BR0013815A - Aperfeiçoamentos em catalise de deshidrogenação - Google Patents

Aperfeiçoamentos em catalise de deshidrogenação

Info

Publication number
BR0013815A
BR0013815A BR0013815-0A BR0013815A BR0013815A BR 0013815 A BR0013815 A BR 0013815A BR 0013815 A BR0013815 A BR 0013815A BR 0013815 A BR0013815 A BR 0013815A
Authority
BR
Brazil
Prior art keywords
dehydrogenation
prepared according
catalysis
catalysts prepared
catalysts
Prior art date
Application number
BR0013815-0A
Other languages
English (en)
Inventor
David R Dyroff
Original Assignee
Huntsman Spec Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Spec Chem Corp filed Critical Huntsman Spec Chem Corp
Publication of BR0013815A publication Critical patent/BR0013815A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C07C5/325—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"APERFEIçOAMENTOS EM CATALISE DE DESHIDROGENAçãO". compreendendo catalisadores suportados e processos úteis na deshidrogenação de hidrocarbonetos. Os catalisadores preparados de acordo com a invenção possuem uma distribuição de tamanho único de poros, que provê um balanço favorável de seletividade, atividade, e estabilidade termal. Numa preferida forma da invenção, os catalisadores preparados de acordo com a invenção são regeneráveis. Parafinas com extensão de detergentes podem ser convertidas para monoolefinas usando um catalisador e o processo providos pela invenção.
BR0013815-0A 1999-08-27 2000-08-03 Aperfeiçoamentos em catalise de deshidrogenação BR0013815A (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US15111399P 1999-08-27 1999-08-27
US15587799P 1999-09-24 1999-09-24
US17998400P 2000-02-03 2000-02-03
US09/533,278 US6417135B1 (en) 1999-08-27 2000-03-22 Advances in dehydrogenation catalysis
PCT/US2000/021265 WO2001015803A1 (en) 1999-08-27 2000-08-03 Advances in dehydrogenation catalysis

Publications (1)

Publication Number Publication Date
BR0013815A true BR0013815A (pt) 2002-04-23

Family

ID=27495958

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0013815-0A BR0013815A (pt) 1999-08-27 2000-08-03 Aperfeiçoamentos em catalise de deshidrogenação

Country Status (14)

Country Link
US (2) US6417135B1 (pt)
EP (1) EP1216093B1 (pt)
KR (1) KR20020040789A (pt)
CN (1) CN1127372C (pt)
AR (1) AR025368A1 (pt)
AU (1) AU6757700A (pt)
BR (1) BR0013815A (pt)
CA (1) CA2381893A1 (pt)
DE (1) DE60003571T2 (pt)
ES (1) ES2202163T3 (pt)
MX (1) MXPA02001925A (pt)
MY (1) MY136001A (pt)
TW (1) TW482695B (pt)
WO (1) WO2001015803A1 (pt)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU5405798A (en) 1996-12-30 1998-07-31 Imd Soft Ltd. Medical information system
US6417135B1 (en) * 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis
US6576588B2 (en) * 2000-04-07 2003-06-10 Catalytic Distillation Technologies Process for selective hydrogenation of alkynes and catalyst therefor
US6586650B2 (en) * 2000-07-21 2003-07-01 Exxonmobil Research And Engineering Company Ring opening with group VIII metal catalysts supported on modified substrate
US7361313B2 (en) * 2003-02-18 2008-04-22 Intel Corporation Methods for uniform metal impregnation into a nanoporous material
EP1430949B1 (en) * 2002-12-10 2008-03-26 Haldor Topsoe A/S Process for catalytic dehydrogenation and catalyst therefore
US7848935B2 (en) * 2003-01-31 2010-12-07 I.M.D. Soft Ltd. Medical information event manager
US8620678B2 (en) * 2003-01-31 2013-12-31 Imd Soft Ltd. Medical information query system
US20060004610A1 (en) * 2004-01-09 2006-01-05 Eran David Clinical data database system and method for a critical care and/or hospital environment
US7521393B2 (en) * 2004-07-27 2009-04-21 Süd-Chemie Inc Selective hydrogenation catalyst designed for raw gas feed streams
WO2006047091A2 (en) * 2004-10-25 2006-05-04 Huntsman Petrochemical Corporation Fuel and oil detergents
US7521392B1 (en) * 2004-11-19 2009-04-21 Nanostellar, Inc. Supported catalysts having platinum particles
US20060173224A1 (en) * 2005-02-01 2006-08-03 Catalytic Distillation Technologies Process and catalyst for selective hydrogenation of dienes and acetylenes
CN100434407C (zh) * 2006-01-19 2008-11-19 中国石油化工股份有限公司 一种丙烷脱氢制丙烯的方法
US8600777B2 (en) * 2008-08-28 2013-12-03 I.M.D. Soft Ltd. Monitoring patient conditions
JP5386584B2 (ja) 2008-08-29 2014-01-15 エクソンモービル・ケミカル・パテンツ・インク フェノールの製造方法
GB0817109D0 (en) * 2008-09-18 2008-10-29 Johnson Matthey Plc Catalyst and process
WO2011087467A1 (en) * 2008-10-27 2011-07-21 Wen-Qing Xu Nickel-based reforming catalyst
KR101218453B1 (ko) * 2008-12-30 2013-01-04 주식회사 효성 탈수소화 촉매
WO2010099422A1 (en) * 2009-02-26 2010-09-02 Imdsoft, Inc. Decision support
WO2011096999A2 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Cyclohexanone dehydrogenation catalyst and process
WO2011096993A2 (en) * 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
WO2011096990A2 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation catalyst and process
SG185716A1 (en) 2010-06-25 2012-12-28 Exxonmobil Chem Patents Inc Dehydrogenation process
CN102775262A (zh) * 2011-05-13 2012-11-14 中国石油天然气股份有限公司 一种低碳烷烃脱氢制备烯烃的方法
RU2612498C2 (ru) 2011-11-21 2017-03-09 Релайанс Индастриз Лтд. Каталитическая композиция для дегидрирования углеводородов и способ ее получения
CN103127935B (zh) * 2011-11-21 2015-07-01 中国石油化工股份有限公司 一种介孔碳负载型铜基催化剂、其制备方法及其应用
CN104507566A (zh) 2012-06-21 2015-04-08 瑞来斯实业公司 废链烷烃脱氢催化剂的再生
CN103769136B (zh) * 2012-10-24 2015-10-21 中国石油化工股份有限公司 一种丙烷氧化脱氢催化剂的制备方法
US20140200384A1 (en) * 2013-01-16 2014-07-17 James W. Kauffman Dehydrogenation manganese-containing catalyst, its use and method of preparation
EP2969172B1 (en) * 2013-03-14 2017-05-10 Clariant Corporation Method of shutting down a reactor
CN105363473B (zh) * 2014-08-27 2018-10-23 中国石油化工股份有限公司 低碳烷烃脱氢制低碳烯烃铂催化剂
DE102014013530A1 (de) * 2014-09-12 2016-03-17 Clariant International Ltd. Extrudierter Cu-Al-Mn-Hydrierkatalysator
ES2740724T3 (es) * 2015-06-29 2020-02-06 Smh Co Ltd Catalizador de deshidrogenación y procedimiento que utiliza el catalizador
US10751703B2 (en) * 2015-06-30 2020-08-25 Reliance Industries Limited Reforming catalyst and a process for preparation thereof
US9956553B2 (en) * 2016-06-28 2018-05-01 Chevron U.S.A. Inc. Regeneration of an ionic liquid catalyst by hydrogenation using a macroporous noble metal catalyst
CN108722402B (zh) * 2017-04-20 2019-08-20 中国石油化工股份有限公司 一种丙烷脱氢催化剂及其制备方法和丙烷脱氢制丙烯的方法
KR102234966B1 (ko) 2017-06-07 2021-03-31 에스케이가스 주식회사 안정성, 전환율 및 선택도가 향상된 올레핀 제조용 촉매 및 그 제조방법
US10646855B2 (en) * 2017-11-02 2020-05-12 Uop Llc Catalyst and process for the selective conversion of hydrocarbons
KR102411271B1 (ko) * 2017-11-02 2022-06-23 유오피 엘엘씨 감소된 수소 대 탄화수소 비에서의 탈수소화 방법
WO2019089908A1 (en) * 2017-11-02 2019-05-09 Uop Llc Processes for regenerating a catalyst for the selective conversion of hydrocarbons
CN110560040B (zh) * 2018-06-05 2021-10-01 中国石油化工股份有限公司 丙烷脱氢制丙烯的催化剂
RU2699354C1 (ru) * 2018-11-27 2019-09-05 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН) Катализатор защитного слоя для переработки тяжелого нефтяного сырья и способ его приготовления
EP3967396A4 (en) * 2019-05-06 2023-04-12 China Petroleum & Chemical Corporation CATALYST FOR DEHYDROGENATING RAW ORGANIC HYDROGEN STORAGE MATERIAL, CATALYST SUPPORT, HYDROGEN STORAGE ALLOY AND METHOD FOR PROVIDING HIGH PURITY HYDROGEN
CN111893360B (zh) * 2019-05-06 2022-10-21 中国石油化工股份有限公司 Ab5型储氢合金及其制备方法和应用以及含有机物氢气提纯方法
CN112934230B (zh) * 2019-11-26 2023-10-27 中国石油天然气股份有限公司 低Pt型长链烷烃脱氢催化剂、其制备方法及应用
KR102332406B1 (ko) * 2020-03-10 2021-11-26 에스케이가스 주식회사 알칸족 가스로부터 올레핀 제조용 탈수소촉매 및 그 제조방법
KR102320432B1 (ko) * 2020-11-03 2021-11-01 에스케이가스 주식회사 알칸족 가스로부터 올레핀을 제조하기 위한 탈수소촉매 및 그 제조방법
US20220203340A1 (en) * 2020-12-30 2022-06-30 Uop Llc Light paraffin dehydrogenation catalysts and their application in fluidized bed dehydrogenation processes

Family Cites Families (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL106369C (pt) 1960-10-21
US3201487A (en) 1961-09-19 1965-08-17 Sinclair Research Inc Aromatic alkylation with a silicaalumina-chromia catalyst
US3274287A (en) 1964-04-21 1966-09-20 Monsanto Co Hydrocarbon conversion process and catalyst
US3315008A (en) 1964-12-28 1967-04-18 Monsanto Co Dehydrogenation of saturated hydrocarbons over noble-metal catalyst
US3315007A (en) 1964-12-28 1967-04-18 Monsanto Co Dehydrogenation of saturated hydrocarbons over noble-metal catalyst
OA02047A (fr) 1965-02-13 1970-05-05 Inst Francais Du Petrole Procédé d'hydrogenation selective des diolefines.
US3293319A (en) 1966-02-14 1966-12-20 Universal Oil Prod Co Catalytic dehydrogenation of paraffinic hydrocarbons
US3448165A (en) 1966-07-26 1969-06-03 Universal Oil Prod Co Catalytic dehydrogenation of paraffinic hydrocarbons at high space velocity
US3632663A (en) 1967-04-21 1972-01-04 British Petroleum Co Production of hexenes
GB1200651A (en) 1967-05-02 1970-07-29 British Petroleum Co Dehydrogenation process
US3484498A (en) 1967-12-11 1969-12-16 Universal Oil Prod Co Process for the preparation of aryl-substituted normal paraffin hydrocarbons
US3458592A (en) 1967-12-12 1969-07-29 Texaco Inc Manufacture of n-mono-olefins from n-paraffins
US3585253A (en) 1968-03-22 1971-06-15 Monsanto Co Production of alkylaryl sulfonates including the step of dehydrogenating normal paraffins with improved catalyst
DE1926503C3 (de) 1968-05-27 1975-03-20 Maruzen Oil Co. Ltd., Osaka (Japan) Verfahren zu selektiven Hydrierung von mehrfach ungesättigten Kohlenwasserstoffen
US3494971A (en) 1969-04-18 1970-02-10 Universal Oil Prod Co Process for the production of a monoalkylated aromatic hydrocarbon
US3576766A (en) 1969-07-09 1971-04-27 Universal Oil Prod Co Dehydrogenation method and catalytic composite for use therein
US3647719A (en) 1969-08-21 1972-03-07 Universal Oil Prod Co Dehydrogenation method and catalytic composite for use therein
US3649566A (en) 1970-01-12 1972-03-14 Universal Oil Prod Co Dehydrogenation catalysts containing platinum rhenium a group vi transition metal and an alkali or alkaline earth metal
US3655621A (en) 1970-03-23 1972-04-11 Signal Oil & Gas Co Adding mercaptan sulfur to a selective hydrogenation process
US3696160A (en) 1970-03-26 1972-10-03 Exxon Research Engineering Co Selective hydrogenation of diolefins
US3632662A (en) 1970-03-26 1972-01-04 Monsanto Co Dehydrogenation process
US3662018A (en) 1970-05-15 1972-05-09 Texaco Inc Process of improving the selectivity of dehydrogenation catalysts
US3761531A (en) 1970-06-26 1973-09-25 Universal Oil Prod Co Dehydrogenation with a multicomponent catalyst
US3767594A (en) 1970-08-20 1973-10-23 Universal Oil Prod Co Dehydrogenation catalyst
US3825612A (en) 1970-10-16 1974-07-23 Universal Oil Prod Co Dehydrogenation with a multicomponent catalyst
US3745112A (en) 1971-11-23 1973-07-10 Universal Oil Prod Co Platinum-tin uniformly dispersed hydro-carbon conversion catalyst and process
US3751506A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst
US3998900A (en) 1973-03-05 1976-12-21 Universal Oil Products Company Dehydrogenation of hydrocarbons with a multimetallic catalytic composite
US4172853A (en) 1973-12-06 1979-10-30 Uop Inc. Hydrocarbon dehydrogenation with a multimetallic catalytic composite
US3993601A (en) * 1974-02-07 1976-11-23 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US3887455A (en) * 1974-03-25 1975-06-03 Exxon Research Engineering Co Ebullating bed process for hydrotreatment of heavy crudes and residua
US3920615A (en) * 1974-08-30 1975-11-18 Monsanto Co Production of alkylaryl sulfonates including the step of dehydrogenating normal paraffins with an improved catalyst
US4048246A (en) 1975-05-05 1977-09-13 Uop Inc. Dehydrogenation method and nonacidic multimetallic catalytic composite for use therein
US4016106A (en) * 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
US4177218A (en) 1976-06-24 1979-12-04 Uop Inc. Dehydrogenation process utilizing multimetallic catalytic composite
US4036743A (en) 1976-09-20 1977-07-19 Uop Inc. Hydrocarbon conversion with an acidic multimetallic catalytic composite
US4070413A (en) 1976-10-28 1978-01-24 Uop Inc. Dehydrogenation of saturated hydrocarbons
US4207425A (en) 1977-04-11 1980-06-10 Uop Inc. Dehydrogenation method and nonacidic multimetallic catalytic composite for use therein
US4136127A (en) 1977-06-27 1979-01-23 Uop Inc. Dehydrogenation method and multimetallic catalytic composite for use therein
US4268706A (en) 1978-05-15 1981-05-19 Uop Inc. Hydrocarbon dehydrogenation method and nonacidic multimetallic catalytic composite for use therein
US4227026A (en) 1978-08-10 1980-10-07 Uop Inc. Dehydrogenation method and nonacidic multimetallic catalytic composite for use therein
US4216346A (en) 1979-03-05 1980-08-05 Uop Inc. Hydrocarbon dehydrogenation method employing platinum-cobalt-zinc catalyst
US4278566A (en) * 1979-03-19 1981-07-14 Standard Oil Company (Indiana) Hydrotreating process
US4312792A (en) 1979-05-04 1982-01-26 Uop Inc. Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein
US4341664A (en) 1979-06-15 1982-07-27 Uop Inc. Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein
US4343724A (en) 1979-10-01 1982-08-10 Uop Inc. Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein
FR2482953A1 (fr) 1980-05-22 1981-11-27 Inst Francais Du Petrole Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a
US4489213A (en) 1980-08-25 1984-12-18 Ashland Oil, Inc. Alumina catalyst for alkylating aromatics with olefins
US4409412A (en) 1981-01-30 1983-10-11 Mobil Oil Corporation Process for producing alkyl aromatic compounds
US4396540A (en) 1981-03-23 1983-08-02 Uop Inc. Hydrocarbon dehydrogenation with a multimetallic catalytic composite
US4358628A (en) 1981-06-26 1982-11-09 Shell Oil Company Alkylation of benzene compounds with detergent range olefins
US4387259A (en) 1981-07-16 1983-06-07 Mobil Oil Corporation Selective alkylation of aromatic hydrocarbons using a mixed ethylene/propylene alkylation agent
US4409401A (en) 1981-08-17 1983-10-11 Phillips Petroleum Company Selective hydrogenation of organic materials
US4486547A (en) 1981-11-05 1984-12-04 Uop Inc. Indium-containing dehydrogenation catalyst
US4430517A (en) 1981-12-02 1984-02-07 Uop Inc. Dehydrogenation process using a catalytic composition
US4551574A (en) 1983-06-02 1985-11-05 Uop Inc. Indium-containing dehydrogenation catalyst
US4551571A (en) 1984-03-14 1985-11-05 Mitsubishi Petrochemical Co., Ltd. Production of alkenylbenzenes
US4523048A (en) 1984-04-04 1985-06-11 Uop Inc. Process for the selective production of alkylbenzenes
US4677237A (en) 1984-11-29 1987-06-30 Uop Inc. Dehydrogenation catalyst compositions
US4595673A (en) 1984-11-29 1986-06-17 Uop Inc. Dehydrogenation catalyst compositions and method of their preparation
US4598060A (en) * 1985-01-28 1986-07-01 Shell Oil Company Process for the preparation of wide pore catalysts
US4608360A (en) 1985-07-02 1986-08-26 Uop Inc. Dehydrogenation catalyst compositions and method of preparing same
US4827072A (en) 1986-06-06 1989-05-02 Uop Inc. Dehydrogenation catalyst composition and hydrocarbon dehydrogenation process
US5028665A (en) * 1989-01-09 1991-07-02 The Dow Chemical Company Polymer hydrogenation catalysts
ES2032371T3 (es) 1990-06-05 1996-03-16 Huntsman Spec Chem Corp Procedimiento para deshidrogenacion de parafina.
JP2814711B2 (ja) * 1990-07-13 1998-10-27 三菱化学株式会社 シクロオレフィンの製造法
DE59300865D1 (de) * 1992-03-13 1995-12-07 Solvay Umweltchemie Gmbh Abriebfester trägerkatalysator.
CA2093412C (en) * 1992-04-20 2002-12-31 Gerald Verdell Nelson Novel hydroconversion process employing catalyst with specified pore size distribution
US5827421A (en) * 1992-04-20 1998-10-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution and no added silica
CN1032678C (zh) * 1992-12-21 1996-09-04 中国石油化工总公司 饱和烃类脱氢用催化剂
US5677260A (en) 1995-06-23 1997-10-14 Indian Petrochemicals Corporation Limited Catalyst composite for dehydrogenation of paraffins to mono-olefins and method for the preparation thereof
US6242379B1 (en) * 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts
US6417135B1 (en) * 1999-08-27 2002-07-09 Huntsman Petrochemical Corporation Advances in dehydrogenation catalysis

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MY136001A (en) 2008-07-31
US6417135B1 (en) 2002-07-09
AR025368A1 (es) 2002-11-20
CN1371304A (zh) 2002-09-25
CN1127372C (zh) 2003-11-12
DE60003571T2 (de) 2004-04-08
EP1216093B1 (en) 2003-06-25
ES2202163T3 (es) 2004-04-01
MXPA02001925A (es) 2002-10-31
US6700028B2 (en) 2004-03-02
DE60003571D1 (de) 2003-07-31
US20020183580A1 (en) 2002-12-05
EP1216093A1 (en) 2002-06-26
CA2381893A1 (en) 2001-03-08

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