AU2008340129B2 - Oxygen-scavenging mixtures - Google Patents

Info

Publication number

AU2008340129B2

AU2008340129B2 AU2008340129A AU2008340129A AU2008340129B2 AU 2008340129 B2 AU2008340129 B2 AU 2008340129B2 AU 2008340129 A AU2008340129 A AU 2008340129A AU 2008340129 A AU2008340129 A AU 2008340129A AU 2008340129 B2 AU2008340129 B2 AU 2008340129B2

Authority

AU

Australia

Prior art keywords

oxygen

scavenging

tert

butyl

metal

Prior art date

2007-12-21

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Ceased

Links

• Espacenet
• Global Dossier
• Discuss

• 239000000203 mixture Substances 0.000 title claims abstract description 150
• 229910052751 metal Inorganic materials 0.000 claims abstract description 40
• 239000002184 metal Substances 0.000 claims abstract description 40
• 239000002105 nanoparticle Substances 0.000 claims abstract description 34
• 239000003792 electrolyte Substances 0.000 claims abstract description 26
• 239000002245 particle Substances 0.000 claims abstract description 19
• 239000012876 carrier material Substances 0.000 claims abstract description 7
• XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 84
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 72
• 239000001301 oxygen Substances 0.000 claims description 72
• 229910052760 oxygen Inorganic materials 0.000 claims description 72
• 238000004806 packaging method and process Methods 0.000 claims description 57
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 50
• 229920001577 copolymer Polymers 0.000 claims description 43
• 230000002000 scavenging effect Effects 0.000 claims description 28
• 229910052742 iron Inorganic materials 0.000 claims description 27
• 229940123973 Oxygen scavenger Drugs 0.000 claims description 26
• 239000011230 binding agent Substances 0.000 claims description 25
• 239000011780 sodium chloride Substances 0.000 claims description 25
• 235000019820 disodium diphosphate Nutrition 0.000 claims description 22
• GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 claims description 22
• 239000002952 polymeric resin Substances 0.000 claims description 17
• 229920003002 synthetic resin Polymers 0.000 claims description 16
• 229920005992 thermoplastic resin Polymers 0.000 claims description 15
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• 239000004952 Polyamide Substances 0.000 claims description 11
• 239000003963 antioxidant agent Substances 0.000 claims description 11
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• 235000013305 food Nutrition 0.000 claims description 10
• 229910052782 aluminium Inorganic materials 0.000 claims description 7
• 229920001519 homopolymer Polymers 0.000 claims description 7
• PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims description 6
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
• 239000004594 Masterbatch (MB) Substances 0.000 claims description 5
• 239000002253 acid Substances 0.000 claims description 5
• 239000000654 additive Substances 0.000 claims description 5
• 229910052749 magnesium Inorganic materials 0.000 claims description 5
• 239000012229 microporous material Substances 0.000 claims description 4
• AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 4
• 229910052725 zinc Inorganic materials 0.000 claims description 4
• MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 claims description 3
• 239000004254 Ammonium phosphate Substances 0.000 claims description 3
• 230000000996 additive effect Effects 0.000 claims description 3
• 150000001336 alkenes Chemical class 0.000 claims description 3
• 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
• 235000019289 ammonium phosphates Nutrition 0.000 claims description 3
• 229960004543 anhydrous citric acid Drugs 0.000 claims description 3
• 229910052802 copper Inorganic materials 0.000 claims description 3
• 239000010949 copper Substances 0.000 claims description 3
• MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
• CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 claims description 3
• 229910052748 manganese Inorganic materials 0.000 claims description 3
• HWPKGOGLCKPRLZ-UHFFFAOYSA-M monosodium citrate Chemical compound [Na+].OC(=O)CC(O)(C([O-])=O)CC(O)=O HWPKGOGLCKPRLZ-UHFFFAOYSA-M 0.000 claims description 3
• 235000001968 nicotinic acid Nutrition 0.000 claims description 3
• 239000011664 nicotinic acid Substances 0.000 claims description 3
• 229960003512 nicotinic acid Drugs 0.000 claims description 3
• GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims description 3
• GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
• 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
• 235000019983 sodium metaphosphate Nutrition 0.000 claims description 3
• UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 claims description 3
• 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
• 229910052718 tin Inorganic materials 0.000 claims description 3
• 239000011135 tin Substances 0.000 claims description 3
• 239000006096 absorbing agent Substances 0.000 claims description 2
• 239000001063 aluminium ammonium sulphate Substances 0.000 claims description 2
• 235000011124 aluminium ammonium sulphate Nutrition 0.000 claims description 2
• 239000001132 aluminium potassium sulphate Substances 0.000 claims description 2
• 235000011126 aluminium potassium sulphate Nutrition 0.000 claims description 2
• 239000001164 aluminium sulphate Substances 0.000 claims description 2
• 235000011128 aluminium sulphate Nutrition 0.000 claims description 2
• LCQXXBOSCBRNNT-UHFFFAOYSA-K ammonium aluminium sulfate Chemical compound [NH4+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LCQXXBOSCBRNNT-UHFFFAOYSA-K 0.000 claims description 2
• BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
• 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
• 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
• BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 claims description 2
• 239000004611 light stabiliser Substances 0.000 claims description 2
• LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical group C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 claims 1
• 239000001166 ammonium sulphate Substances 0.000 claims 1
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
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