AU636603B2 - A fire-resistant prefabricated steel beam - Google Patents

A fire-resistant prefabricated steel beam Download PDF

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Publication number
AU636603B2
AU636603B2 AU53599/90A AU5359990A AU636603B2 AU 636603 B2 AU636603 B2 AU 636603B2 AU 53599/90 A AU53599/90 A AU 53599/90A AU 5359990 A AU5359990 A AU 5359990A AU 636603 B2 AU636603 B2 AU 636603B2
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AU
Australia
Prior art keywords
web
web portions
portions
concrete
steel beam
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Expired
Application number
AU53599/90A
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AU5359990A (en
Inventor
Jorma Kyckling
Pertti Levo
Pekka Nykyri
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Deltatek Oy
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Deltatek Oy
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Filing date
Publication date
Priority claimed from FI891772A external-priority patent/FI891772A/en
Application filed by Deltatek Oy filed Critical Deltatek Oy
Publication of AU5359990A publication Critical patent/AU5359990A/en
Application granted granted Critical
Publication of AU636603B2 publication Critical patent/AU636603B2/en
Anticipated expiration legal-status Critical
Expired legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C3/00Structural elongated elements designed for load-supporting
    • E04C3/02Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces
    • E04C3/29Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces built-up from parts of different material, i.e. composite structures
    • E04C3/293Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces built-up from parts of different material, i.e. composite structures the materials being steel and concrete
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C3/00Structural elongated elements designed for load-supporting
    • E04C3/02Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces
    • E04C3/04Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces of metal
    • E04C3/06Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces of metal with substantially solid, i.e. unapertured, web
    • E04C3/065Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces of metal with substantially solid, i.e. unapertured, web with special adaptations for the passage of cables or conduits through the web
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B1/94Protection against other undesired influences or dangers against fire
    • E04B1/941Building elements specially adapted therefor
    • E04B1/943Building elements specially adapted therefor elongated
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B5/00Floors; Floor construction with regard to insulation; Connections specially adapted therefor
    • E04B5/16Load-carrying floor structures wholly or partly cast or similarly formed in situ
    • E04B5/17Floor structures partly formed in situ
    • E04B5/23Floor structures partly formed in situ with stiffening ribs or other beam-like formations wholly or partly prefabricated
    • E04B5/29Floor structures partly formed in situ with stiffening ribs or other beam-like formations wholly or partly prefabricated the prefabricated parts of the beams consisting wholly of metal

Abstract

The invention relates to a fire-resistant prefabricated steel beam arranged to act together with concrete as a load-bearing jointing construction for various slabs. The beam comprises two web portions and horizontally projecting flange portions extending beyond the web portions. To achieve a simple beam easy to install at least each web portion (2) with its horizontally projecting flange portion (1) is formed by an integral material strip so that the web portion (2) and the projecting flange portion adjoining it form a jointless entity and so that the web portion (2) is in a slanting position with respect to the flange portion. The web portions (2) are arranged side by side so as to slant towards each other and interconnected at edges closer to each other by means of a horizontal upper part (3). The edges of the web portions (2) farther apart from each other are interconnected by means of a plate (4) welded to the web portions. Openings (14) are formed close to the upper edges of the web portions (2) and/or in the horizontal upper part (3) to fill the space defined between the upper part (3) of the web portions (2) and the plate (4) with concrete in a manner known per se.

Description

I LL- ~I OPI DATE 05/11/90 APPLN. ID 53599 AOJP DATE 06/12/90 PCT NUMBER PCT/FI90/00091
PCT
INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (51) International Patent Classification 5 (11) International Publication Number: WO 90/12173 E04C 3/293, E04B 5/29 Al (43) International Publication Date: 18 October 1990 (18.10.90) (21) International Application Number: PCT FI90 00091 (22) International Filing Date: 4 April 1990 (04.04.90) Priority data: 891772 13 April 1989(13.04.89) FI 900985 27 February 1990 (27.02.90) FI ro D7 O 7 *0 o' 1 I/ (71) Applicant tfo- all designated States except 'S :-PEI+K *IA- K'ENNC Y1 [FI/FI]; P.O. Box 4, Vipusenkatu 10, SF- 15211 Lahti (FI).
(72) Inventors; and Inventors/Applicants (for US on/) KYCKLING, Jorma [FI Einonkuja 7, SF-1500 Lahti LEVO, Pertti [FI FI]; PetTijikatu 13, SF-15950 Lahti NYKYRI, Pekka Puustellinpolku 16 C 12, SF-00410 Helsinki (FI).
(74) Agent: OY KOLSTER AB; Iso Roobertinkatu 23, P.O.Box 148, SF-00121 Helsinki (FI).
(81) Designated States: AT (European patent), AL, BE (European patent), CA, CH (European patent), DE (European patent), DK (European patent), ES (European patent), FR (European patent). GB (European patent), IT (European patent), KR, LU (European patent). NL (European patent), NO, SE (European patent), US.
Published With international search report.
636603 S(54)Title: A FIRE-RESISTANT PREFABRICATED STFEL BEAM 6 8 3 9 7 18"" /rr (57) Abstract The invention relates to a fire-resistant prefabricated steel beam arranged to act together with concrete as a load-bearing jointing construction for various slabs. The beam comprises two web portions and horizontally projecting flange portions extending teyond the web portions. To achieve a simple beam easy to install at least each web portion with its horizontally projecting flange portion is formed by an integral material strip so that the web pot ,on and the projecting flange portion adjoining it form a jointless entity and so that the web portion is in a slanting positi n with respect to the flange portion. The web po'' ,ns are arranged side by side so as to slant towards each other and interconnected at edges closer to each other by means of a horizontal upper part The edges of the web portions farther apart from each other are interconnecte, by means of a plate (4) welded to the web portions. Openings (14) are formed close to the upper edges of the web portions and/or in the horizontal upper part to fill the space defined between the upper [,art of the web portions and the plate with concrete in a man.
ner known per se.
See back of page I I II II Y- -I I WO 90/12173 PCT/F190/00091 1 A fire-resistant prefabricated steel beam The invention relates to a fire-resistant prefabricated steel beam arranged to act together with concrete as a load-bearing jointing structure for various slabs and comprising two web portions and horizontally projecting flange portions extending beyond the web portions.
The frame of a prefabricated building is often formed by floor and ceiling structures carried by columns and beams. As the beams act as horizontal load-bearing structures, they have to be sufficiently rigid, that is, about 500 to 800 mm high when made of steel concrete. For heat, water, ventilation and electricity installations, the beams have to be perforated or the height of the floor structure has to be increased correspondingly. In certain cases the high beam structure has been replaced with a lowered beam structure, whereby the web of the beam remains within the floor structure. The height of the lowered beam has been minimized by prestressing, for instance. Technically, a jaw beam is more difficult to manufacture than a normal beam, and the minimum thickness of the lowered portion will nevertheless be 100 to 150 mm.
Beams are also often manufactured of steel.
Steel beams are easier to manufacture than prefabricated concrete beams in addition to which they ,are light to transport and install. Moreover, steel beams are easier to modify at the working site. As steel beams do not require grouting and are light to displace, they can be installed more rapidly than concrete beams. By adjusting the building to the frame construction timetable, the total building time can be decreased. In case of fire the strength of _I~I~F$LI WO 90/12173 PCT/F190/00091 2 steel deteriorates with increasing temperature, wherefore a steel beam has to be protected from fire.
The fire protection is preferably made by embedding the steel profile in a concrete floor structure, whereby the lower flange only has to be protected.
The protection is made either by covering the lower flange with a fire-resistant plate, insulation, paint or spray. For reasons of appearance, the piping and the fire protection are often covered with a socalled suspended ceiling.
This way of fire protection has led to the use of low hat profiles approximately of the same height as the floor unit. In the hat profile the lower flange of a rectangular basic beam is broader than the rest of the beam, thus forming projections for the floor units. Since the structure is low, the steel cannot be utilized optimally with regard to the rigidity of the structure. Despite the extra steel kilos, the hat beam (THQ beam) has been used rather widely in business buildings, for instance, so as to utilize the building volume as efficiently as possible by means of the low floor structure. Considerable savings have also been obtained by means of the low floor structure in special cases where it would otherwise have been necessary to increase the depth of foundation and support foundations of adjacent buildings on urban building sites.
The use of steel beams has been restricted mainly by the span length. With long span "angths the beam structure is very heavy and it has been necessary to camber the beams to eliminate deflections.
With ever increasing construction costs, buildings are today built so that they can be modified later on for other uses. Such versatility is obtained by long floor units and sparse supporting structures by dis- ~i:^III~Ur~CIP~LJP4 n~iXI ICrCXI~ WO 90/12173 PCr/F190/00091 3 placing light partition walls. In view of the manufacturing technique, long beams are difficult to handle, appropriate cambering has to be provided according to the span length despite the thermal stresses caused by welding, and the welding time increases with increasing plate thickness.
To eliminate the above drawbacks, it has more recently been suggested to use a combined structure of a steel beam and concrete. An example of such solutions would be the solution of FI Patent Application 882186. A steel beam of such a combined structure is lighter and can be used with longer span lengths than previously. The steel beam of FI Patent Application 882186 requires less welding as the beam is formed by profile parts preformed by hot rolling. However, the solution of FI Patent Application 882186 is complicated to manufacture because the inserts joining the different materials increase the amcunt of required welding and the great number of small pieces complicates the manufacture of the beam.
The object of the invention is to provide a steel beam to be used with concrete, which avoids the drawbacks of prior art. This is achieved by means of a beam of the invention, which is characterized in that at least each web portion with its horizontally projecting flange portion is formed byv an integral material strip so that the web portion and the projecting flange portion adjoining it form a jointless entity and so that the web portion is in a slanting position with respect to the flange portion, the web portions being arranged side by side so as to slant towards each other and interconnected at edges closer to each other by means of a horizontal upper part, and at edges farther apart from each other by means of a plate welded to the web portions, and openings era s~ l~ ~l~lprs~rssslrn~lg~aa~R~-~PL~~~- I~ WO 90/12173 PCT/FI90/0009' 4 being formed close to the upper edges of the web portions and/or in the horizontal upper part to fill the space defined between the upper part of the web portions and the plate with concrete in a manner known per se. As to the advantages offered by the invention, it is to be mentioned generally that in addition to all the above-mentioned good properties of a steel beam, i.e. easy adaptability to the frame system of the working site, low and light structure, rapid installation, and simple installation of heat, water, ventilation and electricity, the invention offers other considerable advantages.
The beam of the invention is so designed that its steel parts carry the loads of the slab units during installation. The casing formed by the steel beam and the gap defined between the slabs and the steel profile are filled up in connection with the pouring of concrete into the joints of the slabs. In a finished structure, the beam of the invention carries the loads exerted on it due to the adhesion between concrete and steel. The beam is also suited for use together with a jointing slab to be cast on site. The slab and the beam can thus be concreted in one step. The beam of the invention can be fabricated on an automated line, optimizing the required welding in accordance with the required rigidity. The web portions can be simply perforated to improve adhesion. Projections possibly remainLng on the edges of the holes or openings in connection with the perforation improve adhesion between the concrete and the steel. The openings are positioned, for instance, in the upper portion of the slanting web portions, so the grout passes easily inside the beam. The slanting web portions of the beam also enable the slab units to be placed quite close to the bends of the project- 7~~ WO 90/12173 PCT/FI90/00091 ing flange portions without hampering the grc-ting.
For this reason, the jaw is strained to a lesser extent than in solutions in which a separate casting space has to be left between the slab unit and the vertical web portion of the beam. The shape advantageous in case of fire and the pouring of concrete into the joints of the floor units wedge the slabs in place, leaving the projecting flanges solely for the installation of the units. The draw flange of the beam, positioned within the profile can be protected from fire in advance in connection with the manufacture of the beam unit without increasing the height of the floor structure. The projecting flanges prorect the fire protection layer during transport and installation. The fire protection layer may also be protected from mechanical wear and damages by means of a thin plate attached to the projecting flanges.
In the following the invention will be described by means of preferred embodiments shown in the attached drawing, in which Figure 1 ij a cross-sectional view of a beam of the invention; Figure 2 is a side view of the beam of the invention; Figure 3 illustrates the attachment of the beam of the invention to a vertical structure; Figure 4 is a side view of another embodiment of the attachment of the beam of the invention to a vertical structure; Figure 5 is a cross-sectional view of another embodiment of the beam of the invention; Figure 6 is a block diagram of an automated production line of the beam of the invention; and Figure 7 is a cross-sectional view of still 4 la~e~Y--rrrrs~s~sPL C~B~T-eC~~Ya~er WO 90/12173 PCT/F190/00091 6 another embodiment of the beam of the invention.
Figure 1 is a cross-sectional view of the beam of the invention in a situation where slabs rest on the beam and concrete has been poured inside the beam and into the gaps between the beam and the slabs. In the beam of Figure 1, each web portion 2 with an adjoining horizontally projecting flange portion 1 is made of an integral material strip. The web portions 2 are in a slanted position with respect to the projecting flanges 1. The web portion 2 and the projecting flange portion 1 adjoining it may be formed, by bending from a suitable strip of steel, The two web portions 2 with the projecting flanges 1 are positioned side by side so that the web portions slant towards each other and are interconnected at the edges closer to each other by means of a horizontal upper part 3. The horizontal upper part 3 may be formed by a separate material strip, such as a steel strip, which is welded to the _:pper ecges of the web portions.
In the embodiment of Figure 1, the two entities formed by the web portion 2 and the projecting flange 1 are completely jointless.
A horizontal steel plate 4 is weled between the edges of the web portions 2 farther apart from each other in such a manner that the plate acts both as a lower mould wall for the concrete 8 to be poured inside the basic profile and as a lower flange bearing the loads of the beam. In the example of the figure, the plate 4 is positioned higher than the level of the lower surfaces of the projecting flanges 1.
This arrangement enables the beam to be protected from fire without increasin .ts structural thickness.
Shoulders 12 may be attached to the web por- I~lhC D ilr~urmlsiaP~_ iUil_21Xi5~iiP~Ell?-~_rB~PIZZ~r~ 'i- WO 90/12173 PCT/FI90/00091 7 tions 2 slanting towards each other. The plate 4 forming the lower flange rests on the shoulders during welding.
To fill the beam with concrete, the slanting web portions are provided with holes or openings 14.
To ensure adhesion between the steel and the concrete, the edges of the openings 14 are provided with prodlike or platelike projections 5 at the fabrication stage, for instance.
Suspension rods 6 made of steel pass from the upper edge of the beam to the lower edge of the slabs to be supported. The suspension rods increase the ability of the beams to support the slabs together with a wedgelike concrete part 7 formed outside the beam when the beam is being concreted. In addition to the suspension rods 6 it is also possible to use gripping hooks 18 which efficiently anchor the wedgelike concrete part 7 in position. To increase the rigidity of the beam during installation, the steel area of the upper surface can be increased by means of a steel plate 9 or concrete steels welded under or above the upper part of the basic profile. The use of concrete steels improves the adhesive properties.
At the installation stage the beam is supported in the middle on structures beneath it before the slabs are placed in position. The middle support is removed after the grouting has gained sufficient strength. The use of support during grouting ensures efficient adhesion, which decreases deflection during and after construction so that the need of cambering is reduced. The support decreases substantially the need of steel on the compression side caused by stresses occurring during installation.
Figure 2 shows the beam of Figure 1 from the side. The openings in the web portions 2 of the beam I- llrrc- P q~ WO 90/12173 PCT/FI90/00091 8 are so positioned that no cast cavities are formed under the horizontal upper part 3 of the beam in connection with concreting. The openings 14 are positioned in the web portions close to the upper edges.
The openings 14 may also be used for laying reinforcements for slab fields and pipings for heat, water, ventilation and electricity installations.
Figure 3 shows the attachment of the beam of Figures 1 and 2 to a vertical supporting structure or column. The end of the beam is so shaped that a beam bracket 11 can be wholly fitted within the beam. The horizontal upper part of the beam forming the upper flange rests on the bracket, and the beam is tightened to the bracket by means of bolts 13 from the side of the beam against the side of the bracket.
The tightening can also be carried out by means of installing wedges. This ensures that the beam has sufficient torsional rigidity during installation.
Support torque is produced in the jointing beam by providing the bracket with a concrete reinforcment extending through it before the grouting of the joint. The support torque decreases the deformations of the beam and increases the load carrying c pacity.
An alternative way of producing support torque is shown in Figure 4. Draw-bars 16 are arranged to go through the column. They are fixed to the end of tha beam by means of pinching nuts 17. The nuts are tightened through the opening 14 of the web of the beam.
Figure 5 shows another embodiment of the beam of the invention. In this embodiment, the grouting of the beam has been carried out at the fabrication stage. The bending capacity of the beam can be increased by a prestressing technique conventionally applied to concrete beams. The degree of prestressing WO 90/12173 PCT/F190/00091I 9 can be higher than convent ionally as the steel profile around the concrete efficiently limits the cleaving of concrete, functioning as a kind of web reinforcement. in the embodiment of Figure 5, the horizontal upper part 3 of the beam can be provided with openings or holes 20 through which concrete 21 is poured into the inner space of the beam. The edges of the openings or holes 20 can be provided with projections 22 similar to the projections 5 of the openings 14 described above. The embodiment of Figure is otherwise structurally similar to the embodiment of Figure 1.
In the embodiment of Figure 5, no additional steels have to be prcvided on the upper surface of the beam because the beam itself forms a jointing structure at the installation stage. When the beam is bent, the plate 4 receives the tensile stress while the upper portion of the concrete filling of the beam receives the compression stress.
Due to the shape of the beam of the invention it can be produced efficiently on an automated production line. Figure 6 is a block diagram of the beam production line. The desired shape of the beam is achieved, by bending thin steel plate. Holes are made by any suitable means in the web portions, for instance. The projections improving the adhesion are also formed at the perforation stage. The parts a.re sawed into determined dimensions and the beam is cambered according to its span length if desired. The upper part, the possible additional steel of the upper part, and the plate forming the lower flange, which are flame-cut into dimensions, are cambered so as to correspond to the profile in shape. The welding of the additional steels can be carried out easily by means of an automatic welder by submerged arc welding WO 90/12173 PCT/FI90/00091 through welding grooves formed in the corners of the steel plates. Beam head details are welded by robot welding. Finally, the beam is coated and protected from fire if required.
Figure 7 shows still another embodiment of the invention. The embodiment of Figure 7 differs from that of Figures 1 and 2 in that projecting flange portions 31, web portions 32 and an upper part 33 are formed by an integral basic profile in Figure 7. The basic profile may be formed by a cold-moulded profile, for instance. In this embodiment, the projecting flange portions 31, the web portions 32 and the upper part 33 form an integral entity without any joints. The plate forming the lower flange is indicated with the reference numeral 34, the holes with the reference numeral 40, the projections with the reference numeral 42 and the shoulders with the reference numeral 32. Concrete is indicated with the reference numeral 41.
The embodiments described above are not intended to restrict the invention, but the invention czn be modified as desired within the scope of the claims. Accordingly, it is obvious that the beam of the invention or its details need not be exactly similar to those shown in the figures but other alternatives are possible as well.

Claims (8)

1. A fire-resistant prefabricated steel beam arranged to act together with concrete as a load- bearing jointing structure for various slabs and com- prising two web portions and horizontally projecting flange portions extending beyond the web portions, c h a r a c t e r i z ed in that at least each web portion 32) with its horizontally projecting flange portion 31) is formed by an integral ma- terial strip so that the web portion and the projecting flange portion adjoining it form a joint- less :ntity and so that the web portion 32) is in a slanting position with respect to the flange por- tion, the web portions being arranged side by side so as to slant towards each other and inter- connected at edges closer to each other by means of a horizontal upper part 33), and at ndges farther apart from each other by means of a plate 34) welded to the web portions,, and openings (14, 20, being formed close to the upper edges of the web por- tions 32) and/or in the horizontal upper part (3, 33) t; fi.l the space def-ied between the upper part 33) of the web port.ons 32) and the plata (4, 34) with concrete irn a manner known per se.
2. A steel beam according to claim 1, c h a r a c t e r i z e d in that the upper part inter- connecting the web portions at the edges closer to each other is formed by a separate material strip.
3. A steel beam according to claim 1, c h a r a c t e r i z e d in that the web portions (32), the projecting flange portions (31) and t!e horizon- tal upper part (33) are formed by an integral basic profile.
4. A steel beam eccording to claim 1, 2 or 3, i~ 12 characterised in that projections 22, 42) protruding from the plane of the web portion 32) or the upper part 33) are formed in the edges of the openings (14, to ensure adhesion between the concrete and steel.
5. A steel beam according to any one of the preceding claims, characterised in that the plate 34) connecting the lower edges of the web portions 32) is positioned above the plane of the lower surfaces of the projecting flange portions 31).
6. A steel beam according to any one of the preceding claims, characterised in that at least one additional steel plate and/or concrete steel is attached to the horizontal upper part 33).
7. A steel beam according to any one of the preceding claims wherein a layer of fire insulating material is located beneath the plate connecting the lower edges of the web portions.
8. A steel beam substantially as hereinbefore described with reference tn the accompanying drawings. DATED February 4, 1993 CARTER SMITH BEADLE Fellows Institute of Patent Attorneys of Australia Patent Attorneys for the Applicant: DELTATEK OY gn\02\9 re 93 2 4 Ca' gn\O2\89 7orea 93 2 4
AU53599/90A 1989-04-13 1990-04-04 A fire-resistant prefabricated steel beam Expired AU636603B2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FI891772A FI891772A (en) 1989-04-13 1989-04-13 BRANDSAEKER FOERTILLVERKAD STAOLBALK.
FI891772 1989-04-13
FI900985A FI85745C (en) 1989-04-13 1990-02-27 Fireproof prefabricated steel beam
FI900985 1990-02-27

Publications (2)

Publication Number Publication Date
AU5359990A AU5359990A (en) 1990-11-05
AU636603B2 true AU636603B2 (en) 1993-05-06

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AU53599/90A Expired AU636603B2 (en) 1989-04-13 1990-04-04 A fire-resistant prefabricated steel beam

Country Status (9)

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EP (1) EP0467912B1 (en)
KR (1) KR0171608B1 (en)
AT (1) ATE107990T1 (en)
AU (1) AU636603B2 (en)
CA (1) CA2051393C (en)
DE (1) DE69010326T2 (en)
FI (1) FI85745C (en)
MY (1) MY108507A (en)
WO (1) WO1990012173A1 (en)

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SE543184C2 (en) * 2019-02-14 2020-10-20 Vaestsvenska Staalkonstruktioner Ab Fire-resistant steel joist beam with vertical webs, horizontal flanges and a heat-insulating material in a space between the flanges
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CA2051393A1 (en) 1990-10-14
FI900985A0 (en) 1990-02-27
FI85745C (en) 1993-02-23
ATE107990T1 (en) 1994-07-15
EP0467912B1 (en) 1994-06-29
DE69010326T2 (en) 1994-10-20
KR0171608B1 (en) 1999-02-18
KR920701595A (en) 1992-08-12
CA2051393C (en) 1995-09-05
FI85745B (en) 1992-02-14
MY108507A (en) 1996-10-31
WO1990012173A1 (en) 1990-10-18
EP0467912A1 (en) 1992-01-29
DE69010326D1 (en) 1994-08-04
AU5359990A (en) 1990-11-05

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