, catalisador de hidrogenação, processo para produzir etanol e processo de síntese para produzir o catalisador
BR112016026956A2 (pt) método para a produção enzimática de d-eritrose e acetilfosfato".
AR094543A1 (es) Método para producir metacrilato de metilo a partir de propionaldehído y formaldehído mediante esterificación oxidativa
EA200900363A1 (ru) Способ получения фенола посредством новых каталитических систем
BR112016022247A2 (pt) Síntese eficaz de aminas e amidas a partir de álcoois e aldeídos com o uso de catálise em cascata
BR112019023830A2 (pt) processo para preparar metacroleína
MX2018016297A (es) Proceso para la preparacion de aldehidos alfa, beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida.
WO2006115648A3 (en) Diisobutylene process
EA201890877A1 (ru) Способ получения 2-меркаптобензотиазола
BR112015023718A2 (pt) síntese seletiva de acrilato de 2-octila pela esterificação catalisada por ácido de 2-octanol e ácido acrílico
BR112023022205A2 (pt) Processo para converter dirramnolipídeo em monorramnolipídeo
Fan et al. Recent Advances in the Synthesis of Distal Fluorinated Ketones
Ghazali et al. Transesterification of waste cooking oil using chemically treated catalyst
Costescu et al. Compliant solutions for a technological rehabilitation and functional efficiency of an irrigation system
TR201908966A2 (tr) Yekpare si̇fon yapisi
Tok THE RELATION OF MONUMENTSVOCABULARY TO THE TURKIC LANGUAGES
Venkatesan et al. Complete biosynthesis of adipic acid in Saccharomyces cerevisiae
CL2020000548A1 (es) Proceso de producción de xilitol a partir de residuos lignocelulósicos utilizando candida guilliermondii.

Legal Events

Date Code Title Description
B350 Update of information on the portal [chapter 15.35 patent gazette]
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/08/2017, OBSERVADAS AS CONDICOES LEGAIS