BR112012013122A2 - processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico. - Google Patents

processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico.

Info

Publication number
BR112012013122A2
BR112012013122A2 BR112012013122A BR112012013122A BR112012013122A2 BR 112012013122 A2 BR112012013122 A2 BR 112012013122A2 BR 112012013122 A BR112012013122 A BR 112012013122A BR 112012013122 A BR112012013122 A BR 112012013122A BR 112012013122 A2 BR112012013122 A2 BR 112012013122A2
Authority
BR
Brazil
Prior art keywords
compounds
brominated
cyanoalkenylcyclopropanecarboxylic
substituent
acid compound
Prior art date
Application number
BR112012013122A
Other languages
English (en)
Inventor
Mori Tatsuya
Uekawa Toru
Somyo Toshio
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of BR112012013122A2 publication Critical patent/BR112012013122A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
    • C07B35/08—Isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/31—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico - a presente invenção refere-se a um método para a produção de composto ácido (z)-cianoalquenilciclopropanocarboxíico, que inclui a etapa de isomerização de um composto ácido (e)-cianoalquenilciclopropanocarboxíico (1) em um composto ácido (z)-cianoalquenilciclopropanocarboxíico (2) na presença de pelo menos um catalisador de isomerização selecionado do grupo consistindo em bromo, brometo de hidrogênio, ácidos carboxílicos bromados, compostos fosforosos bromados, compstos de imida n-bromados, compostos de amida n-bromados, compostos de alquilsilano bromados, brometo de tionila, compostos de boro bromados, compostos de alumínio bromados, compostos de tiol, compostos de dissulfeto, compostos de ácido tiocarboxílico, ácido nítrico e sis de nitrato: em que r ^1^ e r ^2^representam, r ^1^ representa um grupo alquila que pode ter um substituinte, ou um átomo de halogênio, e r ^2^ representa um átomo de hidrogênio, um grupo alquila que pode ter um substituinte, ou um grupo benzila que pode ter um substituinte.
BR112012013122A 2009-12-02 2010-12-01 processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico. BR112012013122A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2009274314 2009-12-02
JP2009274313 2009-12-02
PCT/JP2010/071951 WO2011068244A1 (ja) 2009-12-02 2010-12-01 （ｚ）－シアノアルケニルシクロプロパンカルボン酸化合物の製造方法

Publications (1)

Publication Number Publication Date
BR112012013122A2 true BR112012013122A2 (pt) 2017-03-14

Family

ID=44115084

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012013122A BR112012013122A2 (pt) 2009-12-02 2010-12-01 processo para preparação de compostos de ácido (z)-cianoalquenilciclopropanocarboxílico.

Country Status (12)

Country Link
US (1) US20130006008A1 (pt)
EP (1) EP2508509B1 (pt)
JP (1) JP5655527B2 (pt)
KR (1) KR20120098837A (pt)
CN (1) CN102639488B (pt)
AU (1) AU2010327557A1 (pt)
BR (1) BR112012013122A2 (pt)
IL (1) IL219832A (pt)
MX (1) MX2012005473A (pt)
TW (1) TW201127295A (pt)
WO (1) WO2011068244A1 (pt)
ZA (1) ZA201203245B (pt)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6068451B2 (ja) * 2011-05-17 2017-01-25 ザ・リージエンツ・オブ・ザ・ユニバーシテイ・オブ・カリフオルニア キナーゼ阻害剤
WO2013187489A1 (ja) * 2012-06-13 2013-12-19 セントラル硝子株式会社 １－クロロ－３，３，３－トリフルオロ－１－プロペン及び１，３，３，３－テトラフルオロプロペンの製造方法
KR101469864B1 (ko) * 2012-12-27 2014-12-08 (주)에이지바이오매틱스 대사증후군 생체나이 측정 시스템 및 단말기
WO2015105850A1 (en) * 2014-01-07 2015-07-16 The General Hospital Corporation Method and apparatus for recording microscopic images from within a living organism using an implantable device
EP3397215A4 (en) * 2016-01-03 2019-08-28 Thika Holdings LLC LUBRICATION DEVICE AND SYSTEM FOR INCREASING PLEASURE
CN110878001A (zh) * 2019-11-29 2020-03-13 温州大学 (z)-烯烃异构化转化为(e)-烯烃的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5820948B2 (ja) * 1974-09-02 1983-04-26 株式会社クラレ デルタ ４ ，デルタ ８− トランスフアルネシルサクサン マタハ ソノエステルルイ ノ セイゾウホウ
JPS5665832A (en) * 1979-11-02 1981-06-03 Nissan Chem Ind Ltd Isomerization of beta-gamma unsaturated alcohol
JP2850471B2 (ja) * 1990-04-11 1999-01-27 日本油脂株式会社 不飽和ジカルボン酸モノエステルの製造方法
FR2772759B1 (fr) * 1997-12-22 2001-03-09 Hoechst Schering Agrevo Sa Nouveaux derives de l'acide 2,2-dimethyl 3-(2-fluorovinyl) cyclopropane carboxylique, leur procede de preparation et leur application comme pesticides
ES2211358B1 (es) * 2002-04-12 2005-10-01 Sumitomo Chemical Company, Limited Compuesto de ester y su uso.
JP4285045B2 (ja) 2002-04-12 2009-06-24 住友化学株式会社 エステル化合物およびその用途
CN1268593C (zh) * 2004-12-29 2006-08-09 浙江大学 将1,4－二氯－2－丁烯从顺式异构化为反式体的方法
JP2008044900A (ja) 2006-08-18 2008-02-28 Sumitomo Chemical Co Ltd （２−ホルミル−１−アルケニル）シクロプロパン化合物の製造方法
JP5526472B2 (ja) 2007-02-28 2014-06-18 住友化学株式会社 エステル化合物及びその用途
JP5012095B2 (ja) * 2007-03-07 2012-08-29 住友化学株式会社 エステル化合物およびその用途
US8263797B2 (en) * 2008-01-10 2012-09-11 Sumitomo Chemical Company, Limited Method for producing cyclopropane carboxylic acid compound and intermediate therefor
JP5760473B2 (ja) * 2010-02-12 2015-08-12 住友化学株式会社 シアノアルケニルシクロプロパンカルボン酸の製造方法

Also Published As

Publication number Publication date
WO2011068244A1 (ja) 2011-06-09
ZA201203245B (en) 2013-07-31
IL219832A (en) 2015-11-30
EP2508509A4 (en) 2014-04-23
TW201127295A (en) 2011-08-16
US20130006008A1 (en) 2013-01-03
JP5655527B2 (ja) 2015-01-21
EP2508509B1 (en) 2016-08-17
AU2010327557A1 (en) 2012-06-07
KR20120098837A (ko) 2012-09-05
MX2012005473A (es) 2012-06-08
IL219832A0 (en) 2012-07-31
CN102639488A (zh) 2012-08-15
EP2508509A1 (en) 2012-10-10
JP2011136982A (ja) 2011-07-14
CN102639488B (zh) 2014-09-24

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]