BR0110413A - Composições de catalisador de polimerização e processos para produção de polìmeros e polìmeros bimodais - Google Patents

Composições de catalisador de polimerização e processos para produção de polìmeros e polìmeros bimodais

Info

Publication number
BR0110413A
BR0110413A BR0110413-6A BR0110413A BR0110413A BR 0110413 A BR0110413 A BR 0110413A BR 0110413 A BR0110413 A BR 0110413A BR 0110413 A BR0110413 A BR 0110413A
Authority
BR
Brazil
Prior art keywords
polymers
processes
producing
bimodal
catalyst compositions
Prior art date
Application number
BR0110413-6A
Other languages
English (en)
Other versions
BRPI0110413B1 (pt
Inventor
Michael D Jensen
Max P Mcdaniel
Elizabeth A Benham
Anthony P Eaton
Joel L Martin
Gil R Hawley
Tony R Crain
Martha J Tanner
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of BR0110413A publication Critical patent/BR0110413A/pt
Publication of BRPI0110413B1 publication Critical patent/BRPI0110413B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/07Catalyst support treated by an anion, e.g. Cl-, F-, SO42-
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)

Abstract

"COMPOSIçõES DE CATALISADOR DE POLIMERIZAçãO E PROCESSOS PARA PRODUçãO DE POLìMEROS E POLìMEROS BIMODAIS". é provido um processo para a produção de uma composição de catalisador. O processo compreende contato de pelo menos um primeiro composto organometálico e pelo menos um ativador para produzir a primeira composição de catalisador. O ativador é selecionado do grupo consistindo em aluminoxanos, flúor-organo boratos e componentes óxido sólidos tratados em combinação com pelo menos um composto organoalumínio. Em uma outra modalidade desta invenção, um processo para produção de uma segunda composição de catalisador para produção de polímeros bimodais é provido. O processo compreende contato de pelo menos um primeiro composto organometálico, pelo menos um ativador e pelo menos um segundo composto organometálico para produzir a segunda composição de catalisador. As primeira e segunda composições de catalisador são também providas bem como processos de polimerização usando as composições para produzir polímeros.
BRPI0110413-6A 2000-04-28 2001-04-27 Processo para produzir uma primeira composição de catalisador BRPI0110413B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/561,306 US6528448B1 (en) 2000-04-28 2000-04-28 Polymerization catalyst compositions and processes to produce polymers and bimodal polymers
PCT/US2001/013830 WO2001083498A1 (en) 2000-04-28 2001-04-27 Polymerization catalyst compositions and processes to produce polymers and bimodal polymers

Publications (2)

Publication Number Publication Date
BR0110413A true BR0110413A (pt) 2003-12-30
BRPI0110413B1 BRPI0110413B1 (pt) 2015-09-01

Family

ID=24241427

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0110413-6A BRPI0110413B1 (pt) 2000-04-28 2001-04-27 Processo para produzir uma primeira composição de catalisador

Country Status (13)

Country Link
US (2) US6528448B1 (pt)
EP (1) EP1278756B1 (pt)
JP (1) JP4778658B2 (pt)
KR (1) KR20020093992A (pt)
AU (1) AU2001257423A1 (pt)
BR (1) BRPI0110413B1 (pt)
CA (1) CA2407602C (pt)
EA (1) EA005850B1 (pt)
HK (1) HK1050201A1 (pt)
IL (1) IL152501A0 (pt)
MX (1) MXPA02010631A (pt)
PL (1) PL360980A1 (pt)
WO (1) WO2001083498A1 (pt)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
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US6613712B1 (en) * 1999-11-24 2003-09-02 Phillips Petroleum Company Organometal catalyst compositions with solid oxide supports treated with fluorine and boron
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6528448B1 (en) * 2000-04-28 2003-03-04 Phillips Petroleum Company Polymerization catalyst compositions and processes to produce polymers and bimodal polymers
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WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7205363B2 (en) 2003-06-11 2007-04-17 Exxon Mobil Chemical Patents Inc. Polymerization processes using antistatic agents
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WO2005090373A1 (de) * 2004-03-17 2005-09-29 Georg-August-Universität Göttingen Sauerstoffverbrückter bimetallischer komplex, dessen herstellung und verwendung für die polymerisations-katalyse
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7148298B2 (en) 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
US7144964B2 (en) * 2004-08-19 2006-12-05 Equistar Chemicals, L.P. Solution polymerization process utilizing preassembled bimetallic Ziegler-Natta catalyst
US8058367B2 (en) 2004-08-27 2011-11-15 Chevron Phillips Chemical Company Lp Methods and systems for controlling polymer particle size
US7645841B2 (en) * 2004-08-27 2010-01-12 Chevron Phillips Chemical Company Lp Method and system to reduce polymerization reactor fouling
US7163906B2 (en) * 2004-11-04 2007-01-16 Chevron Phillips Chemical Company, Llp Organochromium/metallocene combination catalysts for producing bimodal resins
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7312283B2 (en) * 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7576163B2 (en) 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
US7888522B2 (en) * 2007-04-26 2011-02-15 Georg-August-Universität Göttingen Stiftung Öffentlichen Rechts Oxygen-bridged bimetallic complex and polymerization process
US7884165B2 (en) * 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
MX362816B (es) 2009-06-16 2019-02-15 Chevron Phillips Chemical Co Lp Oligomerizacion de alfa olefinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
WO2011044150A1 (en) * 2009-10-06 2011-04-14 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems
US8399580B2 (en) 2010-08-11 2013-03-19 Chevron Philips Chemical Company Lp Additives to chromium catalyst mix tank
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
US8865846B2 (en) * 2012-09-25 2014-10-21 Chevron Phillips Chemical Company Lp Metallocene and half sandwich dual catalyst systems for producing broad molecular weight distribution polymers
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9289748B1 (en) 2015-06-11 2016-03-22 Chevron Phillips Chemical Company Lp Treater regeneration
US9861955B2 (en) 2015-06-11 2018-01-09 Chevron Phillips Chemical Company, Lp Treater regeneration
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US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
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JP7313350B2 (ja) 2017-12-18 2023-07-24 ダウ グローバル テクノロジーズ エルエルシー ジルコノセン-チタノセン触媒系
US10792609B2 (en) 2018-05-07 2020-10-06 Chevron Phillips Chemical Company Lp Nitrogen conservation in polymerization processes
DE102018211596A1 (de) 2018-07-12 2020-01-16 Carl Zeiss Smt Gmbh Verfahren zur Herstellung eines reflektierenden optischen Elementes einer Projektionsbelichtungsanlage und reflektierendes optisches Element für eine Projektionsbelichtungsanlage, Projektionsobjektiv und Projektionsbelichtungsanlage
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US11325995B2 (en) 2020-02-21 2022-05-10 Chevron Phillips Chemical Company Lp Metallocene catalysts for polyethylene
US20230192586A1 (en) 2021-12-16 2023-06-22 Chevron Phillips Chemical Company Lp Gas phase process for acrylate production from ethylene and carbon dioxide

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JPH10292006A (ja) * 1997-04-18 1998-11-04 Mitsui Chem Inc オレフィンの重合方法
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SG72966A1 (en) * 1998-07-08 2000-05-23 Sumitomo Chemical Co Transition metal compound olefin polymerization catalyst component olefin polymerization catalyst and process for producing olefin polymer
US6426395B1 (en) * 1998-08-03 2002-07-30 Chisso Corporation μ-oxo-bis-metallocene complex compounds and catalysts using same for the polymerization of olefins as well as polymerization process
US6528448B1 (en) * 2000-04-28 2003-03-04 Phillips Petroleum Company Polymerization catalyst compositions and processes to produce polymers and bimodal polymers

Also Published As

Publication number Publication date
CA2407602C (en) 2008-04-08
JP2003531957A (ja) 2003-10-28
HK1050201A1 (en) 2003-06-13
JP4778658B2 (ja) 2011-09-21
IL152501A0 (en) 2003-05-29
US20040006186A1 (en) 2004-01-08
EA200201160A1 (ru) 2003-06-26
BRPI0110413B1 (pt) 2015-09-01
WO2001083498A1 (en) 2001-11-08
EP1278756B1 (en) 2014-06-11
PL360980A1 (en) 2004-09-20
EP1278756A4 (en) 2005-02-23
MXPA02010631A (es) 2003-03-10
EA005850B1 (ru) 2005-06-30
CA2407602A1 (en) 2001-11-08
US6936667B2 (en) 2005-08-30
US6528448B1 (en) 2003-03-04
AU2001257423A1 (en) 2001-11-12
KR20020093992A (ko) 2002-12-16
EP1278756A1 (en) 2003-01-29

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