BR112012009770A2 - catalyst for ethanol production by hydrogenation of acetic acid comprising platinum-tin on silicon support - Google Patents

catalyst for ethanol production by hydrogenation of acetic acid comprising platinum-tin on silicon support

Info

Publication number
BR112012009770A2
BR112012009770A2 BR112012009770A BR112012009770A BR112012009770A2 BR 112012009770 A2 BR112012009770 A2 BR 112012009770A2 BR 112012009770 A BR112012009770 A BR 112012009770A BR 112012009770 A BR112012009770 A BR 112012009770A BR 112012009770 A2 BR112012009770 A2 BR 112012009770A2
Authority
BR
Brazil
Prior art keywords
catalyst
acetic acid
hydrogenation
platinum
tin
Prior art date
Application number
BR112012009770A
Other languages
Portuguese (pt)
Inventor
Heiko Weiner
John L Potts
Radmila Jevtic
Victor J Johnston
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BR112012009770A2 publication Critical patent/BR112012009770A2/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

hidrogenação de ácidos carbixílicos em fase gasosa com catalisador ajustável. o processo para formação seletiva de etanol portindo de ácido acético inclui o contato de uma corrente de alimentação contendo ácido acético e hidrogênio a uma temperatura elevada com catalisador que compreende platina e estanho sobre uma sílica com área de superfície alta promovido com metassilicato de cálcio. as seletividades em relação ao etanol de mais de de 85% são conseguidas a 280<198>c com vida de catalisador em centenas de horas.hydrogenation of gas phase carbixylic acids with adjustable catalyst. The process for selective formation of ethanol containing acetic acid includes contacting a feed stream containing acetic acid and hydrogen at an elevated temperature with a catalyst comprising platinum and tin on a high surface area silica promoted with calcium metasilicate. ethanol selectivities of more than 85% are achieved at 280 ° C and catalyst life in hundreds of hours.

BR112012009770A 2009-10-26 2010-10-26 catalyst for ethanol production by hydrogenation of acetic acid comprising platinum-tin on silicon support BR112012009770A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
PCT/US2010/054134 WO2011056595A1 (en) 2009-10-26 2010-10-26 Catalyst for the production of ethanol by hydrogenation of acetic acid comprising platinum -tin on silicaceous support

Publications (1)

Publication Number Publication Date
BR112012009770A2 true BR112012009770A2 (en) 2016-05-17

Family

ID=46506679

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012009770A BR112012009770A2 (en) 2009-10-26 2010-10-26 catalyst for ethanol production by hydrogenation of acetic acid comprising platinum-tin on silicon support

Country Status (11)

Country Link
EP (1) EP2493609A1 (en)
JP (1) JP5775087B2 (en)
CN (1) CN102300635B (en)
AU (1) AU2010315552B2 (en)
BR (1) BR112012009770A2 (en)
CA (1) CA2778957A1 (en)
IL (1) IL219400A0 (en)
MX (1) MX2012004841A (en)
RU (1) RU2549893C2 (en)
WO (1) WO2011056595A1 (en)
ZA (1) ZA201202847B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
CN104039747B (en) * 2011-12-29 2016-12-21 国际人造丝公司 For producing cobalt and the tin catalyst of ethanol
WO2013103395A1 (en) * 2012-01-06 2013-07-11 Celanese International Corporation Precious metal, active metal and modified support - containing hydrogenation catalysts and acetic acid hydrogenation process using the same
US9079851B2 (en) * 2012-02-01 2015-07-14 Greenyug, Llc Ethyl acetate production
US8927786B2 (en) 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
CN102658165B (en) * 2012-04-06 2014-11-05 华东理工大学 Catalyst for preparing ethanol by acetic acid gas phase hydrogenation and preparation method thereof
CN104107701B (en) * 2013-04-16 2016-08-03 中国石油化工股份有限公司 High activity Pt base catalyst, preparation method and its usage
DE102013106787A1 (en) 2013-06-28 2014-12-31 Oxea Gmbh Process for the preparation of n-butane derivatives
DE102013106790A1 (en) 2013-06-28 2014-12-31 Oxea Gmbh Process for the preparation of 1,3-butanediol
CN103331158B (en) * 2013-07-15 2017-08-25 上海华谊（集团）公司 The catalyst and preparation method of a kind of acetic acid preparation of ethanol by hydrogenating
CN111359618B (en) * 2020-04-23 2022-10-25 上海亚铂化工科技有限公司 Catalyst, preparation method and application thereof, and method for catalyzing ester hydrogenation reaction

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
DE19720657A1 (en) * 1997-05-16 1998-11-19 Basf Ag Process for the preparation of aliphatic alcohols
JP3780669B2 (en) * 1997-11-17 2006-05-31 三菱化学株式会社 Method for producing aldehydes and / or alcohols
JP3911955B2 (en) * 1999-04-28 2007-05-09 三菱化学株式会社 A method for producing a ruthenium-tin supported catalyst.
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
EP1277826A1 (en) * 2001-07-18 2003-01-22 ATOFINA Research Hydrogenation and dehydrogenation processes and catalysts therefor
DE102004007498A1 (en) * 2004-02-13 2005-09-01 Basf Ag Hydrogenation process for the preparation of optically active alcohols or carboxylic acids
KR100922998B1 (en) * 2008-03-06 2009-10-22 한국화학연구원 Process for preparing monohydric alcohols from monocarboxylic acids or derivatives thereof

Also Published As

Publication number Publication date
JP5775087B2 (en) 2015-09-09
CA2778957A1 (en) 2011-05-12
IL219400A0 (en) 2012-06-28
EP2493609A1 (en) 2012-09-05
CN102300635B (en) 2014-10-29
RU2012121807A (en) 2013-12-10
JP2013508423A (en) 2013-03-07
WO2011056595A1 (en) 2011-05-12
AU2010315552B2 (en) 2016-05-12
RU2549893C2 (en) 2015-05-10
ZA201202847B (en) 2013-06-26
MX2012004841A (en) 2012-05-29
CN102300635A (en) 2011-12-28
AU2010315552A1 (en) 2012-05-17

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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