BE904371A - Procede d'epoxydation d'une olefine. - Google Patents

Procede d'epoxydation d'une olefine.

Info

Publication number
BE904371A
BE904371A BE0/216381A BE216381A BE904371A BE 904371 A BE904371 A BE 904371A BE 0/216381 A BE0/216381 A BE 0/216381A BE 216381 A BE216381 A BE 216381A BE 904371 A BE904371 A BE 904371A
Authority
BE
Belgium
Prior art keywords
epoxidation
olefin
oxyrane
chosen
butyene
Prior art date
Application number
BE0/216381A
Other languages
English (en)
Original Assignee
Fmc Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fmc Corp filed Critical Fmc Corp
Publication of BE904371A publication Critical patent/BE904371A/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/24—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
    • C07C409/30—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids a >C=O group being bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/54—Preparation of carboxylic acid anhydrides
    • C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • C07D301/16—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof formed in situ, e.g. from carboxylic acids and hydrogen peroxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Catalysts (AREA)

Abstract

Procédé d'époxydation des oléfines en un oxyrane, en formant un acide monopercarboxylique in situ, en faisant réagir un anhydride cyclique d'un polyacide avec du péroxyde d'hydrogène en présence d'un catalyseur basique et en recueillant l'oxyrane sous forme de distillat. Il est avantageux de travailler dans un mélange d'eau et d'un solvant choisi parmi le sulfolane, la pyrolidone, la N-méthyl-2-pyrrolidone, et la tétrabutyl urée, l'oléfine est choisi parmi le propylène et le butyène.
BE0/216381A 1985-10-28 1986-03-07 Procede d'epoxydation d'une olefine. BE904371A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/791,811 US4590286A (en) 1985-10-28 1985-10-28 Process for epoxidizing an olefin

Publications (1)

Publication Number Publication Date
BE904371A true BE904371A (fr) 1986-09-08

Family

ID=25154857

Family Applications (1)

Application Number Title Priority Date Filing Date
BE0/216381A BE904371A (fr) 1985-10-28 1986-03-07 Procede d'epoxydation d'une olefine.

Country Status (10)

Country Link
US (1) US4590286A (fr)
JP (1) JPS62106089A (fr)
BE (1) BE904371A (fr)
CA (1) CA1246595A (fr)
DE (1) DE3607883A1 (fr)
ES (1) ES8800189A1 (fr)
FR (1) FR2589155B1 (fr)
GB (1) GB2182035B (fr)
IT (1) IT1191979B (fr)
MX (1) MX166298B (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19505858A1 (de) * 1995-02-21 1996-10-31 Basf Ag Verfahren zur Herstellung von Epoxiden mittels aromatischer Peroxycarbonsäuren
US6010729A (en) 1998-08-20 2000-01-04 Ecolab Inc. Treatment of animal carcasses
US6534621B2 (en) * 2000-05-18 2003-03-18 Dow Global Technologies Inc. Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom
PL201541B1 (pl) * 2002-10-30 2009-04-30 Inst Farmaceutyczny Sposób wytwarzania N-(4-cyjano-3-trifluorometylofenylo)-2,3-epoksy-2-metylopropanamidu
DE602004013933D1 (de) * 2003-03-04 2008-07-03 Firmenich & Cie Verfahren zur herstellung von lactonen oder epoxiden
WO2005063821A1 (fr) * 2003-12-24 2005-07-14 Pirelli Pneumatici S.P.A. Procede permettant de produire un polymere elastomere expoxyde
US7547421B2 (en) 2006-10-18 2009-06-16 Ecolab Inc. Apparatus and method for making a peroxycarboxylic acid
US8075857B2 (en) 2006-10-18 2011-12-13 Ecolab Usa Inc. Apparatus and method for making a peroxycarboxylic acid
WO2008102659A1 (fr) * 2007-02-22 2008-08-28 Adeka Corporation Composition d'agent oxydant pour l'époxydation d'oléfines et procédé pour l'époxydation des oléfines
JP5357038B2 (ja) * 2007-09-26 2013-12-04 株式会社Ａｄｅｋａ オレフィン類のエポキシ化方法
CN110591054B (zh) * 2019-09-17 2021-05-18 江苏泰特尔新材料科技股份有限公司 一种总氯含量低、无重金属残留的环氧化物及其合成工艺
CN112028858A (zh) * 2020-09-11 2020-12-04 中国天辰工程有限公司 一种环氧环己烷的合成方法
CN112047904A (zh) * 2020-09-11 2020-12-08 中国天辰工程有限公司 一种利用微通道反应器制备环氧环己烷的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3155638A (en) * 1960-06-22 1964-11-03 Allied Chem Process for epoxidation of ethylenically unsaturated compounds
CH393295A (de) * 1960-07-25 1965-06-15 Ciba Geigy Verfahren zur Herstellung von den Oxiranring enthaltenden Verbindungen
FR1452737A (fr) * 1965-07-29 1966-04-15 Air Liquide Procédé de préparation d'acide monoperphtalique stable

Also Published As

Publication number Publication date
GB8604194D0 (en) 1986-03-26
ES8800189A1 (es) 1987-11-01
FR2589155A1 (fr) 1987-04-30
IT8619616A0 (it) 1986-03-04
GB2182035A (en) 1987-05-07
DE3607883A1 (de) 1987-04-30
IT1191979B (it) 1988-03-31
CA1246595A (fr) 1988-12-13
US4590286A (en) 1986-05-20
DE3607883C2 (fr) 1989-12-21
JPH0246583B2 (fr) 1990-10-16
IT8619616A1 (it) 1987-09-04
GB2182035B (en) 1989-12-28
ES552811A0 (es) 1987-11-01
FR2589155B1 (fr) 1989-03-10
MX166298B (es) 1992-12-29
JPS62106089A (ja) 1987-05-16

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Legal Events

Date Code Title Description
RE Patent lapsed

Owner name: FMC CORP.

Effective date: 19990331