BE884396A - Procede d'epoxydation d'olefines par une reaction d'oxydation catalytique en phase liquide - Google Patents
Procede d'epoxydation d'olefines par une reaction d'oxydation catalytique en phase liquide Download PDFInfo
- Publication number
- BE884396A BE884396A BE0/201469A BE201469A BE884396A BE 884396 A BE884396 A BE 884396A BE 0/201469 A BE0/201469 A BE 0/201469A BE 201469 A BE201469 A BE 201469A BE 884396 A BE884396 A BE 884396A
- Authority
- BE
- Belgium
- Prior art keywords
- emi
- group
- hydrogen peroxide
- chosen
- olefin
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 95
- 150000001336 alkenes Chemical class 0.000 title claims description 44
- 230000008569 process Effects 0.000 title claims description 33
- 230000003197 catalytic effect Effects 0.000 title claims description 27
- 238000006735 epoxidation reaction Methods 0.000 title claims description 15
- 238000007254 oxidation reaction Methods 0.000 title description 8
- 239000007791 liquid phase Substances 0.000 title description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 105
- 238000006243 chemical reaction Methods 0.000 claims description 75
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 22
- 150000003839 salts Chemical class 0.000 claims description 20
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- 239000012071 phase Substances 0.000 claims description 17
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- 229910052721 tungsten Inorganic materials 0.000 claims description 15
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 14
- 239000010937 tungsten Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 239000012074 organic phase Substances 0.000 claims description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 11
- 125000004429 atom Chemical group 0.000 claims description 11
- 239000011733 molybdenum Substances 0.000 claims description 11
- 229910052785 arsenic Inorganic materials 0.000 claims description 10
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 10
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- 125000003342 alkenyl group Chemical group 0.000 claims description 3
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- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003254 radicals Chemical group 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- CGFYHILWFSGVJS-UHFFFAOYSA-N silicic acid;trioxotungsten Chemical compound O[Si](O)(O)O.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1.O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 CGFYHILWFSGVJS-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- NNENFOSYDBTCBO-UHFFFAOYSA-M tributyl(hexadecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC NNENFOSYDBTCBO-UHFFFAOYSA-M 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT7924478A IT1122214B (it) | 1979-07-19 | 1979-07-19 | Processo per l'epossidazione catalitica di olefine con acqua ossigenata |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE884396A true BE884396A (fr) | 1981-01-19 |
Family
ID=11213682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE0/201469A BE884396A (fr) | 1979-07-19 | 1980-07-18 | Procede d'epoxydation d'olefines par une reaction d'oxydation catalytique en phase liquide |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5618972A (enrdf_load_stackoverflow) |
| BE (1) | BE884396A (enrdf_load_stackoverflow) |
| IT (1) | IT1122214B (enrdf_load_stackoverflow) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5839676A (ja) * | 1981-09-04 | 1983-03-08 | Mitsubishi Gas Chem Co Inc | オレフインオキシドの製造法 |
| JP2794678B2 (ja) | 1991-08-26 | 1998-09-10 | 株式会社 半導体エネルギー研究所 | 絶縁ゲイト型半導体装置およびその作製方法 |
| BE1011456A3 (fr) * | 1997-09-18 | 1999-09-07 | Solvay | Procede de fabrication d'un oxiranne. |
| JP2003073323A (ja) * | 2001-09-04 | 2003-03-12 | Nippon Shokubai Co Ltd | 有機化合物の酸化方法 |
| JP5243123B2 (ja) * | 2007-12-28 | 2013-07-24 | 日本化薬株式会社 | エポキシ組成物、エポキシ組成物の製造方法、硬化性樹脂組成物、および硬化物 |
| JPWO2009088087A1 (ja) * | 2008-01-10 | 2011-05-26 | 日本化薬株式会社 | エポキシ化触媒、エポキシ化触媒の製造方法、エポキシ化合物の製造方法、硬化性樹脂組成物及びその硬化物 |
| US8742145B2 (en) | 2009-07-24 | 2014-06-03 | Arakawa Chemical Industries, Ltd. | Method for manufacturing an epoxy compound and method for epoxidizing a carbon—carbon double bond |
| KR102049711B1 (ko) | 2012-03-30 | 2019-11-28 | 미쯔비시 케미컬 주식회사 | 에폭시 화합물의 제조 방법 및 에폭시화 반응용 촉매 조성물 |
| DE102014209421A1 (de) * | 2014-05-19 | 2015-11-19 | Evonik Degussa Gmbh | Membrangestützte Katalysatorabtrennung bei der Epoxidierung von cyclischen, ungesättigten C12-Verbindungen zum Beispiel Cyclododecen (CDEN) |
| WO2017089075A1 (de) * | 2015-11-25 | 2017-06-01 | Evonik Degussa Gmbh | Verfahren zur herstellung von 1,2-propandiol aus propen und wasserstoffperoxid |
-
1979
- 1979-07-19 IT IT7924478A patent/IT1122214B/it active
-
1980
- 1980-07-18 JP JP9768280A patent/JPS5618972A/ja active Granted
- 1980-07-18 BE BE0/201469A patent/BE884396A/fr not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0133471B2 (enrdf_load_stackoverflow) | 1989-07-13 |
| IT1122214B (it) | 1986-04-23 |
| IT7924478A0 (it) | 1979-07-19 |
| JPS5618972A (en) | 1981-02-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RE | Patent lapsed |
Owner name: ISTITUTO GUIDO DONEGANI S.P.A. Effective date: 19990731 |