BR112013009717B1 - Estrutura da película de múltiplas camadas refechável fácil de descascar para aplicação de vedação por calor. - Google Patents
Estrutura da película de múltiplas camadas refechável fácil de descascar para aplicação de vedação por calor. Download PDFInfo
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- BR112013009717B1 BR112013009717B1 BR112013009717-5A BR112013009717A BR112013009717B1 BR 112013009717 B1 BR112013009717 B1 BR 112013009717B1 BR 112013009717 A BR112013009717 A BR 112013009717A BR 112013009717 B1 BR112013009717 B1 BR 112013009717B1
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- C—CHEMISTRY; METALLURGY
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Applications Claiming Priority (3)
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| EP10188301.5 | 2010-10-21 | ||
| EP10188301 | 2010-10-21 | ||
| PCT/EP2011/068177 WO2012052429A1 (en) | 2010-10-21 | 2011-10-18 | Pressure sensitive adhesive with butene-1 copolymers |
Publications (2)
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| BR112013009717A2 BR112013009717A2 (pt) | 2016-07-19 |
| BR112013009717B1 true BR112013009717B1 (pt) | 2020-03-31 |
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Country Status (7)
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| US (1) | US9284475B2 (enExample) |
| EP (1) | EP2630211B1 (enExample) |
| JP (1) | JP6005649B2 (enExample) |
| KR (1) | KR101958495B1 (enExample) |
| CN (1) | CN103154176B (enExample) |
| BR (1) | BR112013009717B1 (enExample) |
| WO (1) | WO2012052429A1 (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP2810773A1 (en) * | 2013-06-05 | 2014-12-10 | Basell Poliolefine Italia S.r.l. | Butene-1 copolymer tie layer in multilayer film structures having a low seal temperature and improved hot tack |
| CN104870569B (zh) * | 2013-09-24 | 2018-06-29 | Lg化学株式会社 | 压敏粘合剂组合物 |
| US20170029670A1 (en) * | 2013-11-25 | 2017-02-02 | Basell Poliolefine Italia S.R.L. | Polyolefin based hot melt adhesive composition |
| JP6326253B2 (ja) * | 2014-03-13 | 2018-05-16 | 三井化学株式会社 | ホットメルト用接着剤組成物 |
| ES2768850T3 (es) | 2015-01-23 | 2020-06-23 | Bostik Inc | Adhesivo termofusible de termosellado a baja temperatura de activación basado en poliolefina de metaloceno |
| CA2974136C (en) * | 2015-02-16 | 2019-05-21 | Intercontinental Great Brands Llc | Multi-layer film and reclosable film package |
| PL3260512T3 (pl) * | 2016-06-20 | 2021-08-23 | Henkel Ag & Co. Kgaa | Wytłaczalny klej samoprzylepny na bazie polibutenu-1 odpowiedni do opakowań do ponownego zamykania |
| PL3266824T3 (pl) * | 2016-07-07 | 2022-05-09 | Basell Poliolefine Italia S.R.L. | Kompozycja polimerowa butenu-1 o wysokim wskaźniku szybkości płynięcia |
| EP3266825B1 (en) | 2016-07-07 | 2022-03-09 | Basell Poliolefine Italia S.r.l. | Butene-1 polymer composition having a high melt flow rate |
| BR112019000211A2 (pt) * | 2016-07-07 | 2019-07-09 | Savare I C S R L | formulação de adesivo de colagem a quente, estrutura unida, e, artigo higiênico absorvente. |
| IT201700030594A1 (it) * | 2017-03-20 | 2018-09-20 | Savare I C S R L | Adesivi termofusibili applicabili con processi ad alta velocita' |
| ES2749111T3 (es) | 2016-11-22 | 2020-03-19 | Henkel Ag & Co Kgaa | Adhesivo sensible a presión extruible basado en polímero de polibuteno-1 y un copolímero de estireno adecuado para embalajes recuperables |
| CN110891978A (zh) * | 2017-08-04 | 2020-03-17 | 巴塞尔聚烯烃意大利有限公司 | 具有高熔体流动速率的丁烯-1聚合物组合物 |
| JP2019038965A (ja) * | 2017-08-28 | 2019-03-14 | 住友化学株式会社 | 接着剤 |
| WO2019132523A1 (ko) * | 2017-12-27 | 2019-07-04 | 에스케이이노베이션 주식회사 | 중합체 조성물, 이를 포함하는 수지 조성물 및 중합체 조성물의 제조방법 |
| KR102623485B1 (ko) * | 2017-12-27 | 2024-01-10 | 에스케이이노베이션 주식회사 | 중합체 조성물, 이를 포함하는 수지 조성물 및 중합체 조성물의 제조방법 |
| EP3757162A1 (en) | 2019-06-24 | 2020-12-30 | Sika Technology Ag | Thermoplastic polymer compositions with improved flexibility |
| EP3819317A1 (en) * | 2019-11-07 | 2021-05-12 | Sika Technology Ag | Waterproofing membrane with a self-healing layer |
| WO2021124741A1 (ja) * | 2019-12-20 | 2021-06-24 | 共同印刷株式会社 | 再封性包材 |
| CN116390985B (zh) * | 2020-11-17 | 2024-01-26 | 巴塞尔聚烯烃意大利有限公司 | 可剥离组合物 |
| EP4306557A4 (en) * | 2021-03-08 | 2025-01-22 | Mitsui Chemicals, Inc. | 1-BUTENE/ETHYLENE COPOLYMER, 1-BUTENE-BASED POLYMER COMPOSITION WITH THIS 1-BUTENE/ETHYLENE COPOLYMER AND PROPYLENE-BASED POLYMER |
| EP4562106A1 (fr) * | 2022-07-27 | 2025-06-04 | Bostik SA | Auto-adhesifs thermofusibles pour emballage refermable |
| FR3138438A1 (fr) * | 2022-07-27 | 2024-02-02 | Bostik Sa | Auto-adhesifs thermofusibles pour emballage refermable |
| CN119998421A (zh) * | 2022-09-05 | 2025-05-13 | 三井化学株式会社 | 密封剂树脂组合物及其用途 |
| FR3140791A1 (fr) * | 2022-10-12 | 2024-04-19 | Bostik Sa | Recyclage d’un systeme multicouche |
| EP4524214A1 (en) | 2023-09-13 | 2025-03-19 | Henkel AG & Co. KGaA | Pressure sensitive adhesive composition |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE363977B (enExample) | 1968-11-21 | 1974-02-11 | Montedison Spa | |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| US4568713A (en) | 1984-05-30 | 1986-02-04 | Shell Oil Company | Hot melt poly(butylene/ethylene) adhesives |
| US4937138A (en) | 1988-02-29 | 1990-06-26 | Shell Oil Company | Hot melt polybutylene and poly(butylene/ethylene) adhesives and laminar structures |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| IT1262934B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1256648B (it) | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| JPH08253738A (ja) * | 1995-03-14 | 1996-10-01 | Daiabondo Kogyo Kk | 反応性粘着テープおよび反応性粘着シート |
| AUPO591797A0 (en) | 1997-03-27 | 1997-04-24 | Commonwealth Scientific And Industrial Research Organisation | High avidity polyvalent and polyspecific reagents |
| FR2817502B1 (fr) | 2000-12-06 | 2003-02-28 | Pechiney Emballage Flexible Eu | Materiau d'operculage pelable et refermable |
| FR2820751B1 (fr) | 2001-02-09 | 2005-01-14 | Bostik Findley | Adhesifs thermofusibles auto-adhesifs extrudables a chaud et leur utilisation dans les films multicouches |
| US7420023B2 (en) * | 2002-02-20 | 2008-09-02 | Idemitsu Kosan Co., Ltd. | Process for producing modified butene-1 polymer and modified butene-1 polymer obtained by the process |
| EP1622948B1 (en) | 2003-05-12 | 2019-11-20 | Basell Polyolefine GmbH | Process for polymerizing 1-butene |
| JP4722427B2 (ja) | 2004-08-06 | 2011-07-13 | 日東電工株式会社 | 粘着テープ |
| KR101229293B1 (ko) | 2004-10-18 | 2013-02-05 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 이소탁틱도가 낮은 부텐-1 (공)중합체 |
| US7927679B2 (en) | 2005-10-11 | 2011-04-19 | Curwood, Inc. | Easy-open reclosable films having an interior frangible interface and articles made therefrom |
| DE602008002829D1 (de) * | 2007-04-27 | 2010-11-11 | Basell Poliolefine Srl | Buten-1-terpolymere und herstellungsverfahren dafür |
| EP2158235B1 (en) | 2007-06-25 | 2010-10-20 | Basell Polyolefine GmbH | 1-butene ethylene copolymers |
| JP5117255B2 (ja) * | 2008-03-31 | 2013-01-16 | 三菱樹脂株式会社 | 再封機能付き多層フィルム及びこれを用いた包装体 |
| DE102008026670A1 (de) * | 2008-06-04 | 2009-12-10 | Tesa Se | Klebstoff aus isotaktischem 1-Butenharz |
-
2011
- 2011-10-18 KR KR1020137009674A patent/KR101958495B1/ko active Active
- 2011-10-18 WO PCT/EP2011/068177 patent/WO2012052429A1/en not_active Ceased
- 2011-10-18 BR BR112013009717-5A patent/BR112013009717B1/pt active IP Right Grant
- 2011-10-18 US US13/880,403 patent/US9284475B2/en active Active
- 2011-10-18 EP EP11770463.5A patent/EP2630211B1/en active Active
- 2011-10-18 JP JP2013534292A patent/JP6005649B2/ja active Active
- 2011-10-18 CN CN201180050171.XA patent/CN103154176B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012052429A1 (en) | 2012-04-26 |
| CN103154176B (zh) | 2016-08-10 |
| US9284475B2 (en) | 2016-03-15 |
| EP2630211B1 (en) | 2016-05-18 |
| BR112013009717A2 (pt) | 2016-07-19 |
| JP6005649B2 (ja) | 2016-10-12 |
| KR101958495B1 (ko) | 2019-03-14 |
| EP2630211A1 (en) | 2013-08-28 |
| KR20130129188A (ko) | 2013-11-27 |
| US20130202836A1 (en) | 2013-08-08 |
| CN103154176A (zh) | 2013-06-12 |
| JP2014500340A (ja) | 2014-01-09 |
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 18/10/2011, OBSERVADAS AS CONDICOES LEGAIS. |