BE904371A - Procede d'epoxydation d'une olefine. - Google Patents
Procede d'epoxydation d'une olefine.Info
- Publication number
- BE904371A BE904371A BE0/216381A BE216381A BE904371A BE 904371 A BE904371 A BE 904371A BE 0/216381 A BE0/216381 A BE 0/216381A BE 216381 A BE216381 A BE 216381A BE 904371 A BE904371 A BE 904371A
- Authority
- BE
- Belgium
- Prior art keywords
- epoxidation
- olefin
- oxyrane
- chosen
- butyene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/24—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids
- C07C409/30—Peroxy compounds the —O—O— group being bound between a >C=O group and hydrogen, i.e. peroxy acids a >C=O group being bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
- C07D301/16—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof formed in situ, e.g. from carboxylic acids and hydrogen peroxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Catalysts (AREA)
Abstract
Procédé d'époxydation des oléfines en un oxyrane, en formant un acide monopercarboxylique in situ, en faisant réagir un anhydride cyclique d'un polyacide avec du péroxyde d'hydrogène en présence d'un catalyseur basique et en recueillant l'oxyrane sous forme de distillat. Il est avantageux de travailler dans un mélange d'eau et d'un solvant choisi parmi le sulfolane, la pyrolidone, la N-méthyl-2-pyrrolidone, et la tétrabutyl urée, l'oléfine est choisi parmi le propylène et le butyène.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/791,811 US4590286A (en) | 1985-10-28 | 1985-10-28 | Process for epoxidizing an olefin |
Publications (1)
Publication Number | Publication Date |
---|---|
BE904371A true BE904371A (fr) | 1986-09-08 |
Family
ID=25154857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE0/216381A BE904371A (fr) | 1985-10-28 | 1986-03-07 | Procede d'epoxydation d'une olefine. |
Country Status (10)
Country | Link |
---|---|
US (1) | US4590286A (fr) |
JP (1) | JPS62106089A (fr) |
BE (1) | BE904371A (fr) |
CA (1) | CA1246595A (fr) |
DE (1) | DE3607883A1 (fr) |
ES (1) | ES8800189A1 (fr) |
FR (1) | FR2589155B1 (fr) |
GB (1) | GB2182035B (fr) |
IT (1) | IT1191979B (fr) |
MX (1) | MX166298B (fr) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19505858A1 (de) * | 1995-02-21 | 1996-10-31 | Basf Ag | Verfahren zur Herstellung von Epoxiden mittels aromatischer Peroxycarbonsäuren |
US6010729A (en) | 1998-08-20 | 2000-01-04 | Ecolab Inc. | Treatment of animal carcasses |
US6534621B2 (en) * | 2000-05-18 | 2003-03-18 | Dow Global Technologies Inc. | Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom |
PL201541B1 (pl) * | 2002-10-30 | 2009-04-30 | Inst Farmaceutyczny | Sposób wytwarzania N-(4-cyjano-3-trifluorometylofenylo)-2,3-epoksy-2-metylopropanamidu |
WO2004078738A1 (fr) * | 2003-03-04 | 2004-09-16 | Firmenich Sa | Procede de preparation de lactones ou d'epoxydes |
WO2005063821A1 (fr) * | 2003-12-24 | 2005-07-14 | Pirelli Pneumatici S.P.A. | Procede permettant de produire un polymere elastomere expoxyde |
US8075857B2 (en) | 2006-10-18 | 2011-12-13 | Ecolab Usa Inc. | Apparatus and method for making a peroxycarboxylic acid |
US7547421B2 (en) | 2006-10-18 | 2009-06-16 | Ecolab Inc. | Apparatus and method for making a peroxycarboxylic acid |
CN101616904B (zh) * | 2007-02-22 | 2012-11-14 | 株式会社Adeka | 用于烯烃类的环氧化的氧化剂组合物及烯烃类的环氧化方法 |
CN101801945A (zh) * | 2007-09-26 | 2010-08-11 | 株式会社Adeka | 环氧化用氧化剂组合物及其氧化方法 |
CN110591054B (zh) * | 2019-09-17 | 2021-05-18 | 江苏泰特尔新材料科技股份有限公司 | 一种总氯含量低、无重金属残留的环氧化物及其合成工艺 |
CN112028858A (zh) * | 2020-09-11 | 2020-12-04 | 中国天辰工程有限公司 | 一种环氧环己烷的合成方法 |
CN112047904A (zh) * | 2020-09-11 | 2020-12-08 | 中国天辰工程有限公司 | 一种利用微通道反应器制备环氧环己烷的方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3155638A (en) * | 1960-06-22 | 1964-11-03 | Allied Chem | Process for epoxidation of ethylenically unsaturated compounds |
CH393295A (de) * | 1960-07-25 | 1965-06-15 | Ciba Geigy | Verfahren zur Herstellung von den Oxiranring enthaltenden Verbindungen |
FR1452737A (fr) * | 1965-07-29 | 1966-04-15 | Air Liquide | Procédé de préparation d'acide monoperphtalique stable |
-
1985
- 1985-10-28 US US06/791,811 patent/US4590286A/en not_active Expired - Lifetime
-
1986
- 1986-02-19 CA CA000502183A patent/CA1246595A/fr not_active Expired
- 1986-02-20 GB GB8604194A patent/GB2182035B/en not_active Expired
- 1986-03-04 IT IT19616/86A patent/IT1191979B/it active
- 1986-03-07 FR FR868603240A patent/FR2589155B1/fr not_active Expired
- 1986-03-07 BE BE0/216381A patent/BE904371A/fr not_active IP Right Cessation
- 1986-03-08 ES ES552811A patent/ES8800189A1/es not_active Expired
- 1986-03-10 JP JP61050718A patent/JPS62106089A/ja active Granted
- 1986-03-10 MX MX001813A patent/MX166298B/es unknown
- 1986-03-10 DE DE19863607883 patent/DE3607883A1/de active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2589155B1 (fr) | 1989-03-10 |
MX166298B (es) | 1992-12-29 |
JPH0246583B2 (fr) | 1990-10-16 |
DE3607883C2 (fr) | 1989-12-21 |
ES552811A0 (es) | 1987-11-01 |
GB2182035B (en) | 1989-12-28 |
GB8604194D0 (en) | 1986-03-26 |
ES8800189A1 (es) | 1987-11-01 |
IT1191979B (it) | 1988-03-31 |
US4590286A (en) | 1986-05-20 |
IT8619616A1 (it) | 1987-09-04 |
GB2182035A (en) | 1987-05-07 |
DE3607883A1 (de) | 1987-04-30 |
IT8619616A0 (it) | 1986-03-04 |
JPS62106089A (ja) | 1987-05-16 |
CA1246595A (fr) | 1988-12-13 |
FR2589155A1 (fr) | 1987-04-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Patent lapsed |
Owner name: FMC CORP. Effective date: 19990331 |