ATE434635T1 - Propfung von äthylenisch ungesättigten monomeren auf polymeren - Google Patents
Propfung von äthylenisch ungesättigten monomeren auf polymerenInfo
- Publication number
- ATE434635T1 ATE434635T1 AT99944478T AT99944478T ATE434635T1 AT E434635 T1 ATE434635 T1 AT E434635T1 AT 99944478 T AT99944478 T AT 99944478T AT 99944478 T AT99944478 T AT 99944478T AT E434635 T1 ATE434635 T1 AT E434635T1
- Authority
- AT
- Austria
- Prior art keywords
- polymer
- ethylenically unsaturated
- grafting
- grafted
- radical
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title abstract 6
- 239000000178 monomer Substances 0.000 title abstract 3
- 229920000578 graft copolymer Polymers 0.000 abstract 3
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical compound [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 238000003776 cleavage reaction Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000007017 scission Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98810878 | 1998-09-03 | ||
| PCT/EP1999/006171 WO2000014134A1 (en) | 1998-09-03 | 1999-08-23 | Grafting of ethylenically unsaturated monomers onto polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE434635T1 true ATE434635T1 (de) | 2009-07-15 |
Family
ID=8236299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99944478T ATE434635T1 (de) | 1998-09-03 | 1999-08-23 | Propfung von äthylenisch ungesättigten monomeren auf polymeren |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6525151B1 (enExample) |
| EP (1) | EP1115765B1 (enExample) |
| JP (1) | JP4516212B2 (enExample) |
| KR (1) | KR100575170B1 (enExample) |
| CN (1) | CN1298755C (enExample) |
| AT (1) | ATE434635T1 (enExample) |
| AU (1) | AU759408B2 (enExample) |
| BR (1) | BR9913419A (enExample) |
| CA (1) | CA2341372A1 (enExample) |
| DE (1) | DE69941028D1 (enExample) |
| ES (1) | ES2325697T3 (enExample) |
| WO (1) | WO2000014134A1 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG82601A1 (en) * | 1998-03-09 | 2001-08-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators |
| AU760128B2 (en) * | 1998-09-03 | 2003-05-08 | Ciba Specialty Chemicals Holding Inc. | Grafting of ethylenically unsaturated monomers onto polymers |
| KR20020030822A (ko) * | 1999-09-15 | 2002-04-25 | 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 | 펄프에 대한 친화성이 높은 중합성 안정화제 |
| US6414048B1 (en) * | 1999-12-07 | 2002-07-02 | Sumitomo Electric Fine Polymer, Inc. | Chemical grafting onto a substrate and coating composition |
| TW541303B (en) | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
| CA2444971C (en) | 2001-05-15 | 2011-02-22 | Ciba Specialty Chemicals Holding Inc. | Method of grafting ethylenically unsaturated carboxylic acid derivatives onto thermoplastic polymers using hydroxylamine esters |
| MXPA04012671A (es) * | 2002-06-20 | 2005-03-23 | Ciba Sc Holding Ag | INJERTO DE OLIGOMEROS O POLIMEROS TERMINADOS EN NITROXILO SOBRE POLIMEROS TERMOPLáSTICOS. |
| AU2003297182A1 (en) * | 2002-12-18 | 2004-07-22 | Crompton Corporation | Styrenic polymer composites |
| WO2004069887A2 (en) * | 2003-02-10 | 2004-08-19 | Ciba Specialty Chemicals Holding Inc. | Comb copolymers with defined side chains and process for their manufacture |
| US20040220345A1 (en) * | 2003-05-01 | 2004-11-04 | Firestone Polymers, Llc | Stable free radical polymers |
| US6967228B2 (en) * | 2003-05-01 | 2005-11-22 | Firestone Polymers, Llc | Stable free radical polymers |
| US20070106029A1 (en) * | 2003-06-26 | 2007-05-10 | Mitsubishi Rayon Co., Ltd. | Modified polyolefin resin and composition |
| US7279527B2 (en) * | 2005-04-22 | 2007-10-09 | Bridgestone Corporation | Method of converting anionic living end to protected free radical living end and applications thereof |
| KR100666818B1 (ko) * | 2006-02-20 | 2007-01-09 | 주식회사 엘지화학 | 우수한 저온색상안정성을 갖는 열가소성 성형재 |
| JP2008044996A (ja) * | 2006-08-11 | 2008-02-28 | Mitsui Chemicals Inc | オレフィン系重合体 |
| JP4819616B2 (ja) * | 2006-08-11 | 2011-11-24 | 三井化学株式会社 | オレフィン系重合体 |
| US8030410B2 (en) * | 2006-12-29 | 2011-10-04 | Bridgestone Corporation | Method for generating free radical capable polymers using carbonyl-containing compounds |
| US7737218B2 (en) | 2006-12-29 | 2010-06-15 | Bridgestone Corporation | Method for generating free radical capable polymers using tin or silicon halide compounds |
| US7396887B1 (en) * | 2006-12-29 | 2008-07-08 | Bridgestone Corporation | Insitu removal of chelator from anionic polymerization reactions |
| US7560509B2 (en) * | 2006-12-29 | 2009-07-14 | Bridgestone Corporation | Method of directing grafting by controlling the location of high vinyl segments in a polymer |
| US20080157641A1 (en) * | 2006-12-31 | 2008-07-03 | Rachael Wren Grout | Multi-use Free Standing Seating and Storage Unit |
| CN102167784B (zh) * | 2010-12-30 | 2013-02-20 | 长春工业大学 | 一种水性化三元乙丙橡胶的制备方法 |
| CN102139229B (zh) * | 2011-01-19 | 2012-10-10 | 华东师范大学 | 一种负载型金催化剂的制备方法及其应用 |
| CN104140484B (zh) * | 2013-05-08 | 2016-08-17 | 中国石油化工股份有限公司 | 一种支化稀土异戊橡胶及其制备方法和橡胶组合物 |
| US10538611B2 (en) | 2014-04-18 | 2020-01-21 | Nippon A&L Inc. | Graft copolymer and thermoplastic resin composition |
| CN104650766A (zh) * | 2014-12-17 | 2015-05-27 | 浙江科达利实业有限公司 | 反应粘合剂胶料及其制造工艺 |
| CN105419440A (zh) * | 2015-12-18 | 2016-03-23 | 蚌埠市鑫晟新材料科技有限公司 | 一种可减少污染的内墙涂料添加剂的制备方法 |
| CN108017744B (zh) * | 2016-11-03 | 2021-07-30 | 中国石油化工股份有限公司 | 一种粉末羧基丁苯橡胶及其制备方法和应用 |
| CN109485795B (zh) * | 2018-11-08 | 2021-06-25 | 万华化学集团股份有限公司 | 一种共聚物相容剂及其制备方法和应用 |
| CN112876614A (zh) * | 2021-02-06 | 2021-06-01 | 中交第四公路工程局有限公司 | 一种杜仲胶与马来酸酐的熔融接枝方法 |
| TW202330677A (zh) | 2021-12-10 | 2023-08-01 | 義大利商佛沙里斯股份有限公司 | 橡膠強化的乙烯芳香族(共)聚合物及其製備方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6089452A (ja) * | 1983-07-11 | 1985-05-20 | コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン | 遊離基重合開始用化合物 |
| DE3486145T2 (de) * | 1983-07-11 | 1993-09-23 | Commw Scient Ind Res Org | Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere. |
| US5322912A (en) * | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
| FR2730240A1 (fr) * | 1995-02-07 | 1996-08-09 | Atochem Elf Sa | Stabilisation d'un polymere par un radical libre stable |
| WO1997036944A1 (en) * | 1996-03-29 | 1997-10-09 | The Dow Chemical Company | In situ block copolymer formation during polymerization of a vinyl aromatic monomer |
| US5723511A (en) | 1996-06-17 | 1998-03-03 | Xerox Corporation | Processes for preparing telechelic, branched and star thermoplastic resin polymers |
| US5910549A (en) * | 1996-08-22 | 1999-06-08 | Carnegie-Mellon University | Method for preparation of alkoxyamines from nitroxyl radicals |
| FR2754535A1 (fr) | 1996-10-16 | 1998-04-17 | Atochem Elf Sa | Polymeres greffes a viscosite controlee |
| US6281311B1 (en) * | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| FR2768739B1 (fr) * | 1997-09-19 | 2004-08-06 | Atochem Elf Sa | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
| DE19752394A1 (de) | 1997-11-19 | 1999-05-20 | Basf Ag | Verfahren zur Herstellung von Pfropfpolymerisaten |
| AU760128B2 (en) * | 1998-09-03 | 2003-05-08 | Ciba Specialty Chemicals Holding Inc. | Grafting of ethylenically unsaturated monomers onto polymers |
-
1999
- 1999-08-23 WO PCT/EP1999/006171 patent/WO2000014134A1/en not_active Ceased
- 1999-08-23 CN CNB998104655A patent/CN1298755C/zh not_active Expired - Fee Related
- 1999-08-23 KR KR1020017002032A patent/KR100575170B1/ko not_active Expired - Fee Related
- 1999-08-23 CA CA002341372A patent/CA2341372A1/en not_active Abandoned
- 1999-08-23 DE DE69941028T patent/DE69941028D1/de not_active Expired - Lifetime
- 1999-08-23 ES ES99944478T patent/ES2325697T3/es not_active Expired - Lifetime
- 1999-08-23 EP EP99944478A patent/EP1115765B1/en not_active Expired - Lifetime
- 1999-08-23 AU AU57387/99A patent/AU759408B2/en not_active Ceased
- 1999-08-23 AT AT99944478T patent/ATE434635T1/de not_active IP Right Cessation
- 1999-08-23 BR BR9913419-5A patent/BR9913419A/pt not_active Application Discontinuation
- 1999-08-23 US US09/786,186 patent/US6525151B1/en not_active Expired - Fee Related
- 1999-08-23 JP JP2000568889A patent/JP4516212B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20010072721A (ko) | 2001-07-31 |
| CN1315971A (zh) | 2001-10-03 |
| EP1115765A1 (en) | 2001-07-18 |
| AU759408B2 (en) | 2003-04-17 |
| BR9913419A (pt) | 2001-05-22 |
| DE69941028D1 (de) | 2009-08-06 |
| AU5738799A (en) | 2000-03-27 |
| WO2000014134A1 (en) | 2000-03-16 |
| JP2002524589A (ja) | 2002-08-06 |
| JP4516212B2 (ja) | 2010-08-04 |
| KR100575170B1 (ko) | 2006-04-28 |
| CN1298755C (zh) | 2007-02-07 |
| ES2325697T3 (es) | 2009-09-14 |
| CA2341372A1 (en) | 2000-03-16 |
| EP1115765B1 (en) | 2009-06-24 |
| US6525151B1 (en) | 2003-02-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |