AU759408B2 - Grafting of ethylenically unsaturated monomers onto polymers - Google Patents

Grafting of ethylenically unsaturated monomers onto polymers Download PDF

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Publication number
AU759408B2
AU759408B2 AU57387/99A AU5738799A AU759408B2 AU 759408 B2 AU759408 B2 AU 759408B2 AU 57387/99 A AU57387/99 A AU 57387/99A AU 5738799 A AU5738799 A AU 5738799A AU 759408 B2 AU759408 B2 AU 759408B2
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AU
Australia
Prior art keywords
alkyl
cycloalkyl
radical
substituted
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU57387/99A
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English (en)
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AU5738799A (en
Inventor
Rudolf Pfaendner
Michael Roth
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BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
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Publication of AU5738799A publication Critical patent/AU5738799A/en
Application granted granted Critical
Publication of AU759408B2 publication Critical patent/AU759408B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerization Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AU57387/99A 1998-09-03 1999-08-23 Grafting of ethylenically unsaturated monomers onto polymers Ceased AU759408B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98810878 1998-09-03
EP98810878 1998-09-03
PCT/EP1999/006171 WO2000014134A1 (en) 1998-09-03 1999-08-23 Grafting of ethylenically unsaturated monomers onto polymers

Publications (2)

Publication Number Publication Date
AU5738799A AU5738799A (en) 2000-03-27
AU759408B2 true AU759408B2 (en) 2003-04-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
AU57387/99A Ceased AU759408B2 (en) 1998-09-03 1999-08-23 Grafting of ethylenically unsaturated monomers onto polymers

Country Status (12)

Country Link
US (1) US6525151B1 (enExample)
EP (1) EP1115765B1 (enExample)
JP (1) JP4516212B2 (enExample)
KR (1) KR100575170B1 (enExample)
CN (1) CN1298755C (enExample)
AT (1) ATE434635T1 (enExample)
AU (1) AU759408B2 (enExample)
BR (1) BR9913419A (enExample)
CA (1) CA2341372A1 (enExample)
DE (1) DE69941028D1 (enExample)
ES (1) ES2325697T3 (enExample)
WO (1) WO2000014134A1 (enExample)

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SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
AU760128B2 (en) * 1998-09-03 2003-05-08 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
KR20020030822A (ko) * 1999-09-15 2002-04-25 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 펄프에 대한 친화성이 높은 중합성 안정화제
US6414048B1 (en) * 1999-12-07 2002-07-02 Sumitomo Electric Fine Polymer, Inc. Chemical grafting onto a substrate and coating composition
TW541303B (en) 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
CA2444971C (en) 2001-05-15 2011-02-22 Ciba Specialty Chemicals Holding Inc. Method of grafting ethylenically unsaturated carboxylic acid derivatives onto thermoplastic polymers using hydroxylamine esters
MXPA04012671A (es) * 2002-06-20 2005-03-23 Ciba Sc Holding Ag INJERTO DE OLIGOMEROS O POLIMEROS TERMINADOS EN NITROXILO SOBRE POLIMEROS TERMOPLáSTICOS.
AU2003297182A1 (en) * 2002-12-18 2004-07-22 Crompton Corporation Styrenic polymer composites
WO2004069887A2 (en) * 2003-02-10 2004-08-19 Ciba Specialty Chemicals Holding Inc. Comb copolymers with defined side chains and process for their manufacture
US20040220345A1 (en) * 2003-05-01 2004-11-04 Firestone Polymers, Llc Stable free radical polymers
US6967228B2 (en) * 2003-05-01 2005-11-22 Firestone Polymers, Llc Stable free radical polymers
US20070106029A1 (en) * 2003-06-26 2007-05-10 Mitsubishi Rayon Co., Ltd. Modified polyolefin resin and composition
US7279527B2 (en) * 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
KR100666818B1 (ko) * 2006-02-20 2007-01-09 주식회사 엘지화학 우수한 저온색상안정성을 갖는 열가소성 성형재
JP2008044996A (ja) * 2006-08-11 2008-02-28 Mitsui Chemicals Inc オレフィン系重合体
JP4819616B2 (ja) * 2006-08-11 2011-11-24 三井化学株式会社 オレフィン系重合体
US8030410B2 (en) * 2006-12-29 2011-10-04 Bridgestone Corporation Method for generating free radical capable polymers using carbonyl-containing compounds
US7737218B2 (en) 2006-12-29 2010-06-15 Bridgestone Corporation Method for generating free radical capable polymers using tin or silicon halide compounds
US7396887B1 (en) * 2006-12-29 2008-07-08 Bridgestone Corporation Insitu removal of chelator from anionic polymerization reactions
US7560509B2 (en) * 2006-12-29 2009-07-14 Bridgestone Corporation Method of directing grafting by controlling the location of high vinyl segments in a polymer
US20080157641A1 (en) * 2006-12-31 2008-07-03 Rachael Wren Grout Multi-use Free Standing Seating and Storage Unit
CN102167784B (zh) * 2010-12-30 2013-02-20 长春工业大学 一种水性化三元乙丙橡胶的制备方法
CN102139229B (zh) * 2011-01-19 2012-10-10 华东师范大学 一种负载型金催化剂的制备方法及其应用
CN104140484B (zh) * 2013-05-08 2016-08-17 中国石油化工股份有限公司 一种支化稀土异戊橡胶及其制备方法和橡胶组合物
US10538611B2 (en) 2014-04-18 2020-01-21 Nippon A&L Inc. Graft copolymer and thermoplastic resin composition
CN104650766A (zh) * 2014-12-17 2015-05-27 浙江科达利实业有限公司 反应粘合剂胶料及其制造工艺
CN105419440A (zh) * 2015-12-18 2016-03-23 蚌埠市鑫晟新材料科技有限公司 一种可减少污染的内墙涂料添加剂的制备方法
CN108017744B (zh) * 2016-11-03 2021-07-30 中国石油化工股份有限公司 一种粉末羧基丁苯橡胶及其制备方法和应用
CN109485795B (zh) * 2018-11-08 2021-06-25 万华化学集团股份有限公司 一种共聚物相容剂及其制备方法和应用
CN112876614A (zh) * 2021-02-06 2021-06-01 中交第四公路工程局有限公司 一种杜仲胶与马来酸酐的熔融接枝方法
TW202330677A (zh) 2021-12-10 2023-08-01 義大利商佛沙里斯股份有限公司 橡膠強化的乙烯芳香族(共)聚合物及其製備方法

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WO1997036944A1 (en) * 1996-03-29 1997-10-09 The Dow Chemical Company In situ block copolymer formation during polymerization of a vinyl aromatic monomer

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Publication number Priority date Publication date Assignee Title
US4581429A (en) * 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby
WO1997036944A1 (en) * 1996-03-29 1997-10-09 The Dow Chemical Company In situ block copolymer formation during polymerization of a vinyl aromatic monomer

Also Published As

Publication number Publication date
KR20010072721A (ko) 2001-07-31
CN1315971A (zh) 2001-10-03
EP1115765A1 (en) 2001-07-18
BR9913419A (pt) 2001-05-22
ATE434635T1 (de) 2009-07-15
DE69941028D1 (de) 2009-08-06
AU5738799A (en) 2000-03-27
WO2000014134A1 (en) 2000-03-16
JP2002524589A (ja) 2002-08-06
JP4516212B2 (ja) 2010-08-04
KR100575170B1 (ko) 2006-04-28
CN1298755C (zh) 2007-02-07
ES2325697T3 (es) 2009-09-14
CA2341372A1 (en) 2000-03-16
EP1115765B1 (en) 2009-06-24
US6525151B1 (en) 2003-02-25

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