AU2009228938B2 - Biodegradable polyester, preparation process thereof and products comprising said polyester - Google Patents
Biodegradable polyester, preparation process thereof and products comprising said polyester Download PDFInfo
- Publication number
- AU2009228938B2 AU2009228938B2 AU2009228938A AU2009228938A AU2009228938B2 AU 2009228938 B2 AU2009228938 B2 AU 2009228938B2 AU 2009228938 A AU2009228938 A AU 2009228938A AU 2009228938 A AU2009228938 A AU 2009228938A AU 2009228938 B2 AU2009228938 B2 AU 2009228938B2
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- AU
- Australia
- Prior art keywords
- polyester
- biodegradable
- aliphatic
- aromatic
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000728 polyester Polymers 0.000 title claims abstract description 91
- 229920000229 biodegradable polyester Polymers 0.000 title claims abstract description 44
- 239000004622 biodegradable polyester Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title description 2
- 239000002243 precursor Substances 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 24
- 230000008569 process Effects 0.000 claims abstract description 23
- 238000001125 extrusion Methods 0.000 claims abstract description 18
- 150000002009 diols Chemical class 0.000 claims abstract description 12
- -1 aliphatic dicarboxylic acids Chemical class 0.000 claims description 47
- 239000000155 melt Substances 0.000 claims description 25
- 239000000123 paper Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 235000013305 food Nutrition 0.000 claims description 15
- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- 230000004888 barrier function Effects 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 150000001718 carbodiimides Chemical class 0.000 claims description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 8
- 150000002118 epoxides Chemical class 0.000 claims description 7
- 150000002978 peroxides Chemical class 0.000 claims description 7
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 7
- 239000004626 polylactic acid Substances 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 159000000032 aromatic acids Chemical class 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- 230000001133 acceleration Effects 0.000 claims description 3
- 239000011111 cardboard Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 235000015220 hamburgers Nutrition 0.000 claims description 3
- 235000015243 ice cream Nutrition 0.000 claims description 3
- 235000013618 yogurt Nutrition 0.000 claims description 3
- 150000001491 aromatic compounds Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 235000015895 biscuits Nutrition 0.000 claims description 2
- 235000014121 butter Nutrition 0.000 claims description 2
- 239000011888 foil Substances 0.000 claims description 2
- DNXDYHALMANNEJ-UHFFFAOYSA-N furan-2,3-dicarboxylic acid Chemical compound OC(=O)C=1C=COC=1C(O)=O DNXDYHALMANNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013310 margarine Nutrition 0.000 claims description 2
- 239000003264 margarine Substances 0.000 claims description 2
- 235000013372 meat Nutrition 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000011087 paperboard Substances 0.000 claims description 2
- 150000003022 phthalic acids Chemical class 0.000 claims 1
- 238000007765 extrusion coating Methods 0.000 abstract description 26
- 230000009466 transformation Effects 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 description 55
- 239000010410 layer Substances 0.000 description 26
- 239000000047 product Substances 0.000 description 25
- 239000010408 film Substances 0.000 description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 239000011101 paper laminate Substances 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 235000019698 starch Nutrition 0.000 description 6
- FCHGUOSEXNGSMK-UHFFFAOYSA-N 1-tert-butylperoxy-2,3-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC(OOC(C)(C)C)=C1C(C)C FCHGUOSEXNGSMK-UHFFFAOYSA-N 0.000 description 5
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 229920001684 low density polyethylene Polymers 0.000 description 5
- 239000004702 low-density polyethylene Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920001748 polybutylene Polymers 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 229920000331 Polyhydroxybutyrate Polymers 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000007872 degassing Methods 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 150000001261 hydroxy acids Chemical class 0.000 description 4
- FEKRFYZGYUTGRY-UHFFFAOYSA-N n'-ethylmethanediimine Chemical compound CCN=C=N FEKRFYZGYUTGRY-UHFFFAOYSA-N 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000005015 poly(hydroxybutyrate) Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N Valeric acid Natural products CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 3
- 229920003232 aliphatic polyester Polymers 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Chemical class 0.000 description 3
- 239000002184 metal Chemical class 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 238000007655 standard test method Methods 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 150000003673 urethanes Chemical class 0.000 description 3
- ARXKVVRQIIOZGF-UHFFFAOYSA-N 1,2,4-butanetriol Chemical compound OCCC(O)CO ARXKVVRQIIOZGF-UHFFFAOYSA-N 0.000 description 2
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Natural products OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-Lactic acid Natural products C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920000954 Polyglycolide Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229920002988 biodegradable polymer Polymers 0.000 description 2
- 239000004621 biodegradable polymer Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000006085 branching agent Substances 0.000 description 2
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- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 2
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- CHTHALBTIRVDBM-UHFFFAOYSA-N furan-2,5-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)O1 CHTHALBTIRVDBM-UHFFFAOYSA-N 0.000 description 2
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- SZHOJFHSIKHZHA-UHFFFAOYSA-N n-Tridecanoic acid Natural products CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
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- 239000000049 pigment Substances 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
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Landscapes
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- Wrappers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| ITMI2008A000507 | 2008-03-26 | ||
| IT000507A ITMI20080507A1 (it) | 2008-03-26 | 2008-03-26 | Poliestere biodegradabile, suo processo di preparazione e prodotti comprendenti detto poliestere. |
| PCT/EP2009/053586 WO2009118377A1 (en) | 2008-03-26 | 2009-03-26 | Biodegradable polyester, preparation process thereof and products comprising said polyester |
Publications (3)
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| AU2009228938A1 AU2009228938A1 (en) | 2009-10-01 |
| AU2009228938A2 AU2009228938A2 (en) | 2011-03-31 |
| AU2009228938B2 true AU2009228938B2 (en) | 2014-06-26 |
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| AU2009228938A Active AU2009228938B2 (en) | 2008-03-26 | 2009-03-26 | Biodegradable polyester, preparation process thereof and products comprising said polyester |
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| EP (1) | EP2268698B1 (enExample) |
| JP (1) | JP6244078B2 (enExample) |
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| IT1399032B1 (it) * | 2009-11-06 | 2013-04-05 | Novamont Spa | Poliestere biodegradabile alifatico-aromatico |
| IT1402747B1 (it) * | 2010-10-27 | 2013-09-18 | Novamont Spa | Poliestere biodegradabile e pellicole aderenti per l'imballaggio con esso realizzate |
| IT1403611B1 (it) * | 2010-12-22 | 2013-10-31 | Novamont Spa | Composizione di poliesteri |
| JP2012229395A (ja) * | 2011-04-11 | 2012-11-22 | Canon Inc | プラスチックフィルム |
| WO2012140238A1 (en) * | 2011-04-14 | 2012-10-18 | Universiteit Van Amsterdam | Laminate comprising carrier and coating layer |
| WO2012143323A1 (en) * | 2011-04-20 | 2012-10-26 | Basf Se | Cellulosic barrier packaging material |
| KR101116668B1 (ko) * | 2011-05-16 | 2012-03-07 | (주)케이티에스 | 지방족 폴리에스테르 코팅지 및 그 제조방법 |
| CA2848341C (en) | 2011-09-19 | 2020-01-14 | Novamont S.P.A. | Stable aqueous dispersions comprising complexed starch |
| EP2572875A1 (de) * | 2011-09-26 | 2013-03-27 | Tscheulin-Rothal GmbH | Biologisch abbaubare Verpackungsmaterialien |
| US20130095270A1 (en) | 2011-10-14 | 2013-04-18 | Eastman Chemical Company | Polyester compositions containing furandicarboxylic acid or an ester thereof, cyclobutanediol and cyclohexanedimethanol |
| FR2985260B1 (fr) | 2011-12-29 | 2014-06-27 | Natura Cosmeticos Sa | Procede pour la production de poly(2,5-furanedicarboxylate d'ethylene) a partir d'acide 2,5-furanedicarboxylique et son utilisation, compose polyester et melanges de celui-ci. |
| US8912349B2 (en) | 2012-06-22 | 2014-12-16 | Eastman Chemical Company | Method for producing purified dialkyl-furan-2,5-dicarboxylate separation and solid liquid separation |
| US8658810B2 (en) | 2012-06-22 | 2014-02-25 | Eastman Chemical Company | Method for producing purified dialkyl-furan-2,5-dicarboxylate vapor |
| US8859788B2 (en) | 2012-06-22 | 2014-10-14 | Eastman Chemical Company | Esterification of furan-2,5-dicarboxylic acid to a dialkyl-furan-2,5-dicarboxylate vapor with rectification |
| CN102786782B (zh) * | 2012-07-03 | 2014-03-12 | 广州碧嘉材料科技有限公司 | 一种生物降解材料及其制备方法和应用 |
| KR20140031011A (ko) | 2012-09-04 | 2014-03-12 | 삼성정밀화학 주식회사 | 생분해성 지방족 폴리에스테르의 연속 제조방법 |
| MX380350B (es) * | 2014-04-30 | 2025-03-12 | Stichting Wageningen Res | Poliesteres y copoliesteres termoplasticos de furanoato de poliisoidida y un uso de los mismos en envasado de llenado en caliente. |
| KR20160023973A (ko) * | 2014-08-21 | 2016-03-04 | 삼성정밀화학 주식회사 | 투명 생분해성 고분자 |
| HUP1400467A2 (en) * | 2014-10-03 | 2016-04-28 | Jozsef Sandor Borbely | Process for producing biodegradable packing material |
| ITUB20152688A1 (it) * | 2015-07-31 | 2017-01-31 | Novamont Spa | Composizione polimerica per la realizzazione di articoli stampati biodegradabili in compostaggio industriale. |
| JP6787326B2 (ja) | 2015-09-04 | 2020-11-18 | 三菱ケミカル株式会社 | ポリエステル樹脂及び該ポリエステル樹脂の製造方法並びにポリエステル樹脂組成物 |
| DE102016201498B4 (de) * | 2016-02-01 | 2017-08-17 | Norbert Kuhl | Sauerstoffdichter lebensmittelbehälter |
| CN107304285B (zh) * | 2016-04-21 | 2022-06-21 | 上海浦景化工技术股份有限公司 | 一种聚酯改性材料及其膜制品的制备方法 |
| AU2017348093B2 (en) * | 2016-10-26 | 2021-12-23 | Danimer Ipco, Llc | Renewable, biodegradable marking wax composition |
| CN107459783B (zh) | 2016-12-12 | 2018-07-27 | 金发科技股份有限公司 | 一种聚对苯二甲酸酯-共-癸二酸酯树脂组合物 |
| CN110914344B (zh) * | 2017-05-10 | 2022-05-31 | 巴斯夫欧洲公司 | 用于食品包装的可生物降解的薄膜 |
| PL3642268T3 (pl) * | 2017-06-19 | 2021-12-27 | Basf Se | Biodegradowalna trójwarstwowa folia |
| US20190023675A1 (en) | 2017-07-20 | 2019-01-24 | Eastman Chemical Company | Method for producing purified dialkyl-furan-2,5-dicarboxylate |
| JP7157069B2 (ja) | 2017-10-04 | 2022-10-19 | 日本製紙株式会社 | バリア素材 |
| US11260337B2 (en) * | 2018-03-29 | 2022-03-01 | Uop Llc | Process for the removal of carbon dioxide and heavy hydrocarbons |
| CN109467723A (zh) * | 2018-09-30 | 2019-03-15 | 江苏宏远新材料科技有限公司 | 一种水蒸气阻隔型抗菌环保聚酯薄膜的制备方法 |
| BR112021013825A2 (pt) * | 2019-01-21 | 2021-09-21 | Plantics B.V. | Recipiente biodegradável ou material de placa e método para a fabricação dos mesmos |
| JP7271964B2 (ja) * | 2019-01-23 | 2023-05-12 | 東ソー株式会社 | 樹脂組成物およびその樹脂組成物を用いた積層体 |
| KR101992393B1 (ko) * | 2019-04-03 | 2019-06-24 | (주)새한폴리머 | 생분해성 지방족 폴리에스테르의 연속 제조방법 |
| JP7668228B2 (ja) * | 2019-04-11 | 2025-04-24 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリブチレンテレフタレートの熱成形方法 |
| WO2021151892A1 (en) * | 2020-01-27 | 2021-08-05 | Dsm Ip Assets B.V. | Layered material |
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| CN114055877A (zh) * | 2020-07-29 | 2022-02-18 | 上海紫丹食品包装印刷有限公司 | 耐热、低水蒸气透过率且可生物降解的纸塑复合材料及其制备方法和应用 |
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| WO2003089490A2 (en) * | 2002-04-22 | 2003-10-30 | Novamont S.P.A. | Biodegradable polyesters obtained by reactive extrusion |
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| CA2718212C (en) | 2016-11-29 |
| CN104448281B (zh) | 2018-03-27 |
| BRPI0906336B1 (pt) | 2019-09-03 |
| EP2268698A1 (en) | 2011-01-05 |
| KR20110008054A (ko) | 2011-01-25 |
| AU2009228938A1 (en) | 2009-10-01 |
| BRPI0906336A2 (pt) | 2016-07-26 |
| CN104448281A (zh) | 2015-03-25 |
| JP6244078B2 (ja) | 2017-12-06 |
| JP2011518235A (ja) | 2011-06-23 |
| WO2009118377A1 (en) | 2009-10-01 |
| US8541109B2 (en) | 2013-09-24 |
| US20110020660A1 (en) | 2011-01-27 |
| AU2009228938A2 (en) | 2011-03-31 |
| ITMI20080507A1 (it) | 2009-09-27 |
| KR101600112B1 (ko) | 2016-03-04 |
| RU2010142992A (ru) | 2012-05-10 |
| CA2718212A1 (en) | 2009-10-01 |
| RU2499007C2 (ru) | 2013-11-20 |
| EP2268698B1 (en) | 2019-04-24 |
| CN101981081A (zh) | 2011-02-23 |
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