BR112015006495A2 - processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação - Google Patents

processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação

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Publication number
BR112015006495A2
BR112015006495A2 BR112015006495A BR112015006495A BR112015006495A2 BR 112015006495 A2 BR112015006495 A2 BR 112015006495A2 BR 112015006495 A BR112015006495 A BR 112015006495A BR 112015006495 A BR112015006495 A BR 112015006495A BR 112015006495 A2 BR112015006495 A2 BR 112015006495A2
Authority
BR
Brazil
Prior art keywords
reaction fluid
stabilizing
degradation
hydroformylation reaction
phosphite
Prior art date
Application number
BR112015006495A
Other languages
English (en)
Other versions
BR112015006495B1 (pt
Inventor
A Miller Glenn
A Brammer Michael
B Watson Rick
C Eisenschmid Thomas
Original Assignee
Dow Technology Investments Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Technology Investments Llc filed Critical Dow Technology Investments Llc
Publication of BR112015006495A2 publication Critical patent/BR112015006495A2/pt
Publication of BR112015006495B1 publication Critical patent/BR112015006495B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

resumo “processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação” um processo para estabilizar um ligante fosfito contra degradação num fluido de reação de hidroformilação, o dito processo compreendendo adicionar um epóxido ao fluido de reação, e compreendendo ainda separar um ou mais compostos ácidos de fósforo do fluido de reação tratando o fluido de reação com uma solução aquosa de tampão em condições suficientes para neutralizar e remover pelo menos alguma quantidade dos compostos ácidos de fósforo do fluido de reação. 1/1
BR112015006495-7A 2012-09-25 2013-09-09 Processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação BR112015006495B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261705194P 2012-09-25 2012-09-25
US61/705,194 2012-09-25
PCT/US2013/058714 WO2014051975A1 (en) 2012-09-25 2013-09-09 Process for stabilizing a phosphite ligand against degradation

Publications (2)

Publication Number Publication Date
BR112015006495A2 true BR112015006495A2 (pt) 2017-07-04
BR112015006495B1 BR112015006495B1 (pt) 2020-12-15

Family

ID=49170945

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015006495-7A BR112015006495B1 (pt) 2012-09-25 2013-09-09 Processo para estabilizar um ligante de fosfito contra degradação num fluido de reação de hidroformilação

Country Status (13)

Country Link
US (1) US9328047B2 (pt)
EP (1) EP2900373B1 (pt)
JP (1) JP6068652B2 (pt)
KR (1) KR102111182B1 (pt)
CN (1) CN104955568B (pt)
BR (1) BR112015006495B1 (pt)
IN (1) IN2015DN02639A (pt)
MX (1) MX2015003905A (pt)
MY (1) MY176756A (pt)
PL (1) PL2900373T3 (pt)
RU (1) RU2639156C2 (pt)
WO (1) WO2014051975A1 (pt)
ZA (1) ZA201502223B (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3143031B1 (en) 2014-05-14 2020-11-04 Dow Technology Investments LLC Stabilized organophosphorous compounds
TWI709568B (zh) * 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
CN105498855A (zh) * 2015-12-08 2016-04-20 中国海洋石油总公司 提高醚后c4羰基合成反应铑-双膦催化剂稳定性的方法
RU2751511C9 (ru) 2016-02-11 2021-08-18 Дау Текнолоджи Инвестментс Ллк Способы превращения олефинов в спирты, простые эфиры или их комбинации
CN109535197B (zh) * 2018-12-19 2020-04-21 山东新和成维生素有限公司 一种稳定亚磷酸盐配体的方法及其应用
SE543296C2 (en) * 2019-07-05 2020-11-17 Perstorp Ab A use of epoxide in order to reduce the formation of heavy ends in a hydroformylation process
EP3994119A4 (en) * 2019-07-05 2023-07-26 Perstorp AB METHOD OF REDUCING HEAVYEND FORMATION AND CATALYST LOSS IN A HYDROFORMYLATION PROCESS
WO2021126421A1 (en) 2019-12-19 2021-06-24 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms

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Also Published As

Publication number Publication date
EP2900373A1 (en) 2015-08-05
KR102111182B1 (ko) 2020-05-14
PL2900373T3 (pl) 2019-09-30
CN104955568A (zh) 2015-09-30
KR20150060714A (ko) 2015-06-03
IN2015DN02639A (pt) 2015-09-18
EP2900373B1 (en) 2019-04-17
MX2015003905A (es) 2015-07-17
CN104955568B (zh) 2017-05-03
ZA201502223B (en) 2017-01-25
US9328047B2 (en) 2016-05-03
JP2015530407A (ja) 2015-10-15
JP6068652B2 (ja) 2017-01-25
RU2015115493A (ru) 2016-11-20
US20150232403A1 (en) 2015-08-20
BR112015006495B1 (pt) 2020-12-15
WO2014051975A1 (en) 2014-04-03
MY176756A (en) 2020-08-21
RU2639156C2 (ru) 2017-12-20

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