BR112015019799A2 - material híbrido orgânico-inorgânico, uso de um material híbrido orgânico-inorgânico e processo de recuperação do urânio(vi) - Google Patents

material híbrido orgânico-inorgânico, uso de um material híbrido orgânico-inorgânico e processo de recuperação do urânio(vi)

Info

Publication number
BR112015019799A2
BR112015019799A2 BR112015019799A BR112015019799A BR112015019799A2 BR 112015019799 A2 BR112015019799 A2 BR 112015019799A2 BR 112015019799 A BR112015019799 A BR 112015019799A BR 112015019799 A BR112015019799 A BR 112015019799A BR 112015019799 A2 BR112015019799 A2 BR 112015019799A2
Authority
BR
Brazil
Prior art keywords
organic
hybrid material
inorganic
group
inorganic hybrid
Prior art date
Application number
BR112015019799A
Other languages
English (en)
Other versions
BR112015019799B1 (pt
Inventor
Grandjean Agnès
Goettmann Frédéric
Arrachart Guilhem
Turgis Raphaël
El Mourabit Sabah
Pellet-Rostaing Stéphane
Original Assignee
Centre Nat Rech Scient
Commissariat Energie Atomique
Univ Montpellier 2 Sciences Et Techniques
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre Nat Rech Scient, Commissariat Energie Atomique, Univ Montpellier 2 Sciences Et Techniques filed Critical Centre Nat Rech Scient
Publication of BR112015019799A2 publication Critical patent/BR112015019799A2/pt
Publication of BR112015019799B1 publication Critical patent/BR112015019799B1/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3251—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B01J20/3219—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond involving a particular spacer or linking group, e.g. for attaching an active group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • B01J20/3259—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulfur with at least one silicon atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0265—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries extraction by solid resins
    • C22B60/0269—Extraction by activated carbon containing adsorbents
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0265—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries extraction by solid resins
    • C22B60/0273—Extraction by titanium containing adsorbents, e.g. by hydrous titanium oxide
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0278—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries by chemical methods
    • C22B60/0282—Solutions containing P ions, e.g. treatment of solutions resulting from the leaching of phosphate ores or recovery of uranium from wet-process phosphoric acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Nanotechnology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

resumo “material híbrido orgânico-inorgânico, uso de um material híbrido orgânico-inorgânico e processo de recuperação do urânio(vi)” a presente invenção trata de um material híbrido orgânico-inorgânico que compreende um suporte sólido inorgânico sobre o qual são enxertadas das moléculas orgânicas de fórmula geral (i) a seguir na qual: x, y e z = 0 ou 1, com pelo menos um de x, y e z diferente de 0; m = 1 a 6; v e w = 0 ou 1, com v = 1 quando w = 0, e v = 0 quando w = 1; se x = 0, r1 = h ou um grupo hidrocarbonado, saturado ou insaturado, linear ou ramificado, com c1 a c12, ao passo que, se x = 1, r1 = um grupo ligado ao suporte sólido inorgânico por pelo menos uma ligação covalente; se y = 0, r2 = h ou um grupo hidrocarbonado, saturado ou insaturado, linear ou ramificado, com c1 a c12, ao passo que, se y = 1, r2 = um grupo ligado ao suporte sólido inorgânico por pelo menos uma ligação covalente; se z = 0, r3 = h ou um grupo hidrocarbonado, saturado ou insaturado, linear ou ramificado, com c1 a c12, ao passo que, se z = 1, r3 = um grupo ligado ao suporte sólido inorgânico por pelo menos uma ligação covalente; r4 e r5 = h, um grupo hidrocarbonado, saturado ou insaturado, linear ou ramificado, com c2 a c8, ou um grupo aromático monocíclico. ela trata também dos processos que permitem preparar esse material híbrido bem como dos usos do referido material para extrair o urânio (vi) de um meio aquoso que compreende ácido fosfórico. aplicações: tratamento dos fosfatos naturais.
BR112015019799-0A 2013-02-25 2013-11-08 Material híbrido orgânico-inorgânico, uso de um material híbrido orgânico-inorgânico e processo de recuperação do urânio(vi) BR112015019799B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1351639 2013-02-25
FR1351639A FR3002463B1 (fr) 2013-02-25 2013-02-25 Materiau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux contenant de l'acide phosphorique, ses procedes de preparation et ses utilisations
PCT/EP2013/073429 WO2014127860A1 (fr) 2013-02-25 2013-11-08 Matériau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, ses procédés de préparation et ses utilisations

Publications (2)

Publication Number Publication Date
BR112015019799A2 true BR112015019799A2 (pt) 2017-07-18
BR112015019799B1 BR112015019799B1 (pt) 2022-03-08

Family

ID=48140081

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015019799-0A BR112015019799B1 (pt) 2013-02-25 2013-11-08 Material híbrido orgânico-inorgânico, uso de um material híbrido orgânico-inorgânico e processo de recuperação do urânio(vi)

Country Status (7)

Country Link
US (1) US10130932B2 (pt)
AU (1) AU2013379406B2 (pt)
BR (1) BR112015019799B1 (pt)
FR (1) FR3002463B1 (pt)
MA (1) MA38371B1 (pt)
TN (1) TN2015000334A1 (pt)
WO (1) WO2014127860A1 (pt)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3013059B1 (fr) * 2013-11-08 2016-01-01 Commissariat Energie Atomique Utilisation d'un materiau hybride organique-inorganique pour extraire l'uranium(vi) d'une solution aqueuse d'acide sulfurique, issue notamment de la lixiviation sulfurique d'un minerai uranifere
FR3014336B1 (fr) 2013-12-05 2016-01-22 Commissariat Energie Atomique Utilisation d'un gel alcalin oxydant pour eliminer un biofilm sur une surface d'un substrat solide.
FR3025115B1 (fr) 2014-09-03 2018-12-07 Commissariat A L'energie Atomique Et Aux Energies Alternatives Procede d'extraction selectif de platinoides, a partir d'un support les contenant, avec un milieu d'extraction comprenant un fluide supercritique et un ligand organique.
FR3025799B1 (fr) 2014-09-12 2016-10-14 Commissariat Energie Atomique Procede de preparation d'un materiau solide nanocomposite a base d'hexa- et octacyanometallates de metaux alcalins.
FR3034417B1 (fr) 2015-04-03 2019-03-15 Commissariat A L'energie Atomique Et Aux Energies Alternatives Composes a fonctions oxyde de phosphine et amine, utiles comme ligands de l'uranium(vi), et leurs utilisations, notamment pour extraire l'uranium(vi) de solutions aqueuses d'acide sulfurique
FR3044006B1 (fr) * 2015-11-19 2020-03-06 Orano Mining Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique
FR3044018B1 (fr) 2015-11-19 2017-12-22 Areva Mines Procedes d'extraction et de recuperation de l'uranium present dans une solution aqueuse comprenant de l'acide phosphorique
FR3060006B1 (fr) 2016-12-13 2020-02-28 Orano Mining Materiau organique mesoporeux, utile notamment pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, et ses utilisations
CN107163079B (zh) * 2017-05-09 2019-07-16 凯莱英生命科学技术(天津)有限公司 一种烃基膦酸酯的制备方法
EP3441396A1 (en) * 2017-08-07 2019-02-13 Université de Montpellier Method for separating uranium and/or thorium
DE102018005069A1 (de) 2018-06-26 2020-01-02 Skw Stickstoffwerke Piesteritz Gmbh Verfahren zur Herstellung von harnstoffbasierten Düngemitteln mit elementaren Schwefel und Produkte davon

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4396556A (en) * 1981-03-02 1983-08-02 Occidental Research Corporation Process of preparing organophosphorus compounds by phase transfer catalysis
IL69384A0 (en) 1983-08-01 1983-11-30 Israel Atomic Energy Comm Recovery of uranium from wet process phosphoric acid by liquid-solid ion exchange
FR2896705B1 (fr) 2006-01-30 2008-12-05 Commissariat Energie Atomique Procede de separation en milieu aqueux d'au moins un element actinide d'elements lanthanides par complexation et filtration membranaire
US8343450B2 (en) * 2007-10-09 2013-01-01 Chemnano Materials, Ltd. Functionalized carbon nanotubes, recovery of radionuclides and separation of actinides and lanthanides
US8357628B2 (en) * 2008-08-29 2013-01-22 Agilent Technologies, Inc. Inorganic/organic hybrid totally porous metal oxide particles, methods for making them and separation devices using them
EP3964287A1 (en) * 2009-06-01 2022-03-09 Waters Technologies Corporation Hybrid material for chromatographic separations
US20110110985A1 (en) * 2009-11-06 2011-05-12 Battelle Memorial Institute Functionalized nanomaterials for chelation therapies and sorbent dialysis of toxins
FR2990206B1 (fr) 2012-05-07 2014-06-06 Commissariat Energie Atomique Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations

Also Published As

Publication number Publication date
BR112015019799B1 (pt) 2022-03-08
US10130932B2 (en) 2018-11-20
WO2014127860A1 (fr) 2014-08-28
TN2015000334A1 (fr) 2017-01-03
MA38371A1 (fr) 2016-09-30
FR3002463A1 (fr) 2014-08-29
US20160016150A1 (en) 2016-01-21
AU2013379406B2 (en) 2017-03-09
MA38371B1 (fr) 2017-04-28
FR3002463B1 (fr) 2016-08-19
AU2013379406A1 (en) 2015-09-03

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B15K Others concerning applications: alteration of classification

Free format text: AS CLASSIFICACOES ANTERIORES ERAM: B01J 45/00 , B01J 20/32 , C22B 60/02 , B01J 20/28 , C02F 101/00

Ipc: C22B 60/02 (1974.07), B01J 20/32 (1980.01), C02F 1

B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 08/11/2013, OBSERVADAS AS CONDICOES LEGAIS.