AU3196393A - Reactivation of hydroformylation catalysts - Google Patents

Reactivation of hydroformylation catalysts

Info

Publication number
AU3196393A
AU3196393A AU31963/93A AU3196393A AU3196393A AU 3196393 A AU3196393 A AU 3196393A AU 31963/93 A AU31963/93 A AU 31963/93A AU 3196393 A AU3196393 A AU 3196393A AU 3196393 A AU3196393 A AU 3196393A
Authority
AU
Australia
Prior art keywords
reactivation
hydroformylation catalysts
treating
improving
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU31963/93A
Other languages
English (en)
Inventor
James Edward Babin
David Robert Bryant
Arnold Myron Harrison
David James Miller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of AU3196393A publication Critical patent/AU3196393A/en
Abandoned legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B01J38/62—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S95/00—Gas separation: processes
    • Y10S95/90—Solid sorbent
    • Y10S95/902—Molecular sieve

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)
AU31963/93A 1992-01-24 1993-01-22 Reactivation of hydroformylation catalysts Abandoned AU3196393A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US825083 1992-01-24
US07/825,083 US5237106A (en) 1992-01-24 1992-01-24 Reactivation of hydroformylation catalysts

Publications (1)

Publication Number Publication Date
AU3196393A true AU3196393A (en) 1993-07-29

Family

ID=25243072

Family Applications (1)

Application Number Title Priority Date Filing Date
AU31963/93A Abandoned AU3196393A (en) 1992-01-24 1993-01-22 Reactivation of hydroformylation catalysts

Country Status (22)

Country Link
US (1) US5237106A (Direct)
EP (1) EP0552797B1 (Direct)
JP (1) JP2742860B2 (Direct)
KR (1) KR0131293B1 (Direct)
CN (1) CN1074632A (Direct)
AT (1) ATE136016T1 (Direct)
AU (1) AU3196393A (Direct)
BR (1) BR9300259A (Direct)
CA (1) CA2087892A1 (Direct)
CZ (1) CZ6893A3 (Direct)
DE (1) DE69301930T2 (Direct)
ES (1) ES2085060T3 (Direct)
FI (1) FI930281L (Direct)
HU (1) HUT66778A (Direct)
MX (1) MX9300329A (Direct)
NO (1) NO930219L (Direct)
PL (1) PL170460B1 (Direct)
RO (1) RO111739B1 (Direct)
SA (1) SA93130348B1 (Direct)
SK (1) SK2693A3 (Direct)
TW (1) TW228480B (Direct)
ZA (1) ZA93501B (Direct)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10005084C1 (de) * 2000-02-04 2001-09-13 Celanese Chem Europe Gmbh Verfahren zur Wiedergewinnung von Rhodium aus Reaktionsprodukten der Oxosynthese
GB0113079D0 (en) * 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
US7638039B2 (en) * 2004-06-15 2009-12-29 Cormetech, Inc. In-situ catalyst replacement
CN100526279C (zh) * 2006-04-11 2009-08-12 中国科学院兰州化学物理研究所 连续制备正戊醛的工艺过程
US7962486B2 (en) * 2008-01-10 2011-06-14 International Business Machines Corporation Method and system for discovery and modification of data cluster and synonyms
CN102950027B (zh) * 2011-08-30 2015-03-25 中国石油化工股份有限公司 用于羰基化反应的失活铑配合物催化剂的再生方法
CN102950028B (zh) * 2011-08-31 2015-02-25 中国石油化工股份有限公司 用于羰基化反应的失活铑膦配合物催化剂的再生方法
CN103814006B (zh) * 2012-06-04 2015-08-12 Lg化学株式会社 在反应中具有改善的催化剂稳定性的氢甲酰化方法
CN103506166B (zh) * 2012-06-27 2015-08-19 中国石油化工股份有限公司 失活铑膦催化剂的活化方法
CN103506167B (zh) * 2012-06-27 2015-08-19 中国石油化工股份有限公司 一种失活铑膦催化剂的处理方法
CN103769225B (zh) * 2012-10-22 2016-03-02 中国石油化工股份有限公司 羰基化反应失活或部分失活铑膦催化剂的再生方法
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
CN104248994B (zh) * 2013-06-25 2018-03-20 中国石油化工股份有限公司 羰基化铑膦催化剂的活性恢复方法
CN104513143A (zh) 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 加氢甲酰化方法
EP3801898A1 (en) 2018-05-30 2021-04-14 Dow Technology Investments LLC Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it
MY201587A (en) 2018-05-30 2024-03-02 Dow Technology Investments Llc Methods of controlling hydroformylation processes
JP2021525165A (ja) 2018-05-30 2021-09-24 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスにおける触媒失活を遅らせるための方法、および／またはテトラホスフィン配位子の使用を遅らせるための方法
US20220143590A1 (en) 2019-06-27 2022-05-12 Dow Technology Investments Llc Process to prepare solution from hydroformylation process for precious metal recovery
TWI874467B (zh) * 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
WO2022066596A1 (en) * 2020-09-25 2022-03-31 Lyondell Chemical Technology, L.P. Co-feeding ethylene with allyl alcohol in hydroformylation to make 1,4-butanediol and n-propanol
US12595221B1 (en) 2021-03-31 2026-04-07 Dow Technology Investments Llc Hydroformylation processes
CN120282943A (zh) 2022-12-13 2025-07-08 陶氏技术投资有限责任公司 通过利用降解产物使多膦使用最小化的方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1219763A (en) * 1967-02-02 1971-01-20 Johnson Matthey & Company Improvements in catalytic hydrogenation or hydroformylation
US3555098A (en) * 1967-12-13 1971-01-12 Union Oil Co Hydroformylation
JPS5114482A (ja) * 1974-07-26 1976-02-04 Atsugi Kinzoku Kogyo Kk Kanguchiseizohoho
US4277627A (en) * 1977-01-25 1981-07-07 Union Carbide Corporation Hydroformylation process
EP0007768A3 (en) * 1978-07-27 1980-02-20 DAVY McKEE (LONDON) LIMITED Hydroformylation of alpha-olefinic compounds
US4297239A (en) * 1979-07-16 1981-10-27 Union Carbide Corporation Hydroformylation catalyst reactivation
JPS5633040A (en) * 1979-08-27 1981-04-03 Mitsubishi Chem Ind Ltd Activation of rhodium complex catalyst
US4292196A (en) * 1979-12-10 1981-09-29 Uop Inc. Catalyst recovery
US4374278A (en) * 1980-02-28 1983-02-15 Union Carbide Corporation Hydroformylation catalyst reactivation
US4605780A (en) * 1980-09-24 1986-08-12 Union Carbide Corporation Reactivation of rhodium complex hydroformylation catalysts
JPS5923858B2 (ja) * 1981-01-22 1984-06-05 三菱化学株式会社 ロジウム錯体の取得方法
DE3534314A1 (de) * 1985-09-26 1987-04-02 Ruhrchemie Ag Verfahren zur herstellung von aldehyden
US4845306A (en) * 1987-04-24 1989-07-04 Eastman Kodak Company Catalyst material recovery or concentration process
US4929767A (en) * 1988-08-12 1990-05-29 Union Carbide Chemicals And Plastics Company Inc. Treatment of rhodium catalysts
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
US4950629A (en) * 1988-12-27 1990-08-21 Eli Lilly And Company Process for catalyst recovery
US5183943A (en) * 1991-03-18 1993-02-02 Union Carbide Chemicals & Plastics Technology Corporation Reactivation of hydroformylation catalysts

Also Published As

Publication number Publication date
ATE136016T1 (de) 1996-04-15
CN1074632A (zh) 1993-07-28
ZA93501B (en) 1993-08-25
EP0552797B1 (en) 1996-03-27
MX9300329A (es) 1994-06-30
CA2087892A1 (en) 1993-07-25
JP2742860B2 (ja) 1998-04-22
FI930281A0 (fi) 1993-01-22
JPH05261296A (ja) 1993-10-12
CZ6893A3 (en) 1993-10-13
NO930219L (no) 1993-07-26
BR9300259A (pt) 1993-08-24
KR930016146A (ko) 1993-08-26
FI930281A7 (fi) 1993-07-25
RO111739B1 (ro) 1997-01-30
PL170460B1 (pl) 1996-12-31
ES2085060T3 (es) 1996-05-16
KR0131293B1 (ko) 1998-04-14
DE69301930T2 (de) 1996-10-02
SK2693A3 (en) 1993-11-10
NO930219D0 (no) 1993-01-22
US5237106A (en) 1993-08-17
HU9300185D0 (en) 1993-04-28
EP0552797A1 (en) 1993-07-28
PL297519A1 (en) 1993-08-23
FI930281L (fi) 1993-07-25
HUT66778A (en) 1994-12-28
TW228480B (Direct) 1994-08-21
SA93130348B1 (ar) 2005-07-02
DE69301930D1 (de) 1996-05-02

Similar Documents

Publication Publication Date Title
ZA93501B (en) Reactivation of hydroformylation catalysts.
KR970702751A (ko) 고활성 촉매(high activity catalysts)
PL339801A1 (en) Method of sulphuring the hydrotreating catalysts
ATE195922T1 (de) Verfahren zur katalytischen teiloxydation von kohlenwasserstoff
TW429162B (en) Polymeric carbonylation catalyst system and carbonylation process using the same
ES2036002T3 (es) Reactivacion de catalizadores de hidroformilacion.
GR3019248T3 (en) Deactivator reagent for olefin polymerization catalysts
MX9201189A (es) Reactivacion de catalizadores de hidroformilacion
GB8807284D0 (en) Chemical process
GR3022739T3 (en) Process for the catalytic dehydrogenation of hydrocarbons
ZA933466B (en) Catalyst supports, supported catalysts methods of making the same and methods of using the same
ZA946133B (en) Method of improving catalyst activity, improved catalysts and their use.
ZA927956B (en) Catalyst and process for the catalytic partial oxidation of hydrocarbons.
EP0557790A3 (en) Process for producing isobutylene by oxidative dehydrogenation of isobutane and catalyst therefor
EP0519084A4 (en) Process for producing simultaneously aromatic hydroxy and carbonyl compounds
CA2039265A1 (en) Nitrile-accelerated hydrocarboxylation
RU93004403A (ru) Способ повышения активности катализаторов гидроформилирования
EP0626201A4 (en) PROCESS FOR PRODUCING ACETIC ACID OR METHYL ACETATE AND CATALYST.
ATE122928T1 (de) Dimerisationsverfahren und katalysatoren dafür.
EP0631814A4 (en) HETEROPOLYNUCLEAR COMPLEX Ru-Sn AND METHOD USING THE SAME TO PRODUCE ACETIC ACID OR METHYL ACETATE.
CA2118414A1 (en) Catalyst supports, supported catalysts methods of making the same and methods of using the same
IE871611L (en) Hydrogenation catalysts
FR2696449B1 (fr) Procédé d'isomérisation de lactones en acides penténoïques par catalyse basique.
AU9175291A (en) Process for regenerating fluidized catalytic cracking catalyst
AU8221491A (en) Process for regenerating fluidized catalytic cracking catalyst