AU2004203020B2 - Polymerization process for preparing an aqueous polymer dispersion - Google Patents
Polymerization process for preparing an aqueous polymer dispersion Download PDFInfo
- Publication number
- AU2004203020B2 AU2004203020B2 AU2004203020A AU2004203020A AU2004203020B2 AU 2004203020 B2 AU2004203020 B2 AU 2004203020B2 AU 2004203020 A AU2004203020 A AU 2004203020A AU 2004203020 A AU2004203020 A AU 2004203020A AU 2004203020 B2 AU2004203020 B2 AU 2004203020B2
- Authority
- AU
- Australia
- Prior art keywords
- polymer particles
- polymer
- aqueous
- mode
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 108
- 239000004815 dispersion polymer Substances 0.000 title claims description 85
- 229920000642 polymer Polymers 0.000 claims description 303
- 239000002245 particle Substances 0.000 claims description 277
- 239000000178 monomer Substances 0.000 claims description 173
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 85
- 238000000034 method Methods 0.000 claims description 59
- 239000000203 mixture Substances 0.000 claims description 43
- 239000012736 aqueous medium Substances 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 27
- 230000009477 glass transition Effects 0.000 claims description 26
- 239000004094 surface-active agent Substances 0.000 claims description 20
- 238000009826 distribution Methods 0.000 claims description 16
- 230000000379 polymerizing effect Effects 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 239000000872 buffer Substances 0.000 claims description 2
- 238000007792 addition Methods 0.000 description 67
- 239000008367 deionised water Substances 0.000 description 51
- 229910021641 deionized water Inorganic materials 0.000 description 51
- 230000002209 hydrophobic effect Effects 0.000 description 51
- -1 molecular weight Substances 0.000 description 50
- 239000000839 emulsion Substances 0.000 description 45
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 43
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- 239000004417 polycarbonate Substances 0.000 description 1
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- 229920006324 polyoxymethylene Polymers 0.000 description 1
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- 229920005591 polysilicon Polymers 0.000 description 1
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- 239000004814 polyurethane Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 1
- 229940043349 potassium metabisulfite Drugs 0.000 description 1
- 235000010263 potassium metabisulphite Nutrition 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- ARENMZZMCSLORU-UHFFFAOYSA-N propan-2-yl naphthalene-1-sulfonate Chemical class C1=CC=C2C(S(=O)(=O)OC(C)C)=CC=CC2=C1 ARENMZZMCSLORU-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- OGRPJZFGZFQRHZ-UHFFFAOYSA-M sodium;4-octoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].CCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O OGRPJZFGZFQRHZ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
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- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
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- 238000011105 stabilization Methods 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
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- 229940116411 terpineol Drugs 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
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- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 238000000825 ultraviolet detection Methods 0.000 description 1
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- YRIDFQASBDRMBJ-UHFFFAOYSA-N undec-10-enamide Chemical compound NC(=O)CCCCCCCCC=C YRIDFQASBDRMBJ-UHFFFAOYSA-N 0.000 description 1
- 229940075466 undecylenate Drugs 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical compound C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US48752303P | 2003-07-14 | 2003-07-14 | |
| US60/487,523 | 2003-07-14 |
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| AU2004203020A1 AU2004203020A1 (en) | 2005-02-03 |
| AU2004203020B2 true AU2004203020B2 (en) | 2009-08-20 |
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|---|---|---|---|
| AU2004203020A Ceased AU2004203020B2 (en) | 2003-07-14 | 2004-07-05 | Polymerization process for preparing an aqueous polymer dispersion |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7776975B2 (OSRAM) |
| EP (1) | EP1498430B1 (OSRAM) |
| JP (2) | JP2005036189A (OSRAM) |
| CN (1) | CN100340580C (OSRAM) |
| AU (1) | AU2004203020B2 (OSRAM) |
| BR (1) | BRPI0402631A (OSRAM) |
| DE (1) | DE602004008839T2 (OSRAM) |
| MX (1) | MXPA04006508A (OSRAM) |
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| US7598303B2 (en) * | 2005-02-17 | 2009-10-06 | Rohm And Haas Company | Process for making an aqueous dispersion |
| AU2006201172B2 (en) * | 2005-04-04 | 2010-11-25 | Rohm And Haas Company | Aqueous polymer dispersions |
| DE102005033516A1 (de) * | 2005-07-14 | 2007-01-18 | Basf Ag | Verfahren zur Herstellung von Emulsionspolymerisaten |
| US8482035B2 (en) * | 2005-07-29 | 2013-07-09 | International Rectifier Corporation | Enhancement mode III-nitride transistors with single gate Dielectric structure |
| JP2007091782A (ja) * | 2005-09-27 | 2007-04-12 | Asahi Kasei Chemicals Corp | 架橋性水系コーティング組成物 |
| US7642314B2 (en) * | 2005-12-30 | 2010-01-05 | Columbia Insurance Company | Emulsion polymers having multimodal molecular weight distributions |
| WO2008034856A2 (de) * | 2006-09-20 | 2008-03-27 | Akzo Nobel Chemicals International B.V. | Wässrige siliciumdioxid dispersionen für dicht- und klebstoffformulierungen |
| DE102006045384A1 (de) * | 2006-09-26 | 2008-04-03 | H.C. Starck Gmbh | Wässrige Siliciumdioxid Dispersionen für Klebstoffformulierungen |
| US8338861B2 (en) * | 2007-01-10 | 2012-12-25 | International Rectifier Corporation | III-nitride semiconductor device with stepped gate trench and process for its manufacture |
| AU2008200079B2 (en) * | 2007-01-16 | 2012-03-29 | Rohm And Haas Company | Fast-drying aqueous compositions with hollow particle binders and traffic paints made therewith |
| JP5327684B2 (ja) * | 2008-06-03 | 2013-10-30 | ダウ グローバル テクノロジーズ エルエルシー | 複合分散液、その製造方法、及びそれから製造された物品 |
| JP5518397B2 (ja) * | 2009-08-12 | 2014-06-11 | 富士フイルム株式会社 | 水性インク組成物、複合粒子の製造方法、インクセット、及び、画像形成方法 |
| NZ711526A (en) * | 2009-09-11 | 2017-04-28 | Nat Gypsum Properties Llc | Low dust joint compound and method of making the same |
| BR112012023990A2 (pt) * | 2010-03-23 | 2016-08-02 | Basf Se | revestimento de papel ou formulação aglutinante, papel, e, método para produzir um revestimento de papel ou uma formulação aglutinante |
| CN102933612B (zh) * | 2010-06-10 | 2014-10-01 | 三菱丽阳株式会社 | 丙烯酸系聚合物的制造方法、通过该制造方法而获得的丙烯酸系聚合物及使用了该丙烯酸系聚合物的增塑溶胶组合物 |
| US9102848B2 (en) | 2011-02-28 | 2015-08-11 | Basf Se | Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same |
| US10160891B2 (en) | 2012-02-08 | 2018-12-25 | Honeywell International Inc. | High performance water-based tackified acrylic pressure sensitive adhesives |
| US10167416B2 (en) | 2012-02-08 | 2019-01-01 | Honeywell International Inc. | High performance water-based adhesion compositions and applications |
| US8933148B2 (en) * | 2013-02-06 | 2015-01-13 | Xerox Corporation | Solventless radiation curable stretchable ink composition |
| CN106164100B (zh) * | 2014-04-02 | 2018-10-19 | 东洋油墨Sc控股株式会社 | 乳液型树脂组合物及其制造方法 |
| ES2889898T3 (es) * | 2014-04-15 | 2022-01-14 | Honeywell Int Inc | Composiciones y aplicaciones de adhesión a base de agua de alto rendimiento |
| EP3183383B1 (en) * | 2014-08-20 | 2019-03-13 | Dow Global Technologies LLC | Fast disintegrating nonwoven binder |
| US9421758B2 (en) * | 2014-09-30 | 2016-08-23 | Xerox Corporation | Compositions and use of compositions in printing processes |
| US11220788B2 (en) * | 2015-04-20 | 2022-01-11 | Kotkamills Group Oyj | Method and system for manufacturing a coated paperboard and a coated paperboard |
| US10363572B2 (en) * | 2015-05-06 | 2019-07-30 | Basf Coatings Gmbh | Method for producing a multicoat paint system on plastics substrates |
| US10427388B2 (en) * | 2015-09-24 | 2019-10-01 | Arakawa Chemical Industries, Ltd. | Emulsion composition and production method thereof, and laminate and production method thereof |
| GB201522691D0 (en) * | 2015-12-22 | 2016-02-03 | Lucite Internat Speciality Polymers And Resins Ltd | Additive manufacturing composition |
| RU2762109C2 (ru) * | 2016-11-08 | 2021-12-15 | Дау Глоубл Текнолоджиз Ллк | Контролируемое распределение размера частиц |
| US10526480B2 (en) * | 2016-11-15 | 2020-01-07 | Hercules Llc | Ultra-high solids emulsion and application |
| EP3372649B1 (en) | 2017-03-07 | 2019-09-25 | Organik Kimya Sanayi Ve Tic. A.S. | Polymodal polymer composition |
| KR102385401B1 (ko) * | 2017-09-26 | 2022-04-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 수성 중합체 조성물 |
| EP3611197A1 (en) | 2018-08-17 | 2020-02-19 | Organik Kimya Sanayi Ve Tic. A.S. | Use of a polymodal polymer composition |
| CN110872367B (zh) * | 2018-09-04 | 2023-10-03 | 罗门哈斯公司 | 多级聚合物颗粒的水分散体 |
| ES2870454T3 (es) | 2018-09-11 | 2021-10-27 | Organik Kimya Sanayi Ve Tic A S | Composiciones poliméricas polimodales para aplicaciones de revestimiento |
| WO2020105206A1 (ja) | 2018-11-22 | 2020-05-28 | 株式会社村田製作所 | 伸縮性配線基板及び伸縮性配線基板の製造方法 |
| CA3152104A1 (en) * | 2019-09-30 | 2021-04-08 | Dow Global Technologies Llc | Process for stripping an aqueous dispersion of polymeric beads |
| CN114536212B (zh) * | 2022-01-29 | 2024-02-09 | 浙江环龙新材料科技有限公司 | 一种微孔热塑性聚氨酯抛光垫及其半连续制备方法 |
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| EP1197503A2 (en) * | 2000-10-12 | 2002-04-17 | Rohm And Haas Company | Process for forming an aqueous polymeric dispersion |
| WO2002088203A2 (en) * | 2001-05-02 | 2002-11-07 | 3M Innovative Properties Company | Aqueous emulsion polymerization in the presence of ethers as chain transfer agents to produce fluoropolymers |
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| US4254004A (en) * | 1979-05-09 | 1981-03-03 | Scm Corporation | Emulsion process for polymer particles |
| JP2646770B2 (ja) * | 1989-12-13 | 1997-08-27 | 日本合成ゴム株式会社 | 共重合体ラテックスの製造方法 |
| JP3000654B2 (ja) * | 1990-10-19 | 2000-01-17 | ダイキン工業株式会社 | ポリテトラフルオロエチレン微粒子および粉末 |
| US5308890A (en) * | 1993-02-26 | 1994-05-03 | Rohm And Haas Company | Emulsion polymer blend of a multi-stage latex and a non-film forming latex |
| GB2298208B (en) | 1995-02-23 | 1998-09-09 | Cray Valley Ltd | Aqueous polymer dispersions |
| CA2179681A1 (en) * | 1995-07-05 | 1997-01-06 | Peter C. Hayes | Bimodal latex binder |
| JPH09241310A (ja) * | 1996-03-06 | 1997-09-16 | Hitachi Chem Co Ltd | 単分散樹脂微粒子の製造法 |
| EP0959176B1 (en) * | 1998-05-18 | 2012-09-05 | Rohm And Haas Company | Hollow sphere organic pigment for paper or paper coatings |
| GB9927432D0 (en) | 1999-11-20 | 2000-01-19 | Avecia Bv | Aqueous polymer emulsions |
| CA2445998A1 (en) * | 2001-05-02 | 2002-11-07 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| US6503680B1 (en) * | 2001-08-29 | 2003-01-07 | Xerox Corporation | Latex processes |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP1197503A2 (en) * | 2000-10-12 | 2002-04-17 | Rohm And Haas Company | Process for forming an aqueous polymeric dispersion |
| WO2002088203A2 (en) * | 2001-05-02 | 2002-11-07 | 3M Innovative Properties Company | Aqueous emulsion polymerization in the presence of ethers as chain transfer agents to produce fluoropolymers |
Also Published As
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| MXPA04006508A (es) | 2005-03-31 |
| JP2005036189A (ja) | 2005-02-10 |
| US20050014883A1 (en) | 2005-01-20 |
| DE602004008839T2 (de) | 2008-06-12 |
| EP1498430B1 (en) | 2007-09-12 |
| AU2004203020A1 (en) | 2005-02-03 |
| BRPI0402631A (pt) | 2005-05-24 |
| CN1576282A (zh) | 2005-02-09 |
| DE602004008839D1 (de) | 2007-10-25 |
| US7776975B2 (en) | 2010-08-17 |
| CN100340580C (zh) | 2007-10-03 |
| JP2008019451A (ja) | 2008-01-31 |
| EP1498430A1 (en) | 2005-01-19 |
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