BR112018011910A2 - fibra com baixo teor de fluência estática - Google Patents

fibra com baixo teor de fluência estática

Info

Publication number
BR112018011910A2
BR112018011910A2 BR112018011910-5A BR112018011910A BR112018011910A2 BR 112018011910 A2 BR112018011910 A2 BR 112018011910A2 BR 112018011910 A BR112018011910 A BR 112018011910A BR 112018011910 A2 BR112018011910 A2 BR 112018011910A2
Authority
BR
Brazil
Prior art keywords
fiber
comonomer
solution
gel
uhmwpe
Prior art date
Application number
BR112018011910-5A
Other languages
English (en)
Other versions
BR112018011910B1 (pt
Inventor
Antonius Philomena Engels Tom
De Cremer Gert
Berthoud Romain
Stepanyan Roman
Roozemond Peter
Stefan Emiel Oosterlinck Filip
Richard Severn John
Original Assignee
Dsm Ip Assets B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Ip Assets B.V. filed Critical Dsm Ip Assets B.V.
Publication of BR112018011910A2 publication Critical patent/BR112018011910A2/pt
Publication of BR112018011910B1 publication Critical patent/BR112018011910B1/pt

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/06Wet spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/30Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising olefins as the major constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/068Ultra high molecular weight polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/02Ziegler natta catalyst
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • D10B2321/0211Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/062Load-responsive characteristics stiff, shape retention

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

a invenção se refere a um processo para a preparação de uma fibra de uhmwpe fiada em gel que compreende as etapas de fornecer uma composição de polietileno com peso molecular ultra alto que tem uma viscosidade intrínseca (iv) de pelo menos 8 dl/g, um teor de comonômero (cbr) de pelo menos 0,05 scb/1000tc, uma distribuição em massa média do comonômero (cmad) de pelo menos 0,05, em que o comonômero tem pelo menos 4 átomos de carbono, dissolver a composição em um solvente para formar uma solução polimérica que tem uma concentração de uhmwpe entre 2 e 40 % em peso, fiar a solução polimérica através de um placa de corte de múltiplos orifícios para formar uma fibra de solução, resfriar a fibra de solução para abaixo de 80 °c para formar uma fibra de gel, extrair a fibra em pelo menos uma etapa para formar uma fibra extraída, remover pelo menos uma porção do solvente antes, durante ou depois da extração, em que a razão entre cmad e cbr é maior que 1,0. a invenção se refere, adicionalmente, a uma fibra de uhmwpe fiada em gel obtenível por meio do processo e dos produtos que compreendem a dita fibra de uhmwpe fiada em gel.
BR112018011910-5A 2015-12-15 2016-12-12 Processo para a preparação de uma fibra de uhmwpe fiada em gel, fibra de uhmwpe fiada em gel, produto compreendendo a fibra BR112018011910B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15200047 2015-12-15
EP15200047.7 2015-12-15
PCT/EP2016/080569 WO2017102618A1 (en) 2015-12-15 2016-12-12 Low creep fiber

Publications (2)

Publication Number Publication Date
BR112018011910A2 true BR112018011910A2 (pt) 2018-11-27
BR112018011910B1 BR112018011910B1 (pt) 2022-10-04

Family

ID=54849888

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018011910-5A BR112018011910B1 (pt) 2015-12-15 2016-12-12 Processo para a preparação de uma fibra de uhmwpe fiada em gel, fibra de uhmwpe fiada em gel, produto compreendendo a fibra

Country Status (11)

Country Link
US (1) US10676844B2 (pt)
EP (2) EP3390704B1 (pt)
JP (2) JP6921823B2 (pt)
KR (1) KR102646622B1 (pt)
CN (2) CN112746345B (pt)
BR (1) BR112018011910B1 (pt)
CA (1) CA3008051C (pt)
ES (1) ES2811922T3 (pt)
LT (1) LT3390704T (pt)
PT (1) PT3390704T (pt)
WO (1) WO2017102618A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109306028B (zh) * 2017-07-26 2021-05-25 中国石油化工股份有限公司 纤维用超高分子量聚乙烯、聚乙烯组合物和聚乙烯纤维及其应用
US20220235492A1 (en) 2019-05-14 2022-07-28 Toyobo Co., Ltd. Polyethylene fiber
CN111172607B (zh) * 2020-01-19 2022-11-25 上海化工研究院有限公司 一种抗蠕变超高分子量聚乙烯纤维的制备方法
CN114232121B (zh) * 2022-01-11 2024-06-21 武汉纺织大学 高抗蠕变超高分子量聚乙烯纤维及其制备方法

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IN170335B (pt) 1986-10-31 1992-03-14 Dyneema Vof
JPH089804B2 (ja) * 1987-12-03 1996-01-31 三井石油化学工業株式会社 初期伸びの改善されたポリオレフィン系繊維及びその製法
JPH02112432A (ja) * 1988-10-21 1990-04-25 Mitsui Petrochem Ind Ltd ヨット用帆布
JP3226062B2 (ja) 1993-03-29 2001-11-05 東洋紡績株式会社 高強度ポリエチレン繊維
CN100379769C (zh) * 2003-03-10 2008-04-09 旭化成化学株式会社 超高分子量乙烯聚合物
JP4578483B2 (ja) 2004-01-01 2010-11-10 ディーエスエム アイピー アセッツ ビー.ブイ. 高性能ポリエチレンマルチフィラメント糸の製造方法
ES2375278T3 (es) 2004-01-01 2012-02-28 Dsm Ip Assets B.V. Procedimiento para producir hilo multifilamento de polietileno de alto rendimiento.
WO2005097322A1 (en) 2004-04-08 2005-10-20 Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rossiiskoi Akademii Nauk Method for preparing a catalyst and process for polymerising ethylene and copolymerising ethylene with alpha-olefins
DE102004020524A1 (de) * 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
EP1647616A1 (en) 2004-10-14 2006-04-19 DSM IP Assets B.V. Process for making a monofilament-like product
EP1746187A1 (en) * 2005-07-18 2007-01-24 DSM IP Assets B.V. Polyethylene multi-filament yarn
RU2320410C1 (ru) 2006-11-16 2008-03-27 Институт Катализа Имени Г.К. Борескова Сибирского Отделения Российской Академии Наук Способ приготовления катализатора и процесс полимеризации этилена с использованием этого катализатора
US8889049B2 (en) * 2010-04-30 2014-11-18 Honeywell International Inc Process and product of high strength UHMW PE fibers
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KR101522051B1 (ko) * 2007-10-05 2015-05-20 디에스엠 아이피 어셋츠 비.브이. Uhmwpe 섬유 및 이의 제조 방법
KR101618816B1 (ko) 2007-11-01 2016-05-09 디에스엠 아이피 어셋츠 비.브이. 재료 쉬트 및 이의 제조 방법
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CA2865201C (en) 2012-03-09 2021-05-18 Dsm Ip Assets B.V. Composite panel
AU2014270344B2 (en) 2013-05-23 2017-09-07 Avient Protective Materials B.V. UHMWPE fiber
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Also Published As

Publication number Publication date
EP3390704B1 (en) 2020-07-01
CN108431309B (zh) 2021-02-05
US20180355515A1 (en) 2018-12-13
EP3390704A1 (en) 2018-10-24
JP2018537600A (ja) 2018-12-20
JP7110527B2 (ja) 2022-08-02
KR20180093985A (ko) 2018-08-22
WO2017102618A1 (en) 2017-06-22
KR102646622B1 (ko) 2024-03-11
CA3008051C (en) 2023-10-03
JP2021177025A (ja) 2021-11-11
CA3008051A1 (en) 2017-06-22
CN112746345A (zh) 2021-05-04
PT3390704T (pt) 2020-08-26
JP6921823B2 (ja) 2021-08-18
ES2811922T3 (es) 2021-03-15
BR112018011910B1 (pt) 2022-10-04
CN112746345B (zh) 2023-07-25
LT3390704T (lt) 2020-09-25
CN108431309A (zh) 2018-08-21
EP3739088A1 (en) 2020-11-18
US10676844B2 (en) 2020-06-09

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