BR112012013122A2 - processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico. - Google Patents
processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico.Info
- Publication number
- BR112012013122A2 BR112012013122A2 BR112012013122A BR112012013122A BR112012013122A2 BR 112012013122 A2 BR112012013122 A2 BR 112012013122A2 BR 112012013122 A BR112012013122 A BR 112012013122A BR 112012013122 A BR112012013122 A BR 112012013122A BR 112012013122 A2 BR112012013122 A2 BR 112012013122A2
- Authority
- BR
- Brazil
- Prior art keywords
- compounds
- brominated
- cyanoalkenylcyclopropanecarboxylic
- substituent
- acid compound
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/08—Isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/31—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico - a presente invenção refere-se a um método para a produção de composto ácido (z)-cianoalquenilciclopropanocarboxíico, que inclui a etapa de isomerização de um composto ácido (e)-cianoalquenilciclopropanocarboxíico (1) em um composto ácido (z)-cianoalquenilciclopropanocarboxíico (2) na presença de pelo menos um catalisador de isomerização selecionado do grupo consistindo em bromo, brometo de hidrogênio, ácidos carboxílicos bromados, compostos fosforosos bromados, compstos de imida n-bromados, compostos de amida n-bromados, compostos de alquilsilano bromados, brometo de tionila, compostos de boro bromados, compostos de alumínio bromados, compostos de tiol, compostos de dissulfeto, compostos de ácido tiocarboxílico, ácido nítrico e sis de nitrato: em que r ^1^ e r ^2^representam, r ^1^ representa um grupo alquila que pode ter um substituinte, ou um átomo de halogênio, e r ^2^ representa um átomo de hidrogênio, um grupo alquila que pode ter um substituinte, ou um grupo benzila que pode ter um substituinte.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009274314 | 2009-12-02 | ||
JP2009274313 | 2009-12-02 | ||
PCT/JP2010/071951 WO2011068244A1 (ja) | 2009-12-02 | 2010-12-01 | (z)-シアノアルケニルシクロプロパンカルボン酸化合物の製造方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112012013122A2 true BR112012013122A2 (pt) | 2017-03-14 |
Family
ID=44115084
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012013122A BR112012013122A2 (pt) | 2009-12-02 | 2010-12-01 | processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico. |
Country Status (12)
Country | Link |
---|---|
US (1) | US20130006008A1 (pt) |
EP (1) | EP2508509B1 (pt) |
JP (1) | JP5655527B2 (pt) |
KR (1) | KR20120098837A (pt) |
CN (1) | CN102639488B (pt) |
AU (1) | AU2010327557A1 (pt) |
BR (1) | BR112012013122A2 (pt) |
IL (1) | IL219832A (pt) |
MX (1) | MX2012005473A (pt) |
TW (1) | TW201127295A (pt) |
WO (1) | WO2011068244A1 (pt) |
ZA (1) | ZA201203245B (pt) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6068451B2 (ja) * | 2011-05-17 | 2017-01-25 | ザ・リージエンツ・オブ・ザ・ユニバーシテイ・オブ・カリフオルニア | キナーゼ阻害剤 |
WO2013187489A1 (ja) * | 2012-06-13 | 2013-12-19 | セントラル硝子株式会社 | 1-クロロ-3,3,3-トリフルオロ-1-プロペン及び1,3,3,3-テトラフルオロプロペンの製造方法 |
KR101469864B1 (ko) * | 2012-12-27 | 2014-12-08 | (주)에이지바이오매틱스 | 대사증후군 생체나이 측정 시스템 및 단말기 |
WO2015105850A1 (en) * | 2014-01-07 | 2015-07-16 | The General Hospital Corporation | Method and apparatus for recording microscopic images from within a living organism using an implantable device |
EP3397215A4 (en) * | 2016-01-03 | 2019-08-28 | Thika Holdings LLC | LUBRICATION DEVICE AND SYSTEM FOR INCREASING PLEASURE |
CN110878001A (zh) * | 2019-11-29 | 2020-03-13 | 温州大学 | (z)-烯烃异构化转化为(e)-烯烃的方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5820948B2 (ja) * | 1974-09-02 | 1983-04-26 | 株式会社クラレ | デルタ 4 ,デルタ 8− トランスフアルネシルサクサン マタハ ソノエステルルイ ノ セイゾウホウ |
JPS5665832A (en) * | 1979-11-02 | 1981-06-03 | Nissan Chem Ind Ltd | Isomerization of beta-gamma unsaturated alcohol |
JP2850471B2 (ja) * | 1990-04-11 | 1999-01-27 | 日本油脂株式会社 | 不飽和ジカルボン酸モノエステルの製造方法 |
FR2772759B1 (fr) * | 1997-12-22 | 2001-03-09 | Hoechst Schering Agrevo Sa | Nouveaux derives de l'acide 2,2-dimethyl 3-(2-fluorovinyl) cyclopropane carboxylique, leur procede de preparation et leur application comme pesticides |
ES2211358B1 (es) * | 2002-04-12 | 2005-10-01 | Sumitomo Chemical Company, Limited | Compuesto de ester y su uso. |
JP4285045B2 (ja) | 2002-04-12 | 2009-06-24 | 住友化学株式会社 | エステル化合物およびその用途 |
CN1268593C (zh) * | 2004-12-29 | 2006-08-09 | 浙江大学 | 将1,4-二氯-2-丁烯从顺式异构化为反式体的方法 |
JP2008044900A (ja) | 2006-08-18 | 2008-02-28 | Sumitomo Chemical Co Ltd | (2−ホルミル−1−アルケニル)シクロプロパン化合物の製造方法 |
JP5526472B2 (ja) | 2007-02-28 | 2014-06-18 | 住友化学株式会社 | エステル化合物及びその用途 |
JP5012095B2 (ja) * | 2007-03-07 | 2012-08-29 | 住友化学株式会社 | エステル化合物およびその用途 |
US8263797B2 (en) * | 2008-01-10 | 2012-09-11 | Sumitomo Chemical Company, Limited | Method for producing cyclopropane carboxylic acid compound and intermediate therefor |
JP5760473B2 (ja) * | 2010-02-12 | 2015-08-12 | 住友化学株式会社 | シアノアルケニルシクロプロパンカルボン酸の製造方法 |
-
2010
- 2010-11-30 JP JP2010266201A patent/JP5655527B2/ja active Active
- 2010-12-01 EP EP10834691.7A patent/EP2508509B1/en not_active Not-in-force
- 2010-12-01 US US13/508,935 patent/US20130006008A1/en not_active Abandoned
- 2010-12-01 WO PCT/JP2010/071951 patent/WO2011068244A1/ja active Application Filing
- 2010-12-01 BR BR112012013122A patent/BR112012013122A2/pt not_active IP Right Cessation
- 2010-12-01 KR KR1020127016850A patent/KR20120098837A/ko not_active Application Discontinuation
- 2010-12-01 TW TW099141770A patent/TW201127295A/zh unknown
- 2010-12-01 MX MX2012005473A patent/MX2012005473A/es not_active Application Discontinuation
- 2010-12-01 AU AU2010327557A patent/AU2010327557A1/en not_active Abandoned
- 2010-12-01 CN CN201080054225.5A patent/CN102639488B/zh active Active
-
2012
- 2012-05-04 ZA ZA2012/03245A patent/ZA201203245B/en unknown
- 2012-05-16 IL IL219832A patent/IL219832A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
WO2011068244A1 (ja) | 2011-06-09 |
ZA201203245B (en) | 2013-07-31 |
IL219832A (en) | 2015-11-30 |
EP2508509A4 (en) | 2014-04-23 |
TW201127295A (en) | 2011-08-16 |
US20130006008A1 (en) | 2013-01-03 |
JP5655527B2 (ja) | 2015-01-21 |
EP2508509B1 (en) | 2016-08-17 |
AU2010327557A1 (en) | 2012-06-07 |
KR20120098837A (ko) | 2012-09-05 |
MX2012005473A (es) | 2012-06-08 |
IL219832A0 (en) | 2012-07-31 |
CN102639488A (zh) | 2012-08-15 |
EP2508509A1 (en) | 2012-10-10 |
JP2011136982A (ja) | 2011-07-14 |
CN102639488B (zh) | 2014-09-24 |
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Legal Events
Date | Code | Title | Description |
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B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] | ||
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |