ATE79785T1 - Denitrierungskatalysator zum reduzieren von stickstoffoxiden in abgasen. - Google Patents
Denitrierungskatalysator zum reduzieren von stickstoffoxiden in abgasen.Info
- Publication number
- ATE79785T1 ATE79785T1 AT87116965T AT87116965T ATE79785T1 AT E79785 T1 ATE79785 T1 AT E79785T1 AT 87116965 T AT87116965 T AT 87116965T AT 87116965 T AT87116965 T AT 87116965T AT E79785 T1 ATE79785 T1 AT E79785T1
- Authority
- AT
- Austria
- Prior art keywords
- catalyst
- denitriting
- exhaust gases
- nitrogen oxides
- reducing nitrogen
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title 2
- 239000007789 gas Substances 0.000 title 1
- 238000004438 BET method Methods 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61273854A JPH0817939B2 (ja) | 1986-11-19 | 1986-11-19 | 排煙脱硝触媒 |
| EP87116965A EP0268265B1 (de) | 1986-11-19 | 1987-11-17 | Denitrierungskatalysator zum Reduzieren von Stickstoffoxiden in Abgasen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE79785T1 true ATE79785T1 (de) | 1992-09-15 |
Family
ID=17533479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT87116965T ATE79785T1 (de) | 1986-11-19 | 1987-11-17 | Denitrierungskatalysator zum reduzieren von stickstoffoxiden in abgasen. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4833113A (de) |
| EP (1) | EP0268265B1 (de) |
| JP (1) | JPH0817939B2 (de) |
| AT (1) | ATE79785T1 (de) |
| CA (1) | CA1301144C (de) |
| DE (1) | DE3781373T2 (de) |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4966882A (en) * | 1987-06-05 | 1990-10-30 | Babcock-Hitachi Kabushiki Kaisha | Catalyst for denitration by catalytic reduction using ammonia and a process for producing the same |
| US5087600A (en) * | 1987-06-05 | 1992-02-11 | Babcock-Hitachi Kabushiki Kaisha | Process for producing a catalyst for denitration by catalytic reduction using ammonia |
| DE3816599C1 (en) * | 1988-05-14 | 1989-03-16 | Huels Ag, 4370 Marl, De | Process for eliminating arsenic compounds from exhaust gases |
| US5169619A (en) * | 1988-05-28 | 1992-12-08 | Sakai Chemical Industry Co., Ltd. | Method of producing titanium oxides |
| US5137855A (en) * | 1988-06-09 | 1992-08-11 | W. R. Grace & Co.-Conn. | Catalysts for selective catalytic reduction denox technology |
| US4975256A (en) * | 1988-06-09 | 1990-12-04 | W. R. Grace & Co.-Conn. | Process using catalysts for selective catalytic reduction denox technology |
| US4929586A (en) * | 1988-06-09 | 1990-05-29 | W. R. Grace & Co.-Conn. | Catalysts for selective catalytic reduction DeNOx technology |
| JP2725800B2 (ja) * | 1988-09-19 | 1998-03-11 | バブコツク日立株式会社 | 脱硝触媒の製造方法 |
| SE464688B (sv) * | 1989-02-27 | 1991-06-03 | Eka Nobel Ab | Katalysator foer reducering av kvaeveoxider samt anvaendning daerav |
| EP0403879B1 (de) * | 1989-06-21 | 1996-08-28 | Siemens Aktiengesellschaft | Arsenresistenter Mischoxidkatalysator |
| DE69009125T2 (de) * | 1989-09-14 | 1994-09-29 | Mitsubishi Heavy Ind Ltd | Vorrichtung zur Entstickung von Abgasen bei verschiedenen Temperaturen. |
| WO1993000984A1 (en) * | 1991-07-02 | 1993-01-21 | General Electric Company | A LOW TEMPERATURE, SUPPORTED METAL OXIDE CATALYTIC NOx AND SOx REMOVAL PROCESS FOR RETROFIT TO WET FLUE GAS DESULFURIZATION SYSTEMS |
| US5139982A (en) * | 1991-07-02 | 1992-08-18 | General Electric Company | Supported metal oxide catalysts for the simultaneous removal of NOx and SOx from gas streams |
| US5314551A (en) * | 1991-11-14 | 1994-05-24 | General Tire, Inc. | Tire pitch sequencing for reduced tire tread noise |
| EP0605991A1 (de) * | 1993-01-07 | 1994-07-13 | Ford Motor Company Limited | Nur Basismetall enthaltender Katalysator System für Verbrennungsmotoren |
| EP0605995B1 (de) * | 1993-01-08 | 1998-09-16 | Ford Motor Company Limited | Zweistufiges katalysator System für einem Verbrennungsmotor |
| JP3352494B2 (ja) * | 1993-03-25 | 2002-12-03 | 三井鉱山株式会社 | 窒素酸化物分解触媒及びそれを用いた脱硝方法 |
| DE4321555C1 (de) * | 1993-06-29 | 1994-09-15 | Bayer Ag | Verfahren zur Herstellung von Mischoxidpulvern für Entstickungskatalysatoren |
| US5658546A (en) * | 1993-07-30 | 1997-08-19 | Nippon Shokubai Co., Ltd. | Denitration catalyst |
| CA2212869C (en) * | 1995-03-02 | 2001-05-15 | University Technologies International, Inc. | Photocatalyst compound and process for production thereof |
| DK0768110T3 (da) * | 1995-10-09 | 2002-05-27 | Shell Int Research | Katalysator og fremgangsmåde til omdannelse af nitrogenoxidforbindelser |
| JP3377715B2 (ja) * | 1997-02-27 | 2003-02-17 | 三菱重工業株式会社 | 脱硝触媒の再生方法 |
| DE19806062A1 (de) * | 1998-02-13 | 1999-08-19 | Siemens Ag | Reduktionskatalysator und Verfahren zur Reinigung dieselmotorischen Abgases |
| US6156283A (en) | 1998-03-23 | 2000-12-05 | Engelhard Corporation | Hydrophobic catalytic materials and method of forming the same |
| DE19921207A1 (de) * | 1999-05-07 | 2000-11-16 | Siemens Ag | Verfahren zur Herstellung einer katalytisch aktiven Masse, Katalysator mit einer derart hergestellten katalytisch aktiven Masse sowie Verwendung des Katalysators zum Abbau von Dioxinen und/oder Furanen |
| US6826906B2 (en) * | 2000-08-15 | 2004-12-07 | Engelhard Corporation | Exhaust system for enhanced reduction of nitrogen oxides and particulates from diesel engines |
| KR20030006598A (ko) * | 2001-07-13 | 2003-01-23 | 주식회사 나노 | 배연 탈질 선택적 환원 촉매 담체용 이산화티타늄 분말 및이의 제조방법 |
| JP2004275852A (ja) * | 2003-03-14 | 2004-10-07 | Mitsubishi Heavy Ind Ltd | 排煙脱硝触媒及びその製造方法 |
| US7264784B2 (en) * | 2003-10-22 | 2007-09-04 | Nippon Shokubai Co., Ltd. | Method for treating exhaust gas |
| US7491676B2 (en) * | 2004-10-19 | 2009-02-17 | Millennium Inorganic Chemicals | High activity titania supported metal oxide DeNOx catalysts |
| KR100682515B1 (ko) * | 2005-05-19 | 2007-02-15 | 주식회사 엘지화학 | 메틸벤젠류 부분산화용 촉매의 제조방법 |
| WO2007061209A1 (en) | 2005-11-22 | 2007-05-31 | Lg Chem, Ltd. | Method for preparing catalyst for partial oxidation of methylbenzenes |
| US8148290B2 (en) * | 2006-06-27 | 2012-04-03 | Basf Corporation | Diesel exhaust treatment system catalyst monitoring |
| US8802582B2 (en) * | 2007-01-09 | 2014-08-12 | Catalytic Solutions, Inc. | High temperature ammonia SCR catalyst and method of using the catalyst |
| US7943097B2 (en) | 2007-01-09 | 2011-05-17 | Catalytic Solutions, Inc. | Reactor system for reducing NOx emissions from boilers |
| US20080317652A1 (en) * | 2007-01-09 | 2008-12-25 | Robert Bono | Emission control system internal to a boiler |
| US7767175B2 (en) * | 2007-01-09 | 2010-08-03 | Catalytic Solutions, Inc. | Ammonia SCR catalyst and method of using the catalyst |
| US7527776B2 (en) * | 2007-01-09 | 2009-05-05 | Catalytic Solutions, Inc. | Ammonia SCR catalyst and method of using the catalyst |
| WO2009119639A1 (ja) * | 2008-03-25 | 2009-10-01 | バブコック日立株式会社 | 鉄化合物の影響を抑制した排ガス浄化触媒 |
| US8220274B2 (en) * | 2008-05-15 | 2012-07-17 | Johnson Matthey Inc. | Emission reduction method for use with a heat recovery steam generation system |
| US8148295B2 (en) * | 2009-02-16 | 2012-04-03 | Millennium Inorganic Chemicals, Inc. | Catalyst promoters in vanadium-free mobile catalyst |
| US7879759B2 (en) * | 2009-02-16 | 2011-02-01 | Augustine Steve M | Mobile DeNOx catalyst |
| US7968492B2 (en) * | 2009-05-11 | 2011-06-28 | Millennium Inorganic Chemicals, Inc. | Layered catalyst to improve selectivity or activity of manganese containing vanadium-free mobile catalyst |
| JP5604235B2 (ja) * | 2010-09-07 | 2014-10-08 | バブコック日立株式会社 | 排ガス脱硝触媒およびその製造方法 |
| US8617502B2 (en) | 2011-02-07 | 2013-12-31 | Cristal Usa Inc. | Ce containing, V-free mobile denox catalyst |
| KR102083851B1 (ko) | 2012-08-02 | 2020-05-27 | 지멘스 악티엔게젤샤프트 | 이산화질소의 농도를 낮추기 위한 방법 |
| US8858907B2 (en) * | 2012-08-09 | 2014-10-14 | Exxonmobil Research And Engineering Company | Catalytic reduction of NOx with high activity catalysts with NH3 reductant |
| EP2940162A1 (de) | 2014-04-30 | 2015-11-04 | Tropinon Enterprises Ltd. | Wiederverwendung von titanbasierten Katalysatoren |
| US20160207840A1 (en) * | 2015-01-21 | 2016-07-21 | The Boeing Company | Extrudable ceramic composition and method of making |
| CN104888756A (zh) * | 2015-04-30 | 2015-09-09 | 华南理工大学 | 一种scr脱硝催化剂及其制备方法与应用 |
| CN108367275B (zh) | 2016-09-12 | 2021-09-21 | 中国电力株式会社 | 脱硝催化剂及其制造方法 |
| JP6833494B2 (ja) * | 2016-12-15 | 2021-02-24 | 三菱パワー株式会社 | 燃焼排ガスからNOxを除去するための触媒および方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4085193A (en) * | 1973-12-12 | 1978-04-18 | Mitsubishi Petrochemical Co. Ltd. | Catalytic process for reducing nitrogen oxides to nitrogen |
| JPS5820303B2 (ja) * | 1975-04-24 | 1983-04-22 | 三菱油化株式会社 | チツソサンカブツノカンゲンヨウシヨクバイソセイブツ |
| DE2616744A1 (de) * | 1976-04-15 | 1977-11-03 | Martin Bohlmann | Tuerkantenpuffer fuer kraftwagen |
| JPS55164111A (en) * | 1979-06-06 | 1980-12-20 | Sumitomo Aluminium Smelting Co | Preparation of high strength titania structure by extrusion molding method |
| JPS56158151A (en) * | 1980-05-10 | 1981-12-05 | Babcock Hitachi Kk | Catalyst for removing nitrogen oxide and its production |
| US4520124A (en) * | 1981-03-19 | 1985-05-28 | Sakai Chemical Industry Co., Ltd. | Method for producing a catalytic structure for the reduction of nitrogen oxides |
| US4518710A (en) * | 1984-01-25 | 1985-05-21 | Uop Inc. | Catalyst for the reduction of nitrogen oxides in gaseous mixtures and method of making the catalyst |
| DE3779209D1 (de) * | 1986-07-25 | 1992-06-25 | Mitsubishi Petrochemical Co | Katalysatoren und ihr gebrauch zur entfernung von stickoxiden in abgasen. |
| CA1310005C (en) * | 1986-09-13 | 1992-11-10 | Hiroaki Rikimaru | Catalyst and a method for denitrizing nitrogen oxides contained in waste gases |
-
1986
- 1986-11-19 JP JP61273854A patent/JPH0817939B2/ja not_active Expired - Lifetime
-
1987
- 1987-11-17 DE DE8787116965T patent/DE3781373T2/de not_active Expired - Lifetime
- 1987-11-17 AT AT87116965T patent/ATE79785T1/de not_active IP Right Cessation
- 1987-11-17 EP EP87116965A patent/EP0268265B1/de not_active Expired - Lifetime
- 1987-11-18 CA CA000552089A patent/CA1301144C/en not_active Expired - Lifetime
- 1987-11-19 US US07/122,949 patent/US4833113A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4833113A (en) | 1989-05-23 |
| CA1301144C (en) | 1992-05-19 |
| DE3781373T2 (de) | 1993-07-29 |
| EP0268265B1 (de) | 1992-08-26 |
| JPS63130140A (ja) | 1988-06-02 |
| EP0268265A2 (de) | 1988-05-25 |
| DE3781373D1 (de) | 1992-10-01 |
| EP0268265A3 (en) | 1989-03-08 |
| JPH0817939B2 (ja) | 1996-02-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification | ||
| EELA | Cancelled due to lapse of time |