BR112015032403A2 - processo para produzir um tetraidrofurano-(thf)-2,5-dicarbaldeído, tetraidrofurano (thf)-2,5-dicarbaldeído, método para preparar um composto derivado furânico de um tetraidrofurano (thf)-2,5-dialdeído, composto derivado furânico transformado por oxidação, composto derivado furânico transformado por modificação de base de schiff, composto derivado furânico transformado por sulfonamidação, composto derivado furânico transformado por síntese de mono- e diacetais, composto derivado furânico transformado por aminação redutora, composto derivado furânico transformado por condensação aldólica, composto derivado furânico transformado por formação de oxima, e, composto derivado furânico - Google Patents
processo para produzir um tetraidrofurano-(thf)-2,5-dicarbaldeído, tetraidrofurano (thf)-2,5-dicarbaldeído, método para preparar um composto derivado furânico de um tetraidrofurano (thf)-2,5-dialdeído, composto derivado furânico transformado por oxidação, composto derivado furânico transformado por modificação de base de schiff, composto derivado furânico transformado por sulfonamidação, composto derivado furânico transformado por síntese de mono- e diacetais, composto derivado furânico transformado por aminação redutora, composto derivado furânico transformado por condensação aldólica, composto derivado furânico transformado por formação de oxima, e, composto derivado furânicoInfo
- Publication number
- BR112015032403A2 BR112015032403A2 BR112015032403A BR112015032403A BR112015032403A2 BR 112015032403 A2 BR112015032403 A2 BR 112015032403A2 BR 112015032403 A BR112015032403 A BR 112015032403A BR 112015032403 A BR112015032403 A BR 112015032403A BR 112015032403 A2 BR112015032403 A2 BR 112015032403A2
- Authority
- BR
- Brazil
- Prior art keywords
- transformed
- furan
- thf
- compound
- derivative
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/12—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/14—Radicals substituted by nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/20—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/22—Nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
Abstract
resumo processo para produzir um tetraidrofurano-(thf)- 2,5-dicarbaldeído, tetraidrofurano (thf)-2,5-dicarbaldeído, método para preparar um composto derivado furânico de um tetraidrofurano (thf)-2,5-dialdeído, composto derivado furânico transformado por oxidação, composto derivado furânico transformado por modificação de base de schiff, composto derivado furânico transformado por sulfonamidação, composto derivado furânico transformado por síntese de mono- e diacetais, composto derivado furânico transformado por aminação redutora, composto derivado furânico transformado por condensação aldólica, composto derivado furânico transformado por formação de oxima, e, composto derivado furânico tetraidrofurano-(thf)-2,5-dicarbaldeído e um processo para preparação do mesmo são descritos. o processo envolve reagir thf-dióis em um solvente orgânico inerte com um agente oxidante em uma temperatura de até cerca de 50 °c. o processo pode usar tanto hmf quanto thf-dióis como materiais de partida e permite uma conversão de etapa única de thf-dióis em um material precursor que pode ser transformado em uma multiplicidade de compostos derivados furânicos. thf-dicarbaldeído pode ser modificado de acordo com certos processos de reação para gerar compostos derivados tanto novos quanto existentes. 1/1
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361840896P | 2013-06-28 | 2013-06-28 | |
PCT/US2014/041665 WO2014209595A1 (en) | 2013-06-28 | 2014-06-10 | Tetrahydrofuran-2,5-dicarbaldehydes (diformyl-tetrahydrofuran, dfthf) and process for making the same |
Publications (1)
Publication Number | Publication Date |
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BR112015032403A2 true BR112015032403A2 (pt) | 2017-07-25 |
Family
ID=52142554
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015032403A BR112015032403A2 (pt) | 2013-06-28 | 2014-06-10 | processo para produzir um tetraidrofurano-(thf)-2,5-dicarbaldeído, tetraidrofurano (thf)-2,5-dicarbaldeído, método para preparar um composto derivado furânico de um tetraidrofurano (thf)-2,5-dialdeído, composto derivado furânico transformado por oxidação, composto derivado furânico transformado por modificação de base de schiff, composto derivado furânico transformado por sulfonamidação, composto derivado furânico transformado por síntese de mono- e diacetais, composto derivado furânico transformado por aminação redutora, composto derivado furânico transformado por condensação aldólica, composto derivado furânico transformado por formação de oxima, e, composto derivado furânico |
Country Status (10)
Country | Link |
---|---|
US (1) | US20160096813A1 (pt) |
EP (1) | EP3013145A4 (pt) |
JP (1) | JP2016528194A (pt) |
KR (1) | KR20160024938A (pt) |
CN (1) | CN105324030A (pt) |
AU (1) | AU2014303041A1 (pt) |
BR (1) | BR112015032403A2 (pt) |
CA (1) | CA2912915A1 (pt) |
MX (1) | MX2016000106A (pt) |
WO (1) | WO2014209595A1 (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2208774B2 (de) | 2004-07-02 | 2016-07-06 | Merck Patent GmbH | Flüssigkristallines Medium |
US20160304479A1 (en) * | 2013-12-19 | 2016-10-20 | Archer Daniels Midland Company | Sulfonates of furan-2,5-dimethanol and (tetrahydrofuran-2,5-diyl)dimethanol and derivatives thereof |
WO2017105985A1 (en) * | 2015-12-18 | 2017-06-22 | Archer Daniels Midland Company | Preparation of isohexide-3,6-dicarbaldehydes and isohexide-3,6-dimethanamines |
CN107474026B (zh) * | 2016-06-08 | 2020-08-04 | 中国科学院大连化学物理研究所 | 一种2,5-二氨甲基四氢呋喃的制备方法 |
CN107353267B (zh) * | 2017-07-19 | 2019-11-01 | 四川大学 | 一种合成取代呋喃的方法 |
DE102017008073A1 (de) * | 2017-08-28 | 2019-02-28 | Henkel Ag & Co. Kgaa | Neue anionische Tenside und Wasch- und Reinigungsmittel, welche diese enthalten |
US12024496B2 (en) | 2018-04-13 | 2024-07-02 | Archer-Daniels-Midland Company | Conversion of 1,2,5,6-hexanetetrol (HTO) to tetrahydrofuran dicarboxylic acid (THFDCA) |
WO2021165991A1 (en) * | 2020-02-19 | 2021-08-26 | Council Of Scientific And Industrial Research | Metal catalyst and hydrogen gas free approaches for selective reduction of aldehyde to methyl group of different substituted furans |
Family Cites Families (15)
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GB801169A (en) * | 1956-06-25 | 1958-09-10 | Olin Mathieson | Process for the preparation of 2 (alpha-aminoethyl)-furan and derivatives thereof |
GB946547A (en) * | 1960-03-03 | 1964-01-15 | Wolfen Filmfab Veb | Veterinary preparations for combating endoparasites by intravenous injection |
FR1593733A (pt) * | 1968-11-28 | 1970-06-01 | ||
US3855237A (en) * | 1973-06-14 | 1974-12-17 | Ici America Inc | Process of making hexahydro-1h-furo(3,4-c) pyrrole |
US5138076A (en) * | 1990-12-03 | 1992-08-11 | Great Lakes Chemical Corporation | Process for the preparation of 2-(2-bromo-2-nitroethenyl)furan |
WO2005023787A1 (en) * | 2003-09-10 | 2005-03-17 | Shasun Chemicals And Drugs Limited | Process for the manufacture of 2,1,3-benzoxadiazole-4-carboxaldehyde |
EP1740559B1 (en) * | 2004-04-20 | 2014-10-15 | Merck Sharp & Dohme Corp. | 1,3,5-substituted phenyl derivative compounds useful as beta-secretase inhibitors for the treatment of alzheimer's disease |
US7393963B2 (en) * | 2004-12-10 | 2008-07-01 | Archer-Daniels-Midland Company | Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor |
US7880049B2 (en) * | 2006-06-06 | 2011-02-01 | Wisconsin Alumni Research Foundation | Production of liquid alkanes in the jet fuel range (C8-C15) from biomass-derived carbohydrates |
WO2008113028A1 (en) * | 2007-03-14 | 2008-09-18 | Dynamic Food Ingredients Corporation | Compositions and processes for the selective catalytic oxidation of alcohols |
TR201908177T4 (tr) * | 2009-05-14 | 2019-06-21 | Archer Daniels Midland Co | Bir co(ıı) veya ce(ııı) katalizörü, bir bromür tuzu ve bir solvent varlığında 5-(alkiloksimetil)furfuralin (AMF) oksijen ile oksidasyonu aracılığıyla 2,5-furandikarboksilik asidin (FDCA) hazırlanışına yönelik proses. |
JP4916038B2 (ja) * | 2010-09-02 | 2012-04-11 | 独立行政法人産業技術総合研究所 | フラン類の水素化反応によるテトラヒドロフラン誘導体の製造方法 |
CA2992861C (en) * | 2010-12-16 | 2019-03-05 | Archer Daniels Midland Company | Preparation of aminomethyl furan and alkoxymethyl furan derivatives from carbohydrates |
WO2014121513A1 (en) * | 2013-02-08 | 2014-08-14 | Rhodia Operations | Oxydation of alcohol compounds via mesostructured vpo catalysts |
CN104981462B (zh) * | 2013-02-08 | 2018-09-04 | 罗地亚经营管理公司 | 通过介观结构的vpo催化剂氧化醇化合物 |
-
2014
- 2014-06-10 WO PCT/US2014/041665 patent/WO2014209595A1/en active Application Filing
- 2014-06-10 BR BR112015032403A patent/BR112015032403A2/pt not_active IP Right Cessation
- 2014-06-10 EP EP14817897.3A patent/EP3013145A4/en not_active Withdrawn
- 2014-06-10 AU AU2014303041A patent/AU2014303041A1/en not_active Abandoned
- 2014-06-10 KR KR1020167001740A patent/KR20160024938A/ko not_active Application Discontinuation
- 2014-06-10 CN CN201480035666.9A patent/CN105324030A/zh active Pending
- 2014-06-10 US US14/892,072 patent/US20160096813A1/en not_active Abandoned
- 2014-06-10 JP JP2016523764A patent/JP2016528194A/ja not_active Withdrawn
- 2014-06-10 MX MX2016000106A patent/MX2016000106A/es unknown
- 2014-06-10 CA CA2912915A patent/CA2912915A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US20160096813A1 (en) | 2016-04-07 |
JP2016528194A (ja) | 2016-09-15 |
CN105324030A (zh) | 2016-02-10 |
CA2912915A1 (en) | 2014-12-31 |
KR20160024938A (ko) | 2016-03-07 |
EP3013145A4 (en) | 2017-01-25 |
WO2014209595A1 (en) | 2014-12-31 |
MX2016000106A (es) | 2016-03-01 |
AU2014303041A1 (en) | 2015-12-10 |
EP3013145A1 (en) | 2016-05-04 |
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