BR112012009770A2 - catalisador para a produçao de etanol através da hidrogenação de ácio acético que compreende platina-estanho sobre suporte de silício - Google Patents
catalisador para a produçao de etanol através da hidrogenação de ácio acético que compreende platina-estanho sobre suporte de silícioInfo
- Publication number
- BR112012009770A2 BR112012009770A2 BR112012009770A BR112012009770A BR112012009770A2 BR 112012009770 A2 BR112012009770 A2 BR 112012009770A2 BR 112012009770 A BR112012009770 A BR 112012009770A BR 112012009770 A BR112012009770 A BR 112012009770A BR 112012009770 A2 BR112012009770 A2 BR 112012009770A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- acetic acid
- hydrogenation
- platinum
- tin
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title 1
- FHMDYDAXYDRBGZ-UHFFFAOYSA-N platinum tin Chemical compound [Sn].[Pt] FHMDYDAXYDRBGZ-UHFFFAOYSA-N 0.000 title 1
- 229910052710 silicon Inorganic materials 0.000 title 1
- 239000010703 silicon Substances 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- 235000012241 calcium silicate Nutrition 0.000 abstract 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/588,727 US8309772B2 (en) | 2008-07-31 | 2009-10-26 | Tunable catalyst gas phase hydrogenation of carboxylic acids |
| PCT/US2010/054134 WO2011056595A1 (en) | 2009-10-26 | 2010-10-26 | Catalyst for the production of ethanol by hydrogenation of acetic acid comprising platinum -tin on silicaceous support |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112012009770A2 true BR112012009770A2 (pt) | 2016-05-17 |
Family
ID=46506679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012009770A BR112012009770A2 (pt) | 2009-10-26 | 2010-10-26 | catalisador para a produçao de etanol através da hidrogenação de ácio acético que compreende platina-estanho sobre suporte de silício |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP2493609A1 (https=) |
| JP (1) | JP5775087B2 (https=) |
| CN (1) | CN102300635B (https=) |
| AU (1) | AU2010315552B2 (https=) |
| BR (1) | BR112012009770A2 (https=) |
| CA (1) | CA2778957A1 (https=) |
| IL (1) | IL219400A0 (https=) |
| MX (1) | MX2012004841A (https=) |
| RU (1) | RU2549893C2 (https=) |
| WO (1) | WO2011056595A1 (https=) |
| ZA (1) | ZA201202847B (https=) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9079172B2 (en) | 2012-03-13 | 2015-07-14 | Celanese International Corporation | Promoters for cobalt-tin catalysts for reducing alkanoic acids |
| BR112014015080A2 (pt) * | 2011-12-29 | 2017-06-13 | Celanese Int Corp | catalisador de cobalto e estanho para produzir etanol |
| US9333496B2 (en) | 2012-02-29 | 2016-05-10 | Celanese International Corporation | Cobalt/tin catalyst for producing ethanol |
| US8975200B2 (en) * | 2012-01-06 | 2015-03-10 | Celanese International Corporation | Hydrogenation catalysts with cobalt-modified supports |
| US9079851B2 (en) * | 2012-02-01 | 2015-07-14 | Greenyug, Llc | Ethyl acetate production |
| US8927786B2 (en) | 2012-03-13 | 2015-01-06 | Celanese International Corporation | Ethanol manufacturing process over catalyst having improved radial crush strength |
| CN102658165B (zh) * | 2012-04-06 | 2014-11-05 | 华东理工大学 | 乙酸气相加氢制备乙醇的催化剂及其制备方法 |
| CN104107701B (zh) * | 2013-04-16 | 2016-08-03 | 中国石油化工股份有限公司 | 高活性Pt基催化剂、制备方法及其用途 |
| DE102013106787A1 (de) | 2013-06-28 | 2014-12-31 | Oxea Gmbh | Verfahren zur Herstellung von n-Butanderivaten |
| DE102013106790A1 (de) | 2013-06-28 | 2014-12-31 | Oxea Gmbh | Verfahren zur Herstellung von 1,3-Butandiol |
| CN103331158B (zh) * | 2013-07-15 | 2017-08-25 | 上海华谊（集团）公司 | 一种醋酸加氢制乙醇的催化剂及制备方法 |
| CN111359618B (zh) * | 2020-04-23 | 2022-10-25 | 上海亚铂化工科技有限公司 | 催化剂及其制备方法和应用以及催化酯加氢反应的方法 |
| EP4549622A1 (en) | 2023-10-31 | 2025-05-07 | Basf Se | Hydrogenation of carbonyl compounds using hydrogen with low deuterium content |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8509530D0 (en) | 1985-04-13 | 1985-05-15 | Bp Chem Int Ltd | Hydrogenation of carboxylic acids |
| GB8707595D0 (en) | 1987-03-31 | 1987-05-07 | British Petroleum Co Plc | Chemical process |
| US5149680A (en) | 1987-03-31 | 1992-09-22 | The British Petroleum Company P.L.C. | Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters |
| US5821111A (en) | 1994-03-31 | 1998-10-13 | Bioengineering Resources, Inc. | Bioconversion of waste biomass to useful products |
| USRE35377E (en) | 1993-05-27 | 1996-11-12 | Steinberg; Meyer | Process and apparatus for the production of methanol from condensed carbonaceous material |
| DE19720657A1 (de) * | 1997-05-16 | 1998-11-19 | Basf Ag | Verfahren zur Herstellung von aliphatischen Alkoholen |
| JP3780669B2 (ja) * | 1997-11-17 | 2006-05-31 | 三菱化学株式会社 | アルデヒド類及び、又はアルコール類の製造方法 |
| JP3911955B2 (ja) * | 1999-04-28 | 2007-05-09 | 三菱化学株式会社 | ルテニウム−スズ系担持触媒の製造方法。 |
| US6232352B1 (en) | 1999-11-01 | 2001-05-15 | Acetex Limited | Methanol plant retrofit for acetic acid manufacture |
| US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
| US6685754B2 (en) | 2001-03-06 | 2004-02-03 | Alchemix Corporation | Method for the production of hydrogen-containing gaseous mixtures |
| EP1277826A1 (en) * | 2001-07-18 | 2003-01-22 | ATOFINA Research | Hydrogenation and dehydrogenation processes and catalysts therefor |
| DE102004007498A1 (de) * | 2004-02-13 | 2005-09-01 | Basf Ag | Hydrierverfahren zur Herstellung optisch aktiver Alkohole oder Carbonsäuren |
| KR100922998B1 (ko) * | 2008-03-06 | 2009-10-22 | 한국화학연구원 | 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법 |
-
2010
- 2010-10-26 BR BR112012009770A patent/BR112012009770A2/pt not_active Application Discontinuation
- 2010-10-26 AU AU2010315552A patent/AU2010315552B2/en not_active Expired - Fee Related
- 2010-10-26 EP EP10773794A patent/EP2493609A1/en not_active Withdrawn
- 2010-10-26 RU RU2012121807/04A patent/RU2549893C2/ru not_active IP Right Cessation
- 2010-10-26 JP JP2012535457A patent/JP5775087B2/ja not_active Expired - Fee Related
- 2010-10-26 MX MX2012004841A patent/MX2012004841A/es unknown
- 2010-10-26 CN CN201080006216.9A patent/CN102300635B/zh not_active Expired - Fee Related
- 2010-10-26 WO PCT/US2010/054134 patent/WO2011056595A1/en not_active Ceased
- 2010-10-26 CA CA2778957A patent/CA2778957A1/en not_active Abandoned
-
2012
- 2012-04-18 ZA ZA2012/02847A patent/ZA201202847B/en unknown
- 2012-04-24 IL IL219400A patent/IL219400A0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2010315552B2 (en) | 2016-05-12 |
| JP5775087B2 (ja) | 2015-09-09 |
| CN102300635A (zh) | 2011-12-28 |
| MX2012004841A (es) | 2012-05-29 |
| AU2010315552A1 (en) | 2012-05-17 |
| CA2778957A1 (en) | 2011-05-12 |
| WO2011056595A1 (en) | 2011-05-12 |
| RU2549893C2 (ru) | 2015-05-10 |
| JP2013508423A (ja) | 2013-03-07 |
| ZA201202847B (en) | 2013-06-26 |
| CN102300635B (zh) | 2014-10-29 |
| IL219400A0 (en) | 2012-06-28 |
| EP2493609A1 (en) | 2012-09-05 |
| RU2012121807A (ru) | 2013-12-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL |