MX2019001959A - Conversión de alcoholes en alcanos funcionarizados lineales y ramificados. - Google Patents
Conversión de alcoholes en alcanos funcionarizados lineales y ramificados.Info
- Publication number
- MX2019001959A MX2019001959A MX2019001959A MX2019001959A MX2019001959A MX 2019001959 A MX2019001959 A MX 2019001959A MX 2019001959 A MX2019001959 A MX 2019001959A MX 2019001959 A MX2019001959 A MX 2019001959A MX 2019001959 A MX2019001959 A MX 2019001959A
- Authority
- MX
- Mexico
- Prior art keywords
- alcohols
- linear
- functionalized alkanes
- conversion
- branched
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/02—Reduction
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B33/00—Oxidation in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/04—Dehydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
- C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/86—Use of additives, e.g. for stabilisation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D319/00—Heterocyclic compounds containing six-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D319/04—1,3-Dioxanes; Hydrogenated 1,3-dioxanes
- C07D319/06—1,3-Dioxanes; Hydrogenated 1,3-dioxanes not condensed with other rings
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Las modalidades de la presente tienen que ver con la conversion amigable con el ambiente de alcoholes simples en alcanos lineales o ramificados funcionarizados, por medio de catalisis integrada; los alcoholes primero se oxidan ya sea de forma quimica o enzimatica a los aldehidos o cetonas correspondientes, seguido por condensaciones de aldol usando un catalizador para dar los correspondientes enales o enonas; los enales o enonas de forma subsecuente y selectiva se hidrogenan usando un catalizador metalico heterogeneo reciclable, organocatalizador o una enzima para proporcionar alcanos funcionarizados lineales o ramificados con una funcionalidad aldehido, ceto- o alcohol; el proceso tambien es iterativo y puede extenderse adicionalmente repitiendo la catalisis integrada anterior para producir alcanos funcionarizados de cadena larga a partir de alcoholes simples.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662375805P | 2016-08-16 | 2016-08-16 | |
PCT/SE2017/050826 WO2018034609A1 (en) | 2016-08-16 | 2017-08-16 | Conversion of alcohols to linear and branched functionalized alkanes |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2019001959A true MX2019001959A (es) | 2019-09-04 |
Family
ID=61197366
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2019001959A MX2019001959A (es) | 2016-08-16 | 2017-08-16 | Conversión de alcoholes en alcanos funcionarizados lineales y ramificados. |
Country Status (14)
Country | Link |
---|---|
US (1) | US10611702B2 (es) |
EP (1) | EP3500547B1 (es) |
JP (1) | JP6927533B2 (es) |
KR (1) | KR102277351B1 (es) |
CN (1) | CN109563015B (es) |
AU (1) | AU2017313636B2 (es) |
BR (1) | BR112019002791B1 (es) |
CA (1) | CA3032789C (es) |
MX (1) | MX2019001959A (es) |
NZ (1) | NZ751399A (es) |
RU (1) | RU2732124C1 (es) |
SG (1) | SG11201901309RA (es) |
WO (1) | WO2018034609A1 (es) |
ZA (1) | ZA201901628B (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107930647B (zh) * | 2017-12-06 | 2021-03-09 | 万华化学集团股份有限公司 | 一种催化剂、其制备方法以及2-乙基己醛的制备方法 |
WO2020101902A1 (en) * | 2018-11-13 | 2020-05-22 | Eastman Chemical Company | Self-condensation of aldehydes |
WO2023061971A1 (en) | 2021-10-11 | 2023-04-20 | Organofuel Sweden Ab | A new fuel composition comprising a symmetric branched c12-c18 ether, or 3-(((2-ethylhexyl)oxy)methyl)heptane |
CN115304463A (zh) * | 2022-08-11 | 2022-11-08 | 中国农业科学院植物保护研究所 | 一种苹果蠹蛾信息素的制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6825384B1 (en) * | 2004-01-29 | 2004-11-30 | The Nutrasweet Company | Bromine free TEMPO based catalyst system for oxidation of primary and secondary alcohols using NaOCl as an oxidant |
US7351867B2 (en) * | 2004-02-26 | 2008-04-01 | The Nutrasweet Company | Catalyst system for aerobic oxidation of primary and secondary alcohols |
EP2072491A1 (en) * | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain |
BRPI0903506B1 (pt) * | 2009-08-17 | 2017-12-19 | Kabushiki Kaisha Sangi | A method of synthesis of alcohol for the synthesis of butanol from ethanol ?? |
-
2017
- 2017-08-16 KR KR1020197007111A patent/KR102277351B1/ko active IP Right Grant
- 2017-08-16 CN CN201780050122.3A patent/CN109563015B/zh active Active
- 2017-08-16 CA CA3032789A patent/CA3032789C/en active Active
- 2017-08-16 MX MX2019001959A patent/MX2019001959A/es unknown
- 2017-08-16 NZ NZ751399A patent/NZ751399A/en unknown
- 2017-08-16 AU AU2017313636A patent/AU2017313636B2/en active Active
- 2017-08-16 EP EP17841760.6A patent/EP3500547B1/en active Active
- 2017-08-16 BR BR112019002791-2A patent/BR112019002791B1/pt active IP Right Grant
- 2017-08-16 US US16/325,676 patent/US10611702B2/en active Active
- 2017-08-16 WO PCT/SE2017/050826 patent/WO2018034609A1/en active Search and Examination
- 2017-08-16 RU RU2019105049A patent/RU2732124C1/ru active
- 2017-08-16 JP JP2019505216A patent/JP6927533B2/ja active Active
- 2017-08-16 SG SG11201901309RA patent/SG11201901309RA/en unknown
-
2019
- 2019-03-15 ZA ZA2019/01628A patent/ZA201901628B/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP2019531265A (ja) | 2019-10-31 |
EP3500547A4 (en) | 2020-01-15 |
BR112019002791B1 (pt) | 2022-07-05 |
WO2018034609A1 (en) | 2018-02-22 |
CN109563015B (zh) | 2022-06-24 |
CA3032789A1 (en) | 2018-02-22 |
JP6927533B2 (ja) | 2021-09-01 |
CA3032789C (en) | 2021-07-13 |
RU2732124C1 (ru) | 2020-09-11 |
BR112019002791A2 (pt) | 2019-05-21 |
AU2017313636B2 (en) | 2020-07-09 |
EP3500547B1 (en) | 2023-10-11 |
US20190210940A1 (en) | 2019-07-11 |
US10611702B2 (en) | 2020-04-07 |
EP3500547A1 (en) | 2019-06-26 |
KR102277351B1 (ko) | 2021-07-13 |
EP3500547C0 (en) | 2023-10-11 |
SG11201901309RA (en) | 2019-03-28 |
ZA201901628B (en) | 2021-06-30 |
KR20190042026A (ko) | 2019-04-23 |
CN109563015A (zh) | 2019-04-02 |
AU2017313636A1 (en) | 2019-03-14 |
NZ751399A (en) | 2020-07-31 |
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