BR112018004459A2 - método para a (co)polimerização do radical e (co)polímero acrílico associativo - Google Patents

método para a (co)polimerização do radical e (co)polímero acrílico associativo

Info

Publication number
BR112018004459A2
BR112018004459A2 BR112018004459-8A BR112018004459A BR112018004459A2 BR 112018004459 A2 BR112018004459 A2 BR 112018004459A2 BR 112018004459 A BR112018004459 A BR 112018004459A BR 112018004459 A2 BR112018004459 A2 BR 112018004459A2
Authority
BR
Brazil
Prior art keywords
polymerization
polymer
radical
associative
acrylic polymer
Prior art date
Application number
BR112018004459-8A
Other languages
English (en)
Other versions
BR112018004459B1 (pt
BR112018004459B8 (pt
Inventor
Suau Jean-Marc
Champagne Clémentine
Original Assignee
Coatex
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Coatex filed Critical Coatex
Publication of BR112018004459A2 publication Critical patent/BR112018004459A2/pt
Publication of BR112018004459B1 publication Critical patent/BR112018004459B1/pt
Publication of BR112018004459B8 publication Critical patent/BR112018004459B8/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C08F20/64—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

a presente invenção se refere à síntese de um (co)polímero acrílico associativo por meio de polimerização do radical em emulsão aquosa, dito (co)polímero compreende, pelo menos, uma mistura de oligômeros de ácido acrílico representados pela fórmula (i): em que n é um número inteiro variando a partir de 1 a 10, ditos oligômeros sendo preparados a partir de ácido acrílico a uma temperatura entre 50º c e 200º c na presença de um catalisador básico ou ácido, de água e de inibidores de polimerização. a presente invenção também se refere ao (co)polímero de acrílico associativo obtido através do método e também à utilização deste (co)polímero como espessante em diversas formulações.
BR112018004459A 2015-10-02 2016-09-30 Método para a (co)polimerização radicalar em emulsão aquosa e (co)polímero acrílico associativo BR112018004459B8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1559391 2015-10-02
FR1559391A FR3041963B1 (fr) 2015-10-02 2015-10-02 Procede de synthese de (co)polymeres acryliques a partir d'oligomeres de l'acide acrylique
PCT/FR2016/052502 WO2017055767A1 (fr) 2015-10-02 2016-09-30 Procédé de synthèse de (co)polymères acryliques a partir d'oligomères de l'acide acrylique

Publications (3)

Publication Number Publication Date
BR112018004459A2 true BR112018004459A2 (pt) 2018-09-25
BR112018004459B1 BR112018004459B1 (pt) 2021-12-14
BR112018004459B8 BR112018004459B8 (pt) 2022-03-03

Family

ID=54478898

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018004459A BR112018004459B8 (pt) 2015-10-02 2016-09-30 Método para a (co)polimerização radicalar em emulsão aquosa e (co)polímero acrílico associativo

Country Status (8)

Country Link
US (1) US10941231B2 (pt)
EP (1) EP3356428B1 (pt)
JP (1) JP6961577B2 (pt)
KR (1) KR102630993B1 (pt)
CN (1) CN108137741B (pt)
BR (1) BR112018004459B8 (pt)
FR (1) FR3041963B1 (pt)
WO (1) WO2017055767A1 (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3093724B1 (fr) 2019-03-14 2021-02-19 Arkema France Procede de synthese d’oligomeres d’acide acrylique
FR3125048B1 (fr) * 2021-07-09 2024-04-19 Snf Sa Polymère biosourcé à biodégradabilité améliorée

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4359564A (en) * 1980-03-14 1982-11-16 Rohm & Haas Co. Addition polymer of oligomeric polyesters of acrylic acid
JPH04134049A (ja) * 1990-09-21 1992-05-07 Toagosei Chem Ind Co Ltd ペンタエリスリトールテトラエステルの製造方法
JPH05105732A (ja) * 1991-10-14 1993-04-27 Osaka Organic Chem Ind Ltd 光硬化性組成物
JP2914488B2 (ja) * 1996-02-27 1999-06-28 日本エヌエスシー株式会社 硬化性組成物の製法および使用方法
ATE250637T1 (de) * 1997-12-17 2003-10-15 Ucb Sa Druckempfindliche klebstoffzusammensetzungen
DE102009014877A1 (de) * 2009-03-25 2009-09-24 Clariant International Ltd. Polymere auf Basis von Acryl-, Methacryl- oder Ethacrylamidoalkylsulfonsäure oder -salzen und Carboxyalkylacrylat, -methacrylat oder -ethacrylat oder Oligomeren dieser Carboxy-Verbindungen
FR2972370B1 (fr) * 2011-03-07 2013-03-01 Coatex Sas Procede d'epaississement d'une formulation cosmetique a partir d'une emulsion alkali gonflable d'un polymere a l'amps et riche en acide acrylique.
CN102206297B (zh) * 2011-03-30 2012-08-22 北京神彩优维喷墨材料科技有限公司 一种用于紫外光固化涂料和油墨的低聚物及其制备方法
US9095730B2 (en) * 2011-06-07 2015-08-04 Basf Se Associative thickeners based on methacrylate
CN102585066B (zh) * 2011-06-16 2013-11-06 湖北固润科技股份有限公司 含乙烯基醚官能团的聚（甲基）丙烯酸酯低聚物
KR20150096796A (ko) * 2012-12-20 2015-08-25 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 카르복시에틸 아크릴레이트 함유 코폴리머 안정화제/증점제 및 케라틴성 기재 상의 실리콘 침적의 손실을 완화시키기 위한 방법

Also Published As

Publication number Publication date
FR3041963A1 (fr) 2017-04-07
KR20180064459A (ko) 2018-06-14
CN108137741B (zh) 2020-12-22
WO2017055767A1 (fr) 2017-04-06
JP2018531295A (ja) 2018-10-25
EP3356428A1 (fr) 2018-08-08
EP3356428B1 (fr) 2020-02-12
KR102630993B1 (ko) 2024-01-29
FR3041963B1 (fr) 2019-07-26
BR112018004459B1 (pt) 2021-12-14
JP6961577B2 (ja) 2021-11-05
BR112018004459B8 (pt) 2022-03-03
US10941231B2 (en) 2021-03-09
US20180346625A1 (en) 2018-12-06
CN108137741A (zh) 2018-06-08

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Legal Events

Date Code Title Description
B25A Requested transfer of rights approved

Owner name: ARKEMA FRANCE (FR)

B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 30/09/2016, OBSERVADAS AS CONDICOES LEGAIS.

B16C Correction of notification of the grant [chapter 16.3 patent gazette]

Free format text: REF. RPI 2658 DE 14/12/2021 QUANTO AO ENDERECO.