BR112014015080A2 - cobalt and tin catalyst to produce ethanol - Google Patents
cobalt and tin catalyst to produce ethanolInfo
- Publication number
- BR112014015080A2 BR112014015080A2 BR112014015080A BR112014015080A BR112014015080A2 BR 112014015080 A2 BR112014015080 A2 BR 112014015080A2 BR 112014015080 A BR112014015080 A BR 112014015080A BR 112014015080 A BR112014015080 A BR 112014015080A BR 112014015080 A2 BR112014015080 A2 BR 112014015080A2
- Authority
- BR
- Brazil
- Prior art keywords
- cobalt
- produce ethanol
- tin catalyst
- tin
- active metals
- Prior art date
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 4
- 239000010941 cobalt Substances 0.000 title abstract 3
- 229910017052 cobalt Inorganic materials 0.000 title abstract 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 3
- 239000012974 tin catalyst Substances 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8966—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
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- B01J35/40—
-
- B01J35/51—
-
- B01J35/613—
-
- B01J35/615—
-
- B01J35/635—
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- B01J35/638—
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- B01J35/647—
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
resumo catalisador de cobalto e estanho para produzir etanol a presente invenção refere-se a um processo para a formação de álcoois de ácidos alcanóicos, em que as etapas do processo compreendem: colocar uma corrente de alimentação que contém o ácido alcanóico e hidrogênio em uma temperatura elevada em contato com um catalisador de hidrogenação que compreende de 3 a 25% em peso de metais ativos em um suporte, em que os metais ativos compreendem cobalto e estanho.abstract "cobalt and tin catalyst to produce ethanol" the present invention relates to a process for the formation of alcohols from alkanoic acids, in which the process steps comprise: placing a feed stream that contains the alkanoic acid and hydrogen in an elevated temperature in contact with a hydrogenation catalyst comprising from 3 to 25% by weight of active metals on a support, wherein the active metals comprise cobalt and tin.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161581290P | 2011-12-29 | 2011-12-29 | |
US13/408,240 US9333496B2 (en) | 2012-02-29 | 2012-02-29 | Cobalt/tin catalyst for producing ethanol |
US13/418,749 US9079172B2 (en) | 2012-03-13 | 2012-03-13 | Promoters for cobalt-tin catalysts for reducing alkanoic acids |
US13/480,187 US8455702B1 (en) | 2011-12-29 | 2012-05-24 | Cobalt and tin catalysts for producing ethanol |
PCT/US2012/071355 WO2013101756A1 (en) | 2011-12-29 | 2012-12-21 | Cobalt and tin catalyst for producing ethanol |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112014015080A2 true BR112014015080A2 (en) | 2017-06-13 |
Family
ID=48698574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112014015080A BR112014015080A2 (en) | 2011-12-29 | 2012-12-21 | cobalt and tin catalyst to produce ethanol |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2797865A1 (en) |
CN (1) | CN104039747B (en) |
BR (1) | BR112014015080A2 (en) |
MX (1) | MX2014007394A (en) |
WO (1) | WO2013101756A1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9266095B2 (en) * | 2014-01-27 | 2016-02-23 | Celanese International Corporation | Hydrogenation catalysts with cobalt and alkaline-earth metal modified supports |
US9353035B2 (en) | 2014-04-28 | 2016-05-31 | Celanese International Corporation | Process for producing ethanol with zonal catalysts |
US9382177B2 (en) | 2014-04-28 | 2016-07-05 | Celanese International Corporation | Hydrogenation catalysts comprising a mixed oxide comprising a promoter metal |
US9073815B1 (en) * | 2014-04-28 | 2015-07-07 | Celanese International Corporation | Hydrogenation catalysts comprising a mixed oxide and processes for producing ethanol |
US9670120B2 (en) | 2015-01-27 | 2017-06-06 | Celanese International Corporation | Process for producing ethanol using a solid catalyst |
WO2016175747A1 (en) * | 2015-04-27 | 2016-11-03 | Celanese International Corporation | Hydrogenation catalysts comprising a mixed oxide having bismuth and process for producing ethanol |
CN108586196A (en) * | 2018-04-18 | 2018-09-28 | 肖锦 | A kind of method of ethyl acetate preparation of ethanol by hydrogenating |
CN108358752A (en) * | 2018-04-18 | 2018-08-03 | 肖锦 | A kind of method of acetic acid hydrogenation ethyl alcohol |
CN111715237B (en) * | 2020-06-24 | 2021-05-28 | 中国地质大学(武汉) | Preparation method and application of magnetic nickel-palladium bimetallic supported titanium dioxide nano material |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7608744B1 (en) * | 2008-07-31 | 2009-10-27 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
US7863489B2 (en) * | 2008-07-31 | 2011-01-04 | Celanese International Corporation | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
JP5775087B2 (en) * | 2009-10-26 | 2015-09-09 | セラニーズ・インターナショナル・コーポレーション | Method for producing ethanol by reduction of acetic acid |
US8211821B2 (en) * | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
TW201302684A (en) * | 2011-04-26 | 2013-01-16 | Celanese Int Corp | Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed |
-
2012
- 2012-12-21 EP EP12814099.3A patent/EP2797865A1/en not_active Withdrawn
- 2012-12-21 WO PCT/US2012/071355 patent/WO2013101756A1/en active Application Filing
- 2012-12-21 MX MX2014007394A patent/MX2014007394A/en unknown
- 2012-12-21 BR BR112014015080A patent/BR112014015080A2/en not_active IP Right Cessation
- 2012-12-21 CN CN201280064873.8A patent/CN104039747B/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP2797865A1 (en) | 2014-11-05 |
WO2013101756A1 (en) | 2013-07-04 |
MX2014007394A (en) | 2014-08-21 |
CN104039747A (en) | 2014-09-10 |
CN104039747B (en) | 2016-12-21 |
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Legal Events
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B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 6A ANUIDADE. |
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B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO ARQUIVAMENTO PUBLICADO NA RPI 2495 DE 30/10/2018. |
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B350 | Update of information on the portal [chapter 15.35 patent gazette] |