BR112018016567A2 - processo para preparar homo- ou copolímeros de isobuteno de alta reatividade. - Google Patents

processo para preparar homo- ou copolímeros de isobuteno de alta reatividade.

Info

Publication number
BR112018016567A2
BR112018016567A2 BR112018016567A BR112018016567A BR112018016567A2 BR 112018016567 A2 BR112018016567 A2 BR 112018016567A2 BR 112018016567 A BR112018016567 A BR 112018016567A BR 112018016567 A BR112018016567 A BR 112018016567A BR 112018016567 A2 BR112018016567 A2 BR 112018016567A2
Authority
BR
Brazil
Prior art keywords
copolymers
high reactivity
preparing high
isobutene
isobutene homo
Prior art date
Application number
BR112018016567A
Other languages
English (en)
Other versions
BR112018016567B1 (pt
Inventor
Shiman Dmitryi
Vasilenko Irina
Muehlbach Klaus
Corberan Roc Rosa
V Kostjuk Sergei
Wettling Thomas
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of BR112018016567A2 publication Critical patent/BR112018016567A2/pt
Publication of BR112018016567B1 publication Critical patent/BR112018016567B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

a presente invenção refere-se a um processo para preparar homo- ou copolímeros de isobuteno de alta reatividade com um teor de ligações duplas terminais de vinilideno por extremidade de cadeia de poli-isobuteno de pelo menos 80% em mols, que compreende a polimerização de isobuteno ou de uma mistura de monômeros compreendendo isobuteno na presença de um complexo doador de tri-halogeneto de alumínio eficaz como um catalisador de polimerização ou um complexo doador de halogeneto de alquilalumínio eficaz como um catalisador de polimerização, em que o tri-halogeneto de alumínio ou halogeneto de alquilalumínio é tratado com, pelo menos, um hidrato inorgânico.
BR112018016567-0A 2016-02-16 2017-02-13 Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade BR112018016567B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16155930.7 2016-02-16
EP16155930 2016-02-16
PCT/EP2017/053098 WO2017140603A1 (en) 2016-02-16 2017-02-13 Process for preparing high-reactivity isobutene homo- or copolymers

Publications (2)

Publication Number Publication Date
BR112018016567A2 true BR112018016567A2 (pt) 2019-01-02
BR112018016567B1 BR112018016567B1 (pt) 2022-07-05

Family

ID=55398212

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018016567-0A BR112018016567B1 (pt) 2016-02-16 2017-02-13 Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade

Country Status (10)

Country Link
US (2) US10968294B2 (pt)
EP (1) EP3416992B1 (pt)
JP (1) JP6903069B2 (pt)
KR (1) KR20180109939A (pt)
CN (2) CN108602914B (pt)
BR (1) BR112018016567B1 (pt)
CA (1) CA3014685A1 (pt)
MY (1) MY189238A (pt)
SG (1) SG11201806870WA (pt)
WO (1) WO2017140603A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10968294B2 (en) * 2016-02-16 2021-04-06 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
EP3444283B1 (en) 2017-08-17 2020-02-26 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US10174138B1 (en) * 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
EP4019128B1 (en) * 2019-08-19 2024-02-21 Lg Chem, Ltd. Organic borate-based catalyst, method for preparing isobutene oligomer by using same, and isobutene oligomer prepared thereby
EP3943518A1 (en) * 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene
KR20240016976A (ko) 2021-06-07 2024-02-06 바스프 에스이 특정한 이중 결합 이성질체의 함량이 높은 폴리이소부텐
WO2023152258A1 (en) 2022-02-11 2023-08-17 Basf Se Medium molecular polyisobutene with a high content of certain double bond isomers
WO2023152033A1 (en) 2022-02-11 2023-08-17 Basf Se Medium molecular polyisobutene with a certain distribution of double bond isomers
WO2023198616A1 (en) 2022-04-14 2023-10-19 Basf Se Process for manufacturing of polyisobutene succinic anhydrides
WO2023198589A1 (en) 2022-04-14 2023-10-19 Basf Se Process for manufacturing of polyisobutene succinic anhydrides

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
BE1006694A5 (fr) 1991-06-22 1994-11-22 Basf Ag Procede de preparation de polyisobutenes extremement reactifs.
US5340881A (en) 1992-11-16 1994-08-23 The University Of Akron Aldehyde-telechelic polyisobutylenes, catalytic method for preparing the same with high conversion and selectivity, and block copolymers made thereform
DE19825334A1 (de) 1998-06-05 1999-12-09 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
MY127714A (en) * 1999-07-16 2006-12-29 Basf Ag Method for producing highly reactive polyisobutenes
US7893176B2 (en) * 2007-03-23 2011-02-22 Exxonmobil Chemical Patents Inc. Polydispersity-controlled isoolefin polymerization with polymorphogenates
US8349977B2 (en) * 2010-02-17 2013-01-08 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN102762610A (zh) 2010-02-17 2012-10-31 巴斯夫欧洲公司 生产高反应性异丁烯均聚物或共聚物的方法
CN103764695A (zh) * 2011-08-11 2014-04-30 巴斯夫欧洲公司 生产高反应性异丁烯均聚物或共聚物的方法
US8697820B2 (en) * 2011-08-11 2014-04-15 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
WO2013192186A1 (en) * 2012-06-18 2013-12-27 Petrochemical Supply, Inc. Polyisobutylene composition having internal vinylidene and process for preparing the polyisobutylene polymer composition
US9631038B2 (en) * 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10968294B2 (en) * 2016-02-16 2021-04-06 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
BR112018015440B1 (pt) 2016-02-16 2022-07-05 Basf Se Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade

Also Published As

Publication number Publication date
EP3416992A1 (en) 2018-12-26
WO2017140603A1 (en) 2017-08-24
CN108602914B (zh) 2021-09-24
JP6903069B2 (ja) 2021-07-14
US10968294B2 (en) 2021-04-06
EP3416992B1 (en) 2020-04-15
US20210253752A1 (en) 2021-08-19
US20190062472A1 (en) 2019-02-28
JP2019505643A (ja) 2019-02-28
KR20180109939A (ko) 2018-10-08
US11629206B2 (en) 2023-04-18
CN113698514A (zh) 2021-11-26
CN108602914A (zh) 2018-09-28
MY189238A (en) 2022-01-31
CA3014685A1 (en) 2017-08-24
CN113698514B (zh) 2023-11-10
BR112018016567B1 (pt) 2022-07-05
SG11201806870WA (en) 2018-09-27

Similar Documents

Publication Publication Date Title
BR112018016567A2 (pt) processo para preparar homo- ou copolímeros de isobuteno de alta reatividade.
BR112017014081A2 (pt) uma composição de poliolefina e método para produção da mesma
BR112018009278A2 (pt) polimerizações de radicais livres de alta pressão
BR112019010803A2 (pt) receptores de célula t com pareamento melhorado
BR112018009036A8 (pt) polimerizações via radicais livres a alta pressão para produzir polímeros à base de etileno
BR112015019053A2 (pt) composição de polialuminoxano sólido, catalisador de polimerização de olefina, método de produção de polímero de olefina e método de produção de composição de polialuminoxano sólido
BR112017013863A2 (pt) processo para formar interpolímeros de etileno/alfa-olefina
BR112018004470A2 (pt) processo para produzir polímeros à base de etileno com contagens de gel reduzidas e baixa incrustação de reator
BR112016013791A2 (pt) Processo para formar um polímero à base de etileno
BR112018015440A2 (pt) ?processo para preparar homo- ou copolímeros de isobuteno de alta reatividade?
BR112017002836A2 (pt) composições de terpolímero com clareza e brilho aprimorados
BR112015029828A2 (pt) componentes catalisadores pré-polimerizados para polimerização de olefinas
BR112017020525A2 (pt) processos para a produção de interpolímeros de etileno/alfa-olefina/não conjugados de alto peso molecular com baixos níveis de ramificação de cadeia longa
BR112018074123A2 (pt) doador não ftalato para catalisadores de poliolefina
BR112018010760A2 (pt) composição de borracha
BR112017011523A2 (pt) composição de polietileno, processos para produção de uma composição de polietileno e de um artigo conformado, e, uso de uma composição de polietileno.
BR112017007457A2 (pt) composição de catalisador para a polimerização de olefinas
BR112018077433A2 (pt) processo para preparação de polímeros de ácido acrílico sólidos, e, solução aquosa de polímero de ácido acrílico pelo menos parcialmente neutralizada .
BR112017000643A2 (pt) formulação, processo para preparação de uma formulação, uso de uma formulação, e, folha autoadesiva, fita autoadesiva, etiqueta autoadesiva ou etiqueta de lavagem
BR112015015773A2 (pt) sistema de catalisador ziegler-natta heterogêneo e um processo para polimerização de olefina com uso do mesmo
BR112017024414A2 (pt) um processo para produzir um pré-polímero telequélico reativo de poliolefina
BR112014029395A2 (pt) componentes de catalisador para a polimerização de olefinas
BR112017025038A2 (pt) mistura de polímero em forma granular e processo para fazer a mesma
BR112017015481A2 (pt) método para produção de uma borracha de nitrilo altamente saturada, e, solução ou dispersão de uma borracha de nitrilo
BR112017006060A2 (pt) processo para a polimerização de etileno na presença de um catalisador de polimerização de olefinas

Legal Events

Date Code Title Description
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 13/02/2017, OBSERVADAS AS CONDICOES LEGAIS