ATE548114T1 - Verfahren zur herstellung von nox- reduktionszusammensetzungen zur verwendung bei fcc-verfahren - Google Patents
Verfahren zur herstellung von nox- reduktionszusammensetzungen zur verwendung bei fcc-verfahrenInfo
- Publication number
- ATE548114T1 ATE548114T1 AT03809609T AT03809609T ATE548114T1 AT E548114 T1 ATE548114 T1 AT E548114T1 AT 03809609 T AT03809609 T AT 03809609T AT 03809609 T AT03809609 T AT 03809609T AT E548114 T1 ATE548114 T1 AT E548114T1
- Authority
- AT
- Austria
- Prior art keywords
- slurry
- iii
- metal
- preparing
- metal oxide
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 239000002002 slurry Substances 0.000 abstract 4
- 229910044991 metal oxide Inorganic materials 0.000 abstract 3
- 150000004706 metal oxides Chemical class 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 238000004231 fluid catalytic cracking Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
- C10G11/182—Regeneration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/405—Limiting CO, NOx or SOx emissions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/277,026 US7307038B2 (en) | 2002-10-21 | 2002-10-21 | NOx reduction compositions for use in FCC processes |
| PCT/US2003/033477 WO2004037419A1 (en) | 2002-10-21 | 2003-10-21 | Nox reduction compositions for use in fcc processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE548114T1 true ATE548114T1 (de) | 2012-03-15 |
Family
ID=32093202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03809609T ATE548114T1 (de) | 2002-10-21 | 2003-10-21 | Verfahren zur herstellung von nox- reduktionszusammensetzungen zur verwendung bei fcc-verfahren |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7307038B2 (de) |
| EP (1) | EP1558387B1 (de) |
| JP (1) | JP2006503698A (de) |
| KR (1) | KR100994591B1 (de) |
| CN (2) | CN100484623C (de) |
| AT (1) | ATE548114T1 (de) |
| AU (1) | AU2003277457B2 (de) |
| CA (1) | CA2502988A1 (de) |
| MX (1) | MX260304B (de) |
| NO (1) | NO20052445L (de) |
| SG (1) | SG111729A1 (de) |
| TW (1) | TWI322034B (de) |
| WO (1) | WO2004037419A1 (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003265413B2 (en) * | 2002-08-13 | 2008-07-17 | Intercat, Inc. | Flue gas treatments to reduce NOx and Co emissions |
| US7431825B2 (en) * | 2003-12-05 | 2008-10-07 | Intercat, Inc. | Gasoline sulfur reduction using hydrotalcite like compounds |
| CA2548500C (en) * | 2003-12-05 | 2010-01-12 | Intercat, Inc. | Mixed metal oxide sorbents |
| TWI342335B (en) * | 2004-06-02 | 2011-05-21 | Intercat Inc | Mixed metal oxide additives |
| US7749474B2 (en) * | 2004-08-12 | 2010-07-06 | Ford Global Technologies, Llc | Catalyst composition for use in a lean NOx trap and method of using |
| US7622095B2 (en) * | 2004-08-12 | 2009-11-24 | Ford Global Technologies, Llc | Catalyst composition for use in a lean NOx trap and method of using |
| US7811961B2 (en) * | 2004-08-12 | 2010-10-12 | Ford Global Technologies, Llc | Methods and formulations for enhancing NH3 adsorption capacity of selective catalytic reduction catalysts |
| US20060035782A1 (en) * | 2004-08-12 | 2006-02-16 | Ford Global Technologies, Llc | PROCESSING METHODS AND FORMULATIONS TO ENHANCE STABILITY OF LEAN-NOx-TRAP CATALYSTS BASED ON ALKALI- AND ALKALINE-EARTH-METAL COMPOUNDS |
| MX2007011531A (es) * | 2005-03-24 | 2007-11-16 | Grace W R & Co | Metodo para controlar emisiones de nox en la fccu. |
| US20070129234A1 (en) * | 2005-12-02 | 2007-06-07 | Stockwell David M | Lower temperature CO promoters for FCC with low NOx |
| WO2009075311A1 (ja) * | 2007-12-12 | 2009-06-18 | Nikki-Universal Co., Ltd. | アンモニア分解触媒および該触媒によるアンモニア含有排ガスの処理方法 |
| CN102159314B (zh) * | 2008-09-17 | 2016-08-03 | 株式会社日本触媒 | 氨分解催化剂及其制备方法以及氨处理方法 |
| CA2779427C (en) | 2009-10-30 | 2015-12-29 | Korea Electric Power Corporation | Carbon dioxide absorbent for exhaust gas, and preparation method thereof |
| US9416322B2 (en) * | 2010-03-18 | 2016-08-16 | W. R. Grace & Co.-Conn. | Process for making improved catalysts from clay-derived zeolites |
| EP2554257A4 (de) * | 2010-03-31 | 2014-09-03 | Nippon Catalytic Chem Ind | Katalysator zur zersetzung von ammoniak, verfahren zur herstellung des katalysators und verfahren zur wasserstoffherstellung mithilfe des katalysators |
| CN101822969A (zh) * | 2010-04-02 | 2010-09-08 | 北京化工大学 | 一种含锰的吸附剂组合物及其制备方法 |
| FR2959735B1 (fr) * | 2010-05-06 | 2012-06-22 | Rhodia Operations | Composition a base d'oxydes de zirconium, de cerium d'au moins une autre terre rare, a porosite specifique, procede de preparation et utilisation en catalyse. |
| CN102059122A (zh) * | 2010-11-15 | 2011-05-18 | 苏忠 | 用于焦油裂解的催化剂及其制备方法 |
| CN103897722B (zh) * | 2012-12-27 | 2015-10-14 | 北京三聚环保新材料股份有限公司 | 一种制备fcc脱硫助剂的工艺 |
| CN104759202B (zh) * | 2015-03-12 | 2016-12-07 | 张伟 | 一种脱除催化裂化再生烟气污染物助剂及其制备方法 |
| US11529612B2 (en) | 2017-07-05 | 2022-12-20 | China Petroleum & Chemical Corporation | Composition capable of reducing CO and NOx emissions, preparation method therefor and use thereof, and fluid catalytic cracking method |
| CN109201078B (zh) * | 2017-07-05 | 2020-07-24 | 中国石油化工股份有限公司 | 能够降低CO和NOx排放的组合物及其制备方法和应用以及流化催化裂化方法 |
| CN111346657B (zh) * | 2018-12-20 | 2021-05-14 | 中国石油化工股份有限公司 | 规整结构催化剂及其制备方法和应用及不完全再生烟气的处理方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4290878A (en) | 1978-12-08 | 1981-09-22 | Chevron Research Company | NOx control in platinum-promoted complete combustion cracking catalyst regeneration |
| US4224144A (en) * | 1979-03-19 | 1980-09-23 | Standard Oil Company (Indiana) | Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur |
| US4368057A (en) | 1980-10-14 | 1983-01-11 | Matthews Ronald D | Method for reducing ammonia concentration in pre-combusted fuel gas using nitric oxide |
| CA1264051A (en) * | 1984-10-05 | 1989-12-27 | W. R. Grace Co. | Catalysts and catalyst supports |
| US4668655A (en) * | 1985-07-08 | 1987-05-26 | Texaco Inc. | Catalyst composition for catalytic cracking |
| US4755282A (en) | 1987-07-22 | 1988-07-05 | Shell Oil Company | Process for the reduction of NH3 in regeneration zone off gas by select recycle of certain-sized NH3 decomposition catalysts |
| US4744962A (en) | 1987-07-22 | 1988-05-17 | Shell Oil Company | Process for the reduction of ammonia in regeneration zone off gas by select addition of NOx to the regeneration zone or to the regeneration zone off gas |
| US5021144A (en) | 1989-02-28 | 1991-06-04 | Shell Oil Company | Process for the reduction of NOX in an FCC regeneration system by select control of CO oxidation promoter in the regeneration zone |
| US4973399A (en) | 1989-11-03 | 1990-11-27 | Mobil Oil Corporation | Catalytic cracking of hydrocarbons |
| JP3145175B2 (ja) * | 1992-03-31 | 2001-03-12 | 三井金属鉱業株式会社 | 排ガス浄化用触媒及びその製造方法 |
| DE69435061T2 (de) * | 1993-06-25 | 2008-12-18 | Basf Catalysts Llc | Katalysatorzusammensetzung |
| JP3250714B2 (ja) * | 1994-12-28 | 2002-01-28 | 株式会社豊田中央研究所 | 酸化物担持触媒担体とその製造方法及び排ガス浄化用触媒 |
| US6129834A (en) | 1995-05-05 | 2000-10-10 | W. R. Grace & Co. -Conn. | NOx reduction compositions for use in FCC processes |
| AU718321B2 (en) * | 1995-05-05 | 2000-04-13 | W.R. Grace & Co.-Conn. | Compositions for reduced NOx and combustion promotion in FCC processes |
| US6165933A (en) | 1995-05-05 | 2000-12-26 | W. R. Grace & Co.-Conn. | Reduced NOx combustion promoter for use in FCC processes |
| US6248688B1 (en) * | 1996-09-27 | 2001-06-19 | Engelhard Corporation | Catalyst composition containing oxygen storage components |
| US6800586B2 (en) * | 2001-11-23 | 2004-10-05 | Engelhard Corporation | NOx reduction composition for use in FCC processes |
-
2002
- 2002-10-21 US US10/277,026 patent/US7307038B2/en not_active Expired - Fee Related
-
2003
- 2003-10-20 TW TW092129003A patent/TWI322034B/zh not_active IP Right Cessation
- 2003-10-21 WO PCT/US2003/033477 patent/WO2004037419A1/en active Application Filing
- 2003-10-21 CN CNB2007100886402A patent/CN100484623C/zh not_active Expired - Fee Related
- 2003-10-21 CN CNB200380107195XA patent/CN100415376C/zh not_active Expired - Fee Related
- 2003-10-21 AU AU2003277457A patent/AU2003277457B2/en not_active Ceased
- 2003-10-21 EP EP03809609A patent/EP1558387B1/de not_active Expired - Lifetime
- 2003-10-21 AT AT03809609T patent/ATE548114T1/de active
- 2003-10-21 MX MXPA05004140 patent/MX260304B/es active IP Right Grant
- 2003-10-21 KR KR1020057006887A patent/KR100994591B1/ko not_active IP Right Cessation
- 2003-10-21 JP JP2004547025A patent/JP2006503698A/ja active Pending
- 2003-10-21 CA CA002502988A patent/CA2502988A1/en not_active Abandoned
- 2003-10-21 SG SG200502408A patent/SG111729A1/en unknown
-
2005
- 2005-05-20 NO NO20052445A patent/NO20052445L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003277457A1 (en) | 2004-05-13 |
| CN100415376C (zh) | 2008-09-03 |
| MXPA05004140A (es) | 2005-08-03 |
| CA2502988A1 (en) | 2004-05-06 |
| US7307038B2 (en) | 2007-12-11 |
| EP1558387B1 (de) | 2012-03-07 |
| KR100994591B1 (ko) | 2010-11-15 |
| EP1558387A1 (de) | 2005-08-03 |
| CN1729058A (zh) | 2006-02-01 |
| AU2003277457B2 (en) | 2009-12-03 |
| TWI322034B (en) | 2010-03-21 |
| CN100484623C (zh) | 2009-05-06 |
| MX260304B (es) | 2008-09-05 |
| TW200413091A (en) | 2004-08-01 |
| NO20052445D0 (no) | 2005-05-20 |
| US20040077492A1 (en) | 2004-04-22 |
| KR20050067191A (ko) | 2005-06-30 |
| NO20052445L (no) | 2005-07-21 |
| WO2004037419A1 (en) | 2004-05-06 |
| JP2006503698A (ja) | 2006-02-02 |
| CN101024179A (zh) | 2007-08-29 |
| SG111729A1 (en) | 2007-04-30 |
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