BR112012014347A2 - processo de epoxidação e microestrutura - Google Patents

processo de epoxidação e microestrutura

Info

Publication number
BR112012014347A2
BR112012014347A2 BR112012014347A BR112012014347A BR112012014347A2 BR 112012014347 A2 BR112012014347 A2 BR 112012014347A2 BR 112012014347 A BR112012014347 A BR 112012014347A BR 112012014347 A BR112012014347 A BR 112012014347A BR 112012014347 A2 BR112012014347 A2 BR 112012014347A2
Authority
BR
Brazil
Prior art keywords
hours
temperature
microstructure
epoxidation
epoxidation process
Prior art date
Application number
BR112012014347A
Other languages
English (en)
Inventor
Anding Zhang
Andrzej Rokicki
Harald Dialer
Original Assignee
Scient Design Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scient Design Co filed Critical Scient Design Co
Publication of BR112012014347A2 publication Critical patent/BR112012014347A2/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04Alkali metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • B01J23/36Rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

processo de epoxidação e microestrutura. um método para a partida de um processo para a epoxidação de etileno compreendendo: iniciar uma reação de epoxidação mediante reagir uma composição de gás de alimentação contendo etileno e oxigênio, na presença de um catalisador de epoxidação a uma temperatura de cerca de 180 <198>c a cerca de 210 <198>c, adicionar à composição do gás de alimentação de cerca de 0,05 ppm até cerca de 2 ppm de moderador; aumentar a primeira temperatura até uma segunda temperatura de cerca de 240 <198>c a cerca de 250 <198>c, ao longo de um período de tempo de cerca de 12 horas até cerca de 60 horas; e manter a segunda temperatura por um período de tempo de cerca de 50 horas até cerca de 150 horas.
BR112012014347A 2009-12-23 2010-12-20 processo de epoxidação e microestrutura BR112012014347A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/646,221 US20110152073A1 (en) 2009-12-23 2009-12-23 Epoxidation process and microstructure
PCT/US2010/061224 WO2011079060A2 (en) 2009-12-23 2010-12-20 Epoxidation process and microstructure

Publications (1)

Publication Number Publication Date
BR112012014347A2 true BR112012014347A2 (pt) 2016-08-09

Family

ID=44151912

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012014347A BR112012014347A2 (pt) 2009-12-23 2010-12-20 processo de epoxidação e microestrutura

Country Status (11)

Country Link
US (1) US20110152073A1 (pt)
EP (1) EP2516057A4 (pt)
JP (1) JP2013515598A (pt)
KR (1) KR20120112640A (pt)
CN (1) CN102665898B (pt)
BR (1) BR112012014347A2 (pt)
CA (1) CA2784609A1 (pt)
IN (1) IN2012DN05166A (pt)
MX (1) MX2012007447A (pt)
TW (1) TW201138960A (pt)
WO (1) WO2011079060A2 (pt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN2012DN05178A (pt) * 2009-12-17 2015-10-23 Scient Design Co
US9018126B2 (en) * 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
EP2938435A4 (en) * 2012-12-31 2016-10-05 Scient Design Co CALCINATION PROCESS FOR PREPARING AN IMPROVED ETHYLENE OXIDE CATALYST
WO2014105770A1 (en) 2012-12-31 2014-07-03 Scientific Design Company, Inc. Start-up process for high selectivity ethylene oxide catalysts
CN105122613B (zh) * 2013-02-01 2019-09-13 Ksb 股份公司 转子、磁阻机器以及转子的制造方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4874879A (en) * 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
EP0357293B1 (en) * 1988-08-30 1996-02-28 Union Carbide Corporation Catalysts for the production of ethylene oxide and their preparation processes
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5155242A (en) * 1991-12-05 1992-10-13 Shell Oil Company Process for starting-up an ethylene oxide reactor
US5407888A (en) * 1992-05-12 1995-04-18 Basf Aktiengesellschaft Silver catalyst
JP3923289B2 (ja) * 2000-08-24 2007-05-30 株式会社日本触媒 酸化エチレン製造用触媒の担体、その担体を用いた酸化エチレンの製造用触媒及び酸化エチレンの製造方法
US7193094B2 (en) * 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
DE60332457D1 (de) 2002-06-28 2010-06-17 Shell Int Research Verfahren zur verbesserung der selektivität eines katalysators und verfahren zum epoxidieren eines olefins
MY153179A (en) 2003-02-28 2015-01-29 Shell Int Research A method of manufacturing ethylene oxide
RU2342993C2 (ru) * 2003-05-07 2009-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализаторы, содержащие серебро, получение таких катализаторов и их применение
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
US8791280B2 (en) * 2005-08-10 2014-07-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of catalyst carrier and its use in catalyst preparation
JP4978277B2 (ja) * 2006-04-10 2012-07-18 三菱化学株式会社 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst
IN2012DN05178A (pt) 2009-12-17 2015-10-23 Scient Design Co

Also Published As

Publication number Publication date
IN2012DN05166A (pt) 2015-10-23
WO2011079060A2 (en) 2011-06-30
WO2011079060A3 (en) 2011-10-20
EP2516057A2 (en) 2012-10-31
TW201138960A (en) 2011-11-16
CN102665898A (zh) 2012-09-12
JP2013515598A (ja) 2013-05-09
KR20120112640A (ko) 2012-10-11
US20110152073A1 (en) 2011-06-23
CN102665898B (zh) 2015-09-09
CA2784609A1 (en) 2011-06-30
RU2012131338A (ru) 2014-01-27
EP2516057A4 (en) 2014-01-08
MX2012007447A (es) 2012-07-30

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2384 DE 13-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.