BR112012021646A2 - processo para preparar polímeros de estireno expansíveis - Google Patents

processo para preparar polímeros de estireno expansíveis

Info

Publication number
BR112012021646A2
BR112012021646A2 BR112012021646A BR112012021646A BR112012021646A2 BR 112012021646 A2 BR112012021646 A2 BR 112012021646A2 BR 112012021646 A BR112012021646 A BR 112012021646A BR 112012021646 A BR112012021646 A BR 112012021646A BR 112012021646 A2 BR112012021646 A2 BR 112012021646A2
Authority
BR
Brazil
Prior art keywords
styrene
expandable styrene
styrene polymers
preparing expandable
blowing agent
Prior art date
Application number
BR112012021646A
Other languages
English (en)
Inventor
Bernhard Schmied
Birgit Reinhard
Eckhard Neufeld
Jan Holoch
Jun Gao
Klaus Hahn
Klaus-Dieter Hungenberg
Michel Pepers
Olaf Kriha
Pascal Hesse
Ping Zhang
Rudolf SÜTTINGER
Renata Jovanovic
Wolfgang Ferstl
Wolfgang Kasten
Wolfram Husemann
Original Assignee
Sociedade Europ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sociedade Europ filed Critical Sociedade Europ
Publication of BR112012021646A2 publication Critical patent/BR112012021646A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

processo para preparar polímeros de estireno expansíveis. a invenção refere-se a um método para a produção de polímeros de estireno expansíveis, cujo método compreende os estágios que se seguem: (a) adicionar uma fase aquosa contendo um estabilizador de suspensão e uma fase orgânica contendo estireno e iniciador a um reator (b) iniciar a adição de um agente de sopro em uma taxa de conversão de estireno em uma faixa de 40 a 70% e adição do agente de sopro durante um período de 30 a 60 minutos, (c) adicionar um estabilizador para a estabilização da distribuição do tamanho de partícula do polímero de estireno expansível em uma taxa de conversão de estireno em uma faixa de 65 a 99%.
BR112012021646A 2010-03-12 2011-03-07 processo para preparar polímeros de estireno expansíveis BR112012021646A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10156440 2010-03-12
PCT/EP2011/053374 WO2011110518A1 (de) 2010-03-12 2011-03-07 Verfahren zur herstellung expandierbarer styrolpolymerisate

Publications (1)

Publication Number Publication Date
BR112012021646A2 true BR112012021646A2 (pt) 2016-09-20

Family

ID=44279745

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012021646A BR112012021646A2 (pt) 2010-03-12 2011-03-07 processo para preparar polímeros de estireno expansíveis

Country Status (7)

Country Link
EP (1) EP2545107A1 (pt)
KR (1) KR20130048198A (pt)
CN (1) CN102791781B (pt)
AR (1) AR080755A1 (pt)
BR (1) BR112012021646A2 (pt)
MX (1) MX2012009463A (pt)
WO (1) WO2011110518A1 (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9453083B2 (en) * 2013-03-14 2016-09-27 Saudi Basic Industries Corporation Vinyl polymers prepared via suspension polymerization and methods thereof
CN103965502B (zh) * 2014-04-28 2016-08-24 新疆蓝山屯河新材料有限公司 一种高熔结性可发性聚苯乙烯颗粒的生产方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE346114B (pt) * 1965-05-13 1972-06-26 Hoechst Ag
DD129556A2 (de) * 1974-05-09 1978-01-25 Wolfgang Wagenknecht Verfahren zur herstellung von kohlenhydratmischestern,insbesondere von cellulose
DE3728044A1 (de) 1987-08-22 1989-03-02 Huels Chemische Werke Ag Verfahren zur herstellung von styrolpolymerisaten mit enger korngroessenverteilung
DE4220225A1 (de) 1992-06-20 1993-12-23 Basf Ag Verfahren zur Herstellung von perlförmigen expandierbaren Styrolpolymerisaten
DE19816469C1 (de) * 1998-04-14 1999-12-09 Buna Sow Leuna Olefinverb Gmbh Verfahren und Vorrichtung zur Herstellung von expandierbaren Styrolpolymerisaten
FR2790091B1 (fr) * 1999-02-18 2001-05-11 Rhodia Chimie Sa Procede de preparation de latex par (co)polymerisation en emulsion de monomeres ethyleniquement insatures, avec suivi direct en ligne par spectroscopie raman
JP2005507456A (ja) 2001-10-30 2005-03-17 バイエル アクチェンゲゼルシャフト グラフト重合反応の反応進行の測定方法
JP4670226B2 (ja) * 2003-04-16 2011-04-13 株式会社カネカ スチレン系樹脂粒子の製造方法、及び発泡性スチレン系樹脂粒子の製造方法
EP2032609B1 (de) 2006-06-13 2009-09-02 Basf Se Verfahren zur herstellung von expandierbaren styrolpolymerisaten

Also Published As

Publication number Publication date
KR20130048198A (ko) 2013-05-09
CN102791781B (zh) 2014-08-13
WO2011110518A1 (de) 2011-09-15
MX2012009463A (es) 2012-09-12
CN102791781A (zh) 2012-11-21
EP2545107A1 (de) 2013-01-16
AR080755A1 (es) 2012-05-09

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Legal Events

Date Code Title Description
B08F Application fees: application dismissed [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]