BR112015027368A2 - método para fabricação de pla com o uso de um novo catalisador de polimerização - Google Patents
método para fabricação de pla com o uso de um novo catalisador de polimerizaçãoInfo
- Publication number
- BR112015027368A2 BR112015027368A2 BR112015027368A BR112015027368A BR112015027368A2 BR 112015027368 A2 BR112015027368 A2 BR 112015027368A2 BR 112015027368 A BR112015027368 A BR 112015027368A BR 112015027368 A BR112015027368 A BR 112015027368A BR 112015027368 A2 BR112015027368 A2 BR 112015027368A2
- Authority
- BR
- Brazil
- Prior art keywords
- polymerization catalyst
- polylactide
- metal
- catalyst
- kinetics
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000002685 polymerization catalyst Substances 0.000 title abstract 3
- 229920000747 poly(lactic acid) Polymers 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000011230 binding agent Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000005474 octanoate group Chemical group 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
- C08G18/428—Lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
- C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
resumo patente de invenção: "método para fabricação de pla com o uso de um novo catalisador de polimerização" a invenção refere-se a um método para fabricar polilactídeo, que compreende as etapas de misturar lactídeo e um composto de coordenação de metal como catalisador de polimerização para obter uma mistura de reação, polimerizar o lactídeo na fase líquida em uma temperatura de ao menos 150 °c para formar polilactídeo na fase líquida e permitir que o polilactídeo se solidifique, distinguido pelo fato de que o catalisador de polimerização compreende um composto de coordenação de metal-ligante através do qual o ligante parental satisfaz a fórmula (i), em que r representa um átomo de h, um grupo alifático, um átomo de haleto ou um grupo nitro e o metal é pelo menos um dentre zr e hf os catalisadores inventados mostram uma cinética que é comparável à cinética do catalisador de octoato de sn conhecido.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13166273.6 | 2013-05-02 | ||
| EP13166273.6A EP2799462A1 (en) | 2013-05-02 | 2013-05-02 | Method to manufacture PLA using a new polymerization catalyst |
| PCT/EP2014/058688 WO2014177543A1 (en) | 2013-05-02 | 2014-04-29 | Method to manufacture pla using a new polymerization catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015027368A2 true BR112015027368A2 (pt) | 2017-09-12 |
| BR112015027368B1 BR112015027368B1 (pt) | 2020-08-18 |
Family
ID=48193185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015027368-8A BR112015027368B1 (pt) | 2013-05-02 | 2014-04-29 | Método para fabricaçãode polilactídeo, uso de um composto de coordenação de metal e polilactídeo |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9957350B2 (pt) |
| EP (2) | EP2799462A1 (pt) |
| JP (1) | JP6100970B2 (pt) |
| KR (1) | KR101786841B1 (pt) |
| CN (2) | CN111690125A (pt) |
| AU (1) | AU2014261472B2 (pt) |
| BR (1) | BR112015027368B1 (pt) |
| CA (1) | CA2910710C (pt) |
| EA (1) | EA026866B1 (pt) |
| ES (1) | ES2728002T3 (pt) |
| MX (1) | MX2015015233A (pt) |
| MY (1) | MY179335A (pt) |
| NZ (1) | NZ713759A (pt) |
| PH (1) | PH12015502492A1 (pt) |
| SG (1) | SG11201508918VA (pt) |
| WO (1) | WO2014177543A1 (pt) |
| ZA (1) | ZA201508152B (pt) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3103348A1 (en) * | 2018-06-26 | 2020-01-02 | Total Corbion Pla Bv | Process for the preparation of lactide and polylactide mixture |
| CN109734880B (zh) * | 2018-12-14 | 2021-06-01 | 泰山医学院 | 利用双核手性胺亚胺镁配合物催化丙交酯聚合的方法 |
| KR20220043074A (ko) | 2019-06-03 | 2022-04-05 | 토탈 콜비온 피엘에이 비.브이. | 안정화된 지방족 폴리에스테르를 제조하기 위한 공정 및 이에 의해 수득된 조성물 |
| CN114729111B (zh) * | 2019-11-15 | 2024-05-28 | 道达尔能源科碧恩私人有限公司 | 用于使用液体催化剂配方聚合丙交酯的工艺 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050009687A1 (en) | 2003-05-02 | 2005-01-13 | Verkade John G. | Titanium alkoxide catalysts for polymerization of cyclic esters and methods of polymerization |
| TWI276642B (en) * | 2005-07-22 | 2007-03-21 | Chien-Tien Chen | Nucleophilic acyl substituting polymerizations catalyzed by metal oxide complex |
| GB0522154D0 (en) * | 2005-10-31 | 2005-12-07 | Univ Leeds | Novel catalytic materials and their use in the preparation of polymeric materials |
| AT506038B1 (de) * | 2007-11-14 | 2015-02-15 | Jungbunzlauer Austria Ag | Verfahren zur herstellung zyklischer diester von l-, d- und d,l-milchsäure |
| US20090247710A1 (en) * | 2008-03-31 | 2009-10-01 | Purac Biochem B.V. | Method for manufacturing stable polylactide |
| ATE551376T1 (de) | 2008-03-31 | 2012-04-15 | Purac Biochem Bv | Verfahren zur herstellung von stabilem polylactid |
| CN102300904A (zh) * | 2009-01-30 | 2011-12-28 | 大曹株式会社 | 制造聚乳酸的方法 |
| CN103380135B (zh) * | 2010-12-10 | 2016-08-31 | 科莱恩金融(Bvi)有限公司 | 用于内酯类开环聚合的基于n-杂环卡宾的锆络合物 |
| JP5763402B2 (ja) * | 2011-04-22 | 2015-08-12 | 株式会社クレハ | 生分解性脂肪族ポリエステル粒子、及びその製造方法 |
| JP5676370B2 (ja) * | 2011-06-06 | 2015-02-25 | 株式会社クレハ | 脂肪族ポリエステルの製造方法及び製造装置 |
-
2013
- 2013-05-02 EP EP13166273.6A patent/EP2799462A1/en not_active Withdrawn
-
2014
- 2014-04-29 WO PCT/EP2014/058688 patent/WO2014177543A1/en active Application Filing
- 2014-04-29 BR BR112015027368-8A patent/BR112015027368B1/pt active IP Right Grant
- 2014-04-29 ES ES14721811T patent/ES2728002T3/es active Active
- 2014-04-29 US US14/888,460 patent/US9957350B2/en active Active
- 2014-04-29 MX MX2015015233A patent/MX2015015233A/es unknown
- 2014-04-29 EP EP14721811.9A patent/EP2992029B1/en active Active
- 2014-04-29 SG SG11201508918VA patent/SG11201508918VA/en unknown
- 2014-04-29 CN CN202010749602.2A patent/CN111690125A/zh active Pending
- 2014-04-29 CN CN201480031589.XA patent/CN105518052A/zh active Pending
- 2014-04-29 MY MYPI2015002675A patent/MY179335A/en unknown
- 2014-04-29 KR KR1020157033902A patent/KR101786841B1/ko active IP Right Grant
- 2014-04-29 EA EA201591984A patent/EA026866B1/ru not_active IP Right Cessation
- 2014-04-29 AU AU2014261472A patent/AU2014261472B2/en active Active
- 2014-04-29 NZ NZ713759A patent/NZ713759A/en unknown
- 2014-04-29 CA CA2910710A patent/CA2910710C/en active Active
- 2014-04-29 JP JP2016511037A patent/JP6100970B2/ja active Active
-
2015
- 2015-10-29 PH PH12015502492A patent/PH12015502492A1/en unknown
- 2015-11-04 ZA ZA2015/08152A patent/ZA201508152B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR101786841B1 (ko) | 2017-10-18 |
| EP2992029A1 (en) | 2016-03-09 |
| SG11201508918VA (en) | 2015-11-27 |
| BR112015027368B1 (pt) | 2020-08-18 |
| MY179335A (en) | 2020-11-04 |
| CN111690125A (zh) | 2020-09-22 |
| PH12015502492B1 (en) | 2016-02-22 |
| PH12015502492A1 (en) | 2016-02-22 |
| KR20160003175A (ko) | 2016-01-08 |
| CA2910710A1 (en) | 2014-11-06 |
| CA2910710C (en) | 2019-01-22 |
| ZA201508152B (en) | 2017-08-30 |
| AU2014261472A1 (en) | 2015-12-10 |
| US9957350B2 (en) | 2018-05-01 |
| JP2016516872A (ja) | 2016-06-09 |
| CN105518052A (zh) | 2016-04-20 |
| MX2015015233A (es) | 2016-06-02 |
| EA026866B1 (ru) | 2017-05-31 |
| WO2014177543A1 (en) | 2014-11-06 |
| EA201591984A1 (ru) | 2016-05-31 |
| ES2728002T3 (es) | 2019-10-21 |
| EP2799462A1 (en) | 2014-11-05 |
| AU2014261472B2 (en) | 2017-04-06 |
| US20160075821A1 (en) | 2016-03-17 |
| NZ713759A (en) | 2017-01-27 |
| EP2992029B1 (en) | 2019-03-13 |
| JP6100970B2 (ja) | 2017-03-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 29/04/2014, OBSERVADAS AS CONDICOES LEGAIS. |