BR112017025413A2 - processo para polimerização em um reator de leito fluidizado - Google Patents

processo para polimerização em um reator de leito fluidizado

Info

Publication number
BR112017025413A2
BR112017025413A2 BR112017025413A BR112017025413A BR112017025413A2 BR 112017025413 A2 BR112017025413 A2 BR 112017025413A2 BR 112017025413 A BR112017025413 A BR 112017025413A BR 112017025413 A BR112017025413 A BR 112017025413A BR 112017025413 A2 BR112017025413 A2 BR 112017025413A2
Authority
BR
Brazil
Prior art keywords
polymerization
fluidized bed
bed reactor
initiating
produced
Prior art date
Application number
BR112017025413A
Other languages
English (en)
Other versions
BR112017025413B1 (pt
Inventor
Guillen-Castellanos Sergio
Ker Victoria
Jiang Yan
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of BR112017025413A2 publication Critical patent/BR112017025413A2/pt
Publication of BR112017025413B1 publication Critical patent/BR112017025413B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02Anti-static agent incorporated into the catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/04Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene

Abstract

um processo de polimerização para iniciar um reator em fase gasosa estável quando são produzidos copolímeros de etileno que possuem distribuição de peso molecular e razão de índice de fluidez à fusão relativamente altas.
BR112017025413-1A 2015-05-26 2016-05-13 Processo para polimerização em um reator em fase gasosa BR112017025413B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CA2892552 2015-05-26
CA2892552A CA2892552C (en) 2015-05-26 2015-05-26 Process for polymerization in a fluidized bed reactor
PCT/IB2016/052795 WO2016189412A1 (en) 2015-05-26 2016-05-13 Process for polymerization in a fluidized bed reactor

Publications (2)

Publication Number Publication Date
BR112017025413A2 true BR112017025413A2 (pt) 2018-08-07
BR112017025413B1 BR112017025413B1 (pt) 2021-11-16

Family

ID=56121133

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017025413-1A BR112017025413B1 (pt) 2015-05-26 2016-05-13 Processo para polimerização em um reator em fase gasosa

Country Status (6)

Country Link
US (1) US9708427B2 (pt)
BR (1) BR112017025413B1 (pt)
CA (1) CA2892552C (pt)
MX (1) MX2017014589A (pt)
TW (1) TW201718664A (pt)
WO (1) WO2016189412A1 (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3700948B1 (en) * 2017-10-27 2023-09-20 Univation Technologies, LLC Polyethylene copolymer resins and films

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
JPS5964604A (ja) 1982-10-06 1984-04-12 Sumitomo Chem Co Ltd ポリオレフインの製造方法
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5026795A (en) 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
US4937301A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US4935397A (en) 1988-09-28 1990-06-19 Exxon Chemical Patents Inc. Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2660926B1 (fr) 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
PL166690B1 (pl) 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
JP2665628B2 (ja) 1990-11-22 1997-10-22 富士写真フイルム株式会社 ハロゲン化銀カラー写真感光材料
WO1993003093A1 (en) 1991-07-18 1993-02-18 Exxon Chemical Patents Inc. Heat sealed article
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US6968375B1 (en) 1997-03-28 2005-11-22 Health Hero Network, Inc. Networked system for interactive communication and remote monitoring of individuals
RU2120947C1 (ru) 1993-04-26 1998-10-27 Эксон Кемикэл Пейтентс Инк. Способ газофазной полимеризации в псевдоожиженном слое
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US6124230A (en) 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US6140432A (en) 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US6002033A (en) 1995-11-22 1999-12-14 Fina Research, S.A. Bridged metallocenes for use in catalyst systems
DE19615953A1 (de) 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
CZ170897A3 (en) 1996-06-06 1997-12-17 Union Carbide Chem Plastic Control of static charge in the course of polymerization process during which metallocene catalyst is used
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
CZ20999A3 (cs) 1996-07-22 1999-04-14 The Dow Chemical Company Kovové komplexy obsahující můstkové ne-aromatické aniontové dienylové skupiny, adiční polymerační katalyzátory na bázi těchto komplexů a způsob polymerace
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
CA2206944C (en) 1997-05-30 2006-08-29 Douglas W. Stephan High temperature solution polymerization process
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
CA2210131C (en) 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts
TW562810B (en) 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
KR100342541B1 (ko) 1998-04-16 2002-06-28 나까니시 히로유끼 올레핀 중합촉매 및 중합방법
US7354880B2 (en) 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
CA2245375C (en) 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
CA2247703C (en) 1998-09-22 2007-04-17 Nova Chemicals Ltd. Dual reactor ethylene polymerization process
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
BR0010321B1 (pt) 1999-05-07 2010-04-06 processo para a (co-) polimerização de fase gasosa contìnua de olefinas em um reator de leito fluidizado.
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
CA2278042C (en) 1999-07-19 2008-12-16 Nova Chemicals Corporation Mixed phosphinimine catalyst
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
RU2258712C2 (ru) 2000-12-04 2005-08-20 Юнивейшн Технолоджиз, Ллс Способ полимеризации
EP1401887A1 (en) 2001-04-30 2004-03-31 W.R. Grace &amp; Co.-Conn. Heterogeneous chromium catalysts and processes of polymerization of olefins using same
ATE337343T1 (de) 2001-04-30 2006-09-15 Grace W R & Co Geträgerte dualübergangsmetallkatalysatorsysteme
CA2347410C (en) 2001-05-11 2009-09-08 Nova Chemicals Corporation Solution polymerization process catalyzed by a phosphinimine catalyst
EP1308464A1 (en) 2001-10-19 2003-05-07 BP Chemicals S.N.C. Process for the gas-phase (co-)polymerisation of olefins in a fluidised bed reactor
CA2411183C (en) 2002-11-05 2011-06-14 Nova Chemicals Corporation Heterogeneous/homogeneous copolymer
WO2004087776A1 (en) 2003-04-03 2004-10-14 Basell Polyolefine Gmbh Preparation of polyolefins having high molecular weights in the presence of an organic transition metal compound in a gas-phase fluidized-bed reactor
DE10315349A1 (de) * 2003-04-03 2004-10-14 Basell Polyolefine Gmbh Verfahren zur Herstellung von Polyolefinen mit hohen Molekulargewichten in einem Gasphasenwirbelschichtreaktor in Gegenwart einer Organoübergangsmetallverbindung
EP1834983A1 (en) 2006-03-14 2007-09-19 Ineos Europe Limited Polymer films
GB0610668D0 (en) 2006-05-30 2006-07-12 Nova Chem Int Sa Supported antistatic polymerization catalysts
EP2011822A1 (en) * 2007-07-04 2009-01-07 Borealis Technology Oy Multimodal polyethylene co-polymer resin composition, a preparation process therefore and a polymeric product comprising the same
CA2736410A1 (en) 2008-09-25 2010-04-01 Basell Polyolefine Gmbh Impact resistant lldpe composition and films made thereof
CA2716772C (en) 2009-10-20 2017-09-05 Nova Chemicals Corporation Improved reactor continuity
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2797620C (en) * 2012-12-03 2019-08-27 Nova Chemicals Corporation Controlling resin properties in a gas phase polymerization process

Also Published As

Publication number Publication date
TW201718664A (zh) 2017-06-01
CA2892552A1 (en) 2016-11-26
US20160347878A1 (en) 2016-12-01
US9708427B2 (en) 2017-07-18
WO2016189412A1 (en) 2016-12-01
BR112017025413B1 (pt) 2021-11-16
CA2892552C (en) 2022-02-15
MX2017014589A (es) 2018-03-01

Similar Documents

Publication Publication Date Title
PH12017501675A1 (en) Novel siloxane polymer compositions and their use
BR112016029439A2 (pt) processo para polimerização de olefinas
MX2018006214A (es) Resina de rotomoldeo de alta densidad.
MX2018006855A (es) Proceso de llenado en caliente con tapas hechas de composiciones de polietileno bimodales.
MX2022005282A (es) Metodo para producir polietileno y polietileno del mismo.
BR112014024449A2 (pt) composição, método de geração de uma partícula do vetor lentiviral pseutipado, e, partícula do vetor lentiviral.
PT3530675T (pt) Sistema de reator para polimerização de polietileno multimodal
BR112016029266A2 (pt) sistemas de catalisador para polimerização de olefinas
MX2021014739A (es) Fosfinimida de titanio y sistemas de catalizadores de iminoimidazolidida de titanio con soportes de activador.
MX2016002876A (es) Poliolefinas de alta densidad con mayor resistencia al agrietamiento por estres.
MX2015010737A (es) Procesos de polietileno y sus composiciones.
BR112018008481A2 (pt) métodos e sistemas de controle de purgação de produtos de polímero
BR112013024750A2 (pt) métodos, artigos e composições de ciclodextrina
BR112014014694A2 (pt) utilização de hidrogênio e um composto de organozinco para controle de polimerização e propriedade do polímero
BR112017010556A2 (pt) suportes passivados: catalisador, processo, produto e película
BR112017009658A2 (pt) processo e composição de moldagem por sopro
EP3505569A4 (en) AT ROOM TEMPERATURE CURABLE, ORGANOPOLYSILOXANENTAL COOLIZATION COMPOSITION AND BY A HARDENED PRODUCT SEALED ITEM
BR112014032814A8 (pt) Composição de polímeros capazes de absorver radiação ultravioleta e composição
EP3187514A4 (en) Polymerizable monomer, curable composition and resin member
SG10201912855UA (en) Solid catalyst component for polymerization of olefins, method for producing solid catalyst component for polymerization of olefins, catalyst for polymerization of olefins, method for producing polymer of olefin, method for producing propylene copolymer and propylene copolymer
EP3187515A4 (en) Polymerizable monomer, curable composition and resin member
ZA202002481B (en) Method of splitting the return fluidization gas in a gas solids olefin polymerization reactor
IL266417B (en) Olefin polymerization process in a gas wave reactor with three or more polymerization zones
EA201691947A1 (ru) Полиэтилен высокой плотности, растянутый в твердом состоянии
MY184536A (en) Modifier control in high pressure polyethylene production

Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 13/05/2016, OBSERVADAS AS CONDICOES LEGAIS.