BR112012033217A2 - composições aquosas para branqueamento e sombreamento em aplicações de revestimento - Google Patents
composições aquosas para branqueamento e sombreamento em aplicações de revestimentoInfo
- Publication number
- BR112012033217A2 BR112012033217A2 BR112012033217A BR112012033217A BR112012033217A2 BR 112012033217 A2 BR112012033217 A2 BR 112012033217A2 BR 112012033217 A BR112012033217 A BR 112012033217A BR 112012033217 A BR112012033217 A BR 112012033217A BR 112012033217 A2 BR112012033217 A2 BR 112012033217A2
- Authority
- BR
- Brazil
- Prior art keywords
- linear
- branched
- ammonium
- tetrasubstituted
- tri
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 238000004061 bleaching Methods 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 2
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 abstract 2
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 abstract 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 229940098465 tincture Drugs 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012463 white pigment Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/10—Amino derivatives of triarylmethanes
- C09B11/12—Amino derivatives of triarylmethanes without any OH group bound to an aryl nucleus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/14—Styryl dyes
- C09B23/148—Stilbene dyes containing the moiety -C6H5-CH=CH-C6H5
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/32—Bleaching agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31975—Of cellulosic next to another carbohydrate
- Y10T428/31978—Cellulosic next to another cellulosic
- Y10T428/31986—Regenerated or modified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31993—Of paper
Abstract
composições aquosas para branqueamento e sombreamento em aplicações de revestimento. a presente invenção refere-se á composição aquosa de revestimento para branqueamento ótico e sombreamento de substratos compreendendo (a) pelo menos um branqueador ótico da fórmula (i) na qual a carga aniônica no branqueador é equilibrada por uma carga catiônica composta de um ou mais cátions idênticos ou diferentes selecionados a partir do grupo consistindo em hidrogênio, um cátion de metal alcalino, metal alcalinoterroso, amônio que é mono-, di-,tri- ou tetrassubstituído por um radical alquila c~ 1~-c~ 4~ linear ou ramificado, amônio que é mono-, di-, tri- ou tetrassubstituído por uma mistura de radical c~ 1~-c~ 4~ alquila linear ou ramificado e hidroxialquila linear ou ramificado ou as misturas dos ditos compostos, r~ 1~ e r~ 1~ podem ser os mesmos ou diferentes, e cada um é hidrogênio, alquila c~ 1~-c~ 4~ linear ou ramificado, hidroxialquila c~ 2~-c~ 4~ linear ou ramificado, ch~ 2~ co~ 2~, ch~ 2~ch~ 2~conh~ 2~, r~ 2~ e r~ 2~ podem ser os mesmos ou diferentes, e cada um é alquila c~ 1~-c~ 4~ linear ou ramificado, hidroxialquila c~ 2~-c~ 4~ linear ou ramificado, ch~ 2~ co~ 2~-, ch(co~ 2~)ch~ 2~co~ 2~, ch(co~ 2~) ch~ 2~ch~ 2~ch~ 2~co~ 2~, ch~ 2~ ch~ 2~co~ 2~, ch~ 2~ ch(ch3) co~ 2~, benzila, ou r~ 1~ e r~ 2~ e/ou r~ 1~ e r~ 2~, em conjunto com o átomo de nitrogênio vizinho significa um anel de morfolina e p é 0,1 ou 2, (b) pelo menos uma tintura de sombreamento da fórmula (ii) na qual r~ 3~ significa h, metila ou etila, r~ 4~ significa parametoxifenila, metila ou etila, r~ 4~ significa parametoxifenila, metila ou etila, m significa um cátion selecionado do grupo consistindo em hidrogênio, um cátion de metal alcalino, metal alcalinoterroso, amônio, amônio que é mono-, di-, tri- ou tetrassubstituído por um radical alquila c~ 1~-c~ 4~ linear ou ramificado, amônio que é mono-, di-, tri- ou tetrassubstituído por um radical hidroxialquila c~ 1~-c~ 4~ linear ou ramificado, amônio que é di-, tri- ou tetrassubstituído por uma mistura do radical c~ 1~-c~ 4~ alquila linear ou ramificado e hidroxialquila linear ou ramificado ou misturas dos ditos compostos, (c) pelo menos um pigmento branco, (d) pelo menos um aglutinante primário, (e) opcionalmente um ou mais aglutinantes secundários e (f) água.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10006814.7 | 2010-07-01 | ||
| EP10006814 | 2010-07-01 | ||
| PCT/EP2011/003047 WO2012000624A1 (en) | 2010-07-01 | 2011-06-21 | Aqueous compositions for whitening and shading in coating applications |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012033217A2 true BR112012033217A2 (pt) | 2016-11-16 |
| BR112012033217B1 BR112012033217B1 (pt) | 2020-02-27 |
Family
ID=43416494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012033217-1A BR112012033217B1 (pt) | 2010-07-01 | 2011-06-21 | Composições aquosas para branqueamento e sombreamento em aplicações de revestimento |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US8932727B2 (pt) |
| EP (1) | EP2588666B1 (pt) |
| JP (1) | JP5774693B2 (pt) |
| KR (1) | KR20130123356A (pt) |
| CN (1) | CN102971463B (pt) |
| AR (1) | AR081792A1 (pt) |
| AU (1) | AU2011273960A1 (pt) |
| BR (1) | BR112012033217B1 (pt) |
| CA (1) | CA2804169C (pt) |
| ES (1) | ES2688665T3 (pt) |
| HK (1) | HK1182423A1 (pt) |
| PL (1) | PL2588666T3 (pt) |
| PT (1) | PT2588666T (pt) |
| RU (1) | RU2564310C2 (pt) |
| TW (1) | TW201219623A (pt) |
| WO (1) | WO2012000624A1 (pt) |
| ZA (1) | ZA201208496B (pt) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1712677A1 (en) * | 2005-04-08 | 2006-10-18 | Clariant International Ltd. | Aqueous solutions of optical brighteners |
| JP5774693B2 (ja) * | 2010-07-01 | 2015-09-09 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | コーティング用途での白色化及び色調整用の水性組成物 |
| US8945718B2 (en) * | 2010-07-01 | 2015-02-03 | Clariant Finance (Bvi) Limited | Aqueous compositions for whitening and shading in coating applications |
| AU2011281933A1 (en) * | 2010-07-23 | 2012-11-29 | Clariant Finance (Bvi) Limited | Method for preparing white paper |
| TWI810729B (zh) | 2012-09-25 | 2023-08-01 | 美商百歐維拉提夫治療公司 | Ｆｉｘ多肽的應用 |
| PL3623392T3 (pl) | 2018-09-14 | 2024-01-15 | Archroma Ip Gmbh | Optycznie rozjaśnione lateksy |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3479349A (en) * | 1967-08-03 | 1969-11-18 | Geigy Chem Corp | Polysulfonated bis-s-triazinylamino-stilbene-2,2'-disulfonic acids |
| BE755820A (fr) * | 1969-09-12 | 1971-03-08 | Sandoz Sa | Composition de blanchiment optique |
| GR71714B (pt) * | 1979-11-09 | 1983-06-21 | Colgate Palmolive Co | |
| SU1714016A1 (ru) * | 1990-05-22 | 1992-02-23 | Центральный научно-исследовательский институт бумаги | Способ обработки волокнистой массы при изготовлении бумаги |
| EP0534903B1 (de) | 1991-09-26 | 1997-06-25 | Ciba SC Holding AG | Verfahren zum Färben von Papier mit Disazofarbstoffen |
| DE19916078A1 (de) * | 1999-04-09 | 2000-10-12 | Jorax Labor Fuer Chemische Und | Verfahren zur Verbesserung von Weißgrad, Helligkeit und Farbort von Faserstoffen, von anorganischen Füllstoffen und Pigmenten sowie von Bindemitteln für die Papierherstellung |
| US6723846B1 (en) * | 1999-09-10 | 2004-04-20 | Ciba Specialty Chemicals Corporation | Triazinylaminostilbene derivative as fluorescent whitening agents |
| GB0021404D0 (en) | 2000-09-01 | 2000-10-18 | Clariant Int Ltd | Improvement in or to organic compounds |
| GB0100610D0 (en) * | 2001-01-10 | 2001-02-21 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| EP1342759A1 (en) * | 2002-03-08 | 2003-09-10 | Eastman Kodak Company | Ink jet ink set |
| DE10217677A1 (de) | 2002-04-19 | 2003-11-06 | Bayer Ag | Verwendung von Aufhellern zur Herstellung von Streichmassen |
| EP1612209A1 (en) * | 2004-06-28 | 2006-01-04 | Clariant International Ltd. | Improvements relating to optical brightening agents |
| EP1807496A1 (en) * | 2004-10-08 | 2007-07-18 | The Procter and Gamble Company | Fabric care compositions comprising hueing dye |
| US7967948B2 (en) * | 2006-06-02 | 2011-06-28 | International Paper Company | Process for non-chlorine oxidative bleaching of mechanical pulp in the presence of optical brightening agents |
| CA2659540A1 (en) * | 2006-08-08 | 2008-02-14 | Clariant Finance (Bvi) Limited | Aqueous solutions of optical brighteners |
| AU2007283654A1 (en) * | 2006-08-08 | 2008-02-14 | Clariant Finance (Bvi) Limited | Aqueous solutions of optical brighteners |
| TW201000716A (en) * | 2008-01-28 | 2010-01-01 | Akzo Nobel Nv | A method for production of paper |
| BRPI0909829B1 (pt) * | 2008-03-26 | 2018-11-21 | Archroma Ip Gmbh | composições aperfeiçoadas de abrilhantamento óptico |
| WO2011009632A1 (en) * | 2009-07-24 | 2011-01-27 | Clariant International Ltd | Aqueous solutions of acid dyes for shading in size press applications |
| TWI506183B (zh) * | 2010-02-11 | 2015-11-01 | Clariant Finance Bvi Ltd | 於施漿壓印應用中用於調色光之水性上漿組成物 |
| JP5774693B2 (ja) * | 2010-07-01 | 2015-09-09 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | コーティング用途での白色化及び色調整用の水性組成物 |
-
2011
- 2011-06-21 JP JP2013517066A patent/JP5774693B2/ja active Active
- 2011-06-21 US US13/703,290 patent/US8932727B2/en active Active
- 2011-06-21 KR KR20137000165A patent/KR20130123356A/ko active Search and Examination
- 2011-06-21 CA CA2804169A patent/CA2804169C/en active Active
- 2011-06-21 AU AU2011273960A patent/AU2011273960A1/en not_active Abandoned
- 2011-06-21 WO PCT/EP2011/003047 patent/WO2012000624A1/en active Application Filing
- 2011-06-21 CN CN201180030227.5A patent/CN102971463B/zh active Active
- 2011-06-21 PL PL11726715T patent/PL2588666T3/pl unknown
- 2011-06-21 ES ES11726715.3T patent/ES2688665T3/es active Active
- 2011-06-21 BR BR112012033217-1A patent/BR112012033217B1/pt active IP Right Grant
- 2011-06-21 RU RU2013104018/05A patent/RU2564310C2/ru not_active IP Right Cessation
- 2011-06-21 EP EP11726715.3A patent/EP2588666B1/en active Active
- 2011-06-21 PT PT11726715T patent/PT2588666T/pt unknown
- 2011-06-24 TW TW100122238A patent/TW201219623A/zh unknown
- 2011-06-29 AR ARP110102295 patent/AR081792A1/es active IP Right Grant
-
2012
- 2012-11-12 ZA ZA2012/08496A patent/ZA201208496B/en unknown
-
2013
- 2013-08-21 HK HK13109782.8A patent/HK1182423A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES2688665T3 (es) | 2018-11-06 |
| EP2588666B1 (en) | 2018-08-08 |
| WO2012000624A1 (en) | 2012-01-05 |
| CA2804169C (en) | 2018-07-10 |
| PL2588666T3 (pl) | 2019-03-29 |
| EP2588666A1 (en) | 2013-05-08 |
| PT2588666T (pt) | 2018-10-26 |
| RU2564310C2 (ru) | 2015-09-27 |
| AR081792A1 (es) | 2012-10-17 |
| BR112012033217B1 (pt) | 2020-02-27 |
| HK1182423A1 (en) | 2013-11-29 |
| ZA201208496B (en) | 2013-09-25 |
| CA2804169A1 (en) | 2012-01-05 |
| CN102971463A (zh) | 2013-03-13 |
| KR20130123356A (ko) | 2013-11-12 |
| AU2011273960A1 (en) | 2012-11-29 |
| JP5774693B2 (ja) | 2015-09-09 |
| US8932727B2 (en) | 2015-01-13 |
| CN102971463B (zh) | 2015-08-26 |
| US20130209820A1 (en) | 2013-08-15 |
| RU2013104018A (ru) | 2014-08-10 |
| JP2013536267A (ja) | 2013-09-19 |
| TW201219623A (en) | 2012-05-16 |
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