BR112017007941B1 - Composição com base em poli(arileno éter cetona), processo para a preparação da referida composição, uso da mesma e objeto fabricado a partir desta - Google Patents
Composição com base em poli(arileno éter cetona), processo para a preparação da referida composição, uso da mesma e objeto fabricado a partir desta Download PDFInfo
- Publication number
- BR112017007941B1 BR112017007941B1 BR112017007941-0A BR112017007941A BR112017007941B1 BR 112017007941 B1 BR112017007941 B1 BR 112017007941B1 BR 112017007941 A BR112017007941 A BR 112017007941A BR 112017007941 B1 BR112017007941 B1 BR 112017007941B1
- Authority
- BR
- Brazil
- Prior art keywords
- composition
- pekk
- peek
- weight
- terephthalic
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 118
- 238000000034 method Methods 0.000 title claims description 22
- 230000008569 process Effects 0.000 title claims description 15
- 238000002360 preparation method Methods 0.000 title claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title description 8
- -1 ETHER KETONE Chemical class 0.000 title description 4
- 229920002530 polyetherether ketone Polymers 0.000 claims abstract description 67
- 229920001652 poly(etherketoneketone) Polymers 0.000 claims abstract description 60
- 238000000149 argon plasma sintering Methods 0.000 claims description 8
- 238000001746 injection moulding Methods 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000008240 homogeneous mixture Substances 0.000 claims description 2
- 229920008285 Poly(ether ketone) PEK Polymers 0.000 claims 1
- 238000005056 compaction Methods 0.000 claims 1
- 238000007580 dry-mixing Methods 0.000 claims 1
- 238000001192 hot extrusion Methods 0.000 claims 1
- 229920001657 poly(etheretherketoneketone) Polymers 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 description 44
- 230000008025 crystallization Effects 0.000 description 44
- 239000000463 material Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000000956 alloy Substances 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 8
- 238000005259 measurement Methods 0.000 description 6
- 230000003042 antagnostic effect Effects 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 229920001643 poly(ether ketone) Polymers 0.000 description 5
- 229920004695 VICTREX™ PEEK Polymers 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 238000009864 tensile test Methods 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 229920001660 poly(etherketone-etherketoneketone) Chemical group 0.000 description 3
- 229920006260 polyaryletherketone Polymers 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 125000000468 ketone group Chemical group 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920011674 Kepstan® 6003 Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/16—Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group
- C08G2650/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group containing ketone groups, e.g. polyarylethylketones, PEEK or PEK
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1460158A FR3027603B1 (fr) | 2014-10-22 | 2014-10-22 | Composition a base de polyarylene-ether-cetone a proprietes ameliorees |
| FR1460158 | 2014-10-22 | ||
| PCT/EP2015/073349 WO2016062558A1 (en) | 2014-10-22 | 2015-10-09 | Composition based on poly (arylene ether ketone) having improved properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112017007941A2 BR112017007941A2 (pt) | 2017-12-19 |
| BR112017007941B1 true BR112017007941B1 (pt) | 2021-08-24 |
Family
ID=52589492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112017007941-0A BR112017007941B1 (pt) | 2014-10-22 | 2015-10-09 | Composição com base em poli(arileno éter cetona), processo para a preparação da referida composição, uso da mesma e objeto fabricado a partir desta |
Country Status (12)
| Country | Link |
|---|---|
| US (4) | US10150866B2 (enExample) |
| EP (2) | EP3012297B2 (enExample) |
| JP (2) | JP6505219B2 (enExample) |
| KR (1) | KR101855054B1 (enExample) |
| CN (1) | CN107001787B (enExample) |
| BR (1) | BR112017007941B1 (enExample) |
| CA (1) | CA2965371C (enExample) |
| ES (2) | ES2711305T3 (enExample) |
| FR (1) | FR3027603B1 (enExample) |
| MX (1) | MX2017005144A (enExample) |
| RU (1) | RU2677666C2 (enExample) |
| WO (1) | WO2016062558A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3027603B1 (fr) * | 2014-10-22 | 2016-11-18 | Arkema France | Composition a base de polyarylene-ether-cetone a proprietes ameliorees |
| CN108779365B (zh) | 2016-03-09 | 2021-07-09 | 索尔维特殊聚合物美国有限责任公司 | 聚芳醚酮组合物及涂覆金属表面的方法 |
| US11352480B2 (en) | 2016-03-18 | 2022-06-07 | Ticona Llc | Polyaryletherketone composition |
| CN109843973B (zh) | 2016-08-02 | 2021-12-03 | 索尔维特殊聚合物美国有限责任公司 | 包含低分子量芳香族化合物的聚(芳醚酮)(paek)组合物 |
| FR3065002B1 (fr) | 2017-04-05 | 2020-05-15 | Arkema France | Procede d'impregnation de fibres de renfort avec des polyarylethercetones et semi-produits ainsi obtenus |
| FR3070979B1 (fr) * | 2017-09-08 | 2019-08-30 | Arkema France | Pieces en polyether cetone cetone presentant une stabilite dimensionnelle amelioree |
| EP3681687A4 (en) * | 2017-09-15 | 2021-06-02 | Arkema, Inc. | PROCESS FOR GENERATIVE MANUFACTURING WITH PEKK EXTRUSION AND PRODUCTS |
| FR3071184B1 (fr) * | 2017-09-18 | 2021-11-19 | Arkema France | Procede d'impregnation de fibres de renfort avec des polyarylethercetones et semi-produits ainsi obtenus |
| FR3074184B1 (fr) * | 2017-11-27 | 2020-07-24 | Arkema France | Utilisation de pekk pour la fabrication de pieces a faible permeabilite gazeuse |
| US11118053B2 (en) | 2018-03-09 | 2021-09-14 | Ticona Llc | Polyaryletherketone/polyarylene sulfide composition |
| JP7197420B2 (ja) * | 2019-03-29 | 2022-12-27 | エセックス古河マグネットワイヤジャパン株式会社 | 絶縁電線、コイル、及び電気・電子機器 |
| EP3825345A1 (en) * | 2019-11-19 | 2021-05-26 | Arkema France | Improved powder for additive manufacturing |
| US20240254332A1 (en) * | 2020-06-11 | 2024-08-01 | Solvay Specialty Polymers Usa, Llc | Blends of poly(etherketoneketone) polymers |
| US20230331979A1 (en) * | 2020-06-11 | 2023-10-19 | Solvay Specialty Polymers Usa, Llc | Fiber reinforced thermoplastic matrix composite material |
| GB2600905A (en) | 2020-06-18 | 2022-05-18 | Victrex Mfg Ltd | Polymeric material and use thereof |
| US20230250230A1 (en) * | 2020-06-22 | 2023-08-10 | Solvay Specialty Polymers Usa, Llc | Reinforced paek compositions comprising recylced carbon fibers |
| EP4008742A1 (en) * | 2020-12-04 | 2022-06-08 | Arkema France | Pulverulent composition based on paek(s), sintering construction process and object derived therefrom |
| EP4271725A1 (en) * | 2020-12-30 | 2023-11-08 | Arkema France | Additive manufacturing process by extrusion of a poly-ether-ketone-ketone based composition |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3516966A (en) * | 1968-02-05 | 1970-06-23 | Du Pont | Polyketone copolymers |
| US4609714A (en) * | 1983-09-29 | 1986-09-02 | Union Carbide Corporation | Blends of poly(aryl ketones) |
| JPS61500021A (ja) * | 1983-09-29 | 1986-01-09 | アモコ、コ−ポレ−ション | ポリ（アリ−ルケトン）から成るブレンド |
| US4774296A (en) * | 1985-05-02 | 1988-09-27 | Amoco Corporation | Block polymers containing a poly(aryl ether ketone) and methods for their production |
| US4668744A (en) * | 1985-10-15 | 1987-05-26 | Amoco Corporation | Novel poly(aryl ether ketone) polyester block copolymers |
| US4959423A (en) | 1987-04-20 | 1990-09-25 | Amoco Corporation | Nucleating agents for poly(aryl ether ketones) |
| US4996287A (en) * | 1988-12-13 | 1991-02-26 | E. I. Du Pont De Nemours And Company | Thermoformable polyaryletherketone sheet |
| US5124413A (en) * | 1990-09-13 | 1992-06-23 | E. I. Du Pont De Nemours And Company | Films or sheets of blends of amorpous poly(aryl ether ketones) with polyarylates and laminates thereof |
| DE4039924A1 (de) * | 1990-12-14 | 1992-06-17 | Hoechst Ag | Legierungen aus teilkristallinen und amorphen polyaryletherketonen |
| EP2208207A4 (en) | 2007-11-02 | 2012-05-30 | Polymics Ltd | HIGH-TEMPERATURE PROTECTION STRUCTURE FOR SUBSTRATE |
| US9895842B2 (en) * | 2008-05-20 | 2018-02-20 | Eos Gmbh Electro Optical Systems | Selective sintering of structurally modified polymers |
| JP2010095615A (ja) * | 2008-10-16 | 2010-04-30 | Kaneka Corp | ポリエーテルエーテルケトン、それを含有する樹脂組成物、およびその成形体 |
| CN102361898B (zh) * | 2009-03-20 | 2014-09-24 | 阿科玛股份有限公司 | 聚醚酮酮非织造垫 |
| FR3027603B1 (fr) * | 2014-10-22 | 2016-11-18 | Arkema France | Composition a base de polyarylene-ether-cetone a proprietes ameliorees |
-
2014
- 2014-10-22 FR FR1460158A patent/FR3027603B1/fr active Active
-
2015
- 2015-10-09 ES ES15775727T patent/ES2711305T3/es active Active
- 2015-10-09 RU RU2017115887A patent/RU2677666C2/ru active
- 2015-10-09 BR BR112017007941-0A patent/BR112017007941B1/pt active IP Right Grant
- 2015-10-09 WO PCT/EP2015/073349 patent/WO2016062558A1/en not_active Ceased
- 2015-10-09 US US15/520,913 patent/US10150866B2/en active Active
- 2015-10-09 EP EP15189066.2A patent/EP3012297B2/en active Active
- 2015-10-09 CA CA2965371A patent/CA2965371C/en active Active
- 2015-10-09 CN CN201580062632.3A patent/CN107001787B/zh active Active
- 2015-10-09 MX MX2017005144A patent/MX2017005144A/es unknown
- 2015-10-09 EP EP15775727.9A patent/EP3209729B1/en active Active
- 2015-10-09 JP JP2017521508A patent/JP6505219B2/ja active Active
- 2015-10-09 ES ES15189066.2T patent/ES2638654T3/es active Active
- 2015-10-09 KR KR1020177013482A patent/KR101855054B1/ko active Active
- 2015-10-22 US US14/920,075 patent/US9624371B2/en active Active
-
2018
- 2018-11-29 US US16/204,290 patent/US20190203044A1/en not_active Abandoned
-
2019
- 2019-02-12 JP JP2019022785A patent/JP6823675B2/ja active Active
-
2022
- 2022-11-28 US US18/059,120 patent/US20230085897A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20190203044A1 (en) | 2019-07-04 |
| JP6505219B2 (ja) | 2019-04-24 |
| US20160115314A1 (en) | 2016-04-28 |
| JP6823675B2 (ja) | 2021-02-03 |
| WO2016062558A1 (en) | 2016-04-28 |
| CA2965371C (en) | 2019-08-06 |
| US10150866B2 (en) | 2018-12-11 |
| US9624371B2 (en) | 2017-04-18 |
| EP3209729A1 (en) | 2017-08-30 |
| EP3012297B2 (en) | 2020-08-26 |
| MX2017005144A (es) | 2017-07-24 |
| CN107001787A (zh) | 2017-08-01 |
| EP3012297B1 (en) | 2017-06-28 |
| US20230085897A1 (en) | 2023-03-23 |
| CN107001787B (zh) | 2019-08-02 |
| ES2711305T3 (es) | 2019-05-03 |
| JP2017531726A (ja) | 2017-10-26 |
| US20170335101A1 (en) | 2017-11-23 |
| CA2965371A1 (en) | 2016-04-28 |
| FR3027603B1 (fr) | 2016-11-18 |
| RU2017115887A (ru) | 2018-11-23 |
| BR112017007941A2 (pt) | 2017-12-19 |
| KR20170063961A (ko) | 2017-06-08 |
| RU2677666C2 (ru) | 2019-01-18 |
| KR101855054B1 (ko) | 2018-05-04 |
| JP2019112640A (ja) | 2019-07-11 |
| FR3027603A1 (fr) | 2016-04-29 |
| ES2638654T3 (es) | 2017-10-23 |
| EP3209729B1 (en) | 2018-07-11 |
| RU2017115887A3 (enExample) | 2018-11-23 |
| EP3012297A1 (en) | 2016-04-27 |
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