CA2293120A1 - Gasoline sulfur reduction in fluid catalytic cracking - Google Patents

Gasoline sulfur reduction in fluid catalytic cracking Download PDF

Info

Publication number
CA2293120A1
CA2293120A1 CA002293120A CA2293120A CA2293120A1 CA 2293120 A1 CA2293120 A1 CA 2293120A1 CA 002293120 A CA002293120 A CA 002293120A CA 2293120 A CA2293120 A CA 2293120A CA 2293120 A1 CA2293120 A1 CA 2293120A1
Authority
CA
Canada
Prior art keywords
sulfur reduction
cracking
component
metal
catalytic cracking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002293120A
Other languages
French (fr)
Other versions
CA2293120C (en
Inventor
Wu-Cheng Cheng
Terry G. Roberie
Hye Kyung Cho Timken
Scott Kevin Purnell
Xinjin Zhao
Arthur W. Chester
Michael S. Ziebarth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
ExxonMobil Oil Corp
Original Assignee
WR Grace and Co Conn
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/221,539 external-priority patent/US6846403B2/en
Priority claimed from US09/221,540 external-priority patent/US20020153283A1/en
Application filed by WR Grace and Co Conn, Mobil Oil Corp filed Critical WR Grace and Co Conn
Publication of CA2293120A1 publication Critical patent/CA2293120A1/en
Application granted granted Critical
Publication of CA2293120C publication Critical patent/CA2293120C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The sulfur content of liquid cracking products of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 4 of the Periodic Table, preferably vanadium. The preferred rare earth metal is cerium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
CA002293120A 1998-12-28 1999-12-24 Gasoline sulfur reduction in fluid catalytic cracking Expired - Lifetime CA2293120C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US09/221,539 1998-12-28
US09/221,539 US6846403B2 (en) 1998-12-28 1998-12-28 Gasoline sulfur reduction in fluid catalytic cracking
US09/221,540 US20020153283A1 (en) 1998-12-28 1998-12-28 Gasoline sulfur reduction in fluid catalytic cracking
US09/221,540 1998-12-28

Publications (2)

Publication Number Publication Date
CA2293120A1 true CA2293120A1 (en) 2000-06-28
CA2293120C CA2293120C (en) 2004-12-21

Family

ID=26915876

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002293120A Expired - Lifetime CA2293120C (en) 1998-12-28 1999-12-24 Gasoline sulfur reduction in fluid catalytic cracking

Country Status (14)

Country Link
JP (1) JP3550065B2 (en)
KR (1) KR100331611B1 (en)
CN (1) CN1244406C (en)
AU (1) AU726990B2 (en)
CA (1) CA2293120C (en)
DE (1) DE19962669B4 (en)
DK (1) DK176408B1 (en)
FR (1) FR2787806B1 (en)
GB (1) GB2345293B (en)
IT (1) IT1315272B1 (en)
NL (1) NL1013966C2 (en)
SE (1) SE523251C2 (en)
SG (1) SG82059A1 (en)
TW (1) TW527413B (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6635169B1 (en) * 1999-09-20 2003-10-21 Mobil Oil Corporation Method for reducing gasoline sulfur in fluid catalytic cracking
CN1156555C (en) 2000-08-10 2004-07-07 中国石油化工集团公司 Assistant for calalytic cracking and its preparing process
CA2490908C (en) 2002-06-28 2011-09-20 Albemarle Netherlands B.V. Fcc catalyst for reducing the sulfur content in gasoline and diesel
CN1261216C (en) 2003-05-30 2006-06-28 中国石油化工股份有限公司 Hydrocarbon cracking catalyst with molecular sieve and preparing method thereof
CN1261528C (en) 2003-06-30 2006-06-28 中国石油化工股份有限公司 Cracking catalyst having desulfidation
CN1333044C (en) 2003-09-28 2007-08-22 中国石油化工股份有限公司 Method for cracking hydrocarbon oil
US7347930B2 (en) 2003-10-16 2008-03-25 China Petroleum & Chemical Corporation Process for cracking hydrocarbon oils
US8084383B2 (en) * 2004-03-16 2011-12-27 W.R. Grace & Co.-Conn. Gasoline sulfur reduction catalyst for fluid catalytic cracking process
CN100389172C (en) * 2004-09-28 2008-05-21 中国石油化工股份有限公司 Composition with desulfation function
CN1958730B (en) * 2005-10-31 2010-05-12 中国石油化工股份有限公司 Method for reducing content of sulphur in gasoline
JP4840907B2 (en) * 2005-11-11 2011-12-21 独立行政法人産業技術総合研究所 Method for producing organic sulfur compound adsorbent
RU2008140381A (en) * 2006-03-15 2010-04-20 Басф Каталистс Ллк (Us) COMPOSITION OF THE CATALYST TO REDUCE THE SULFUR CONTENT IN GASOLINE IN THE PROCESS OF CATALYTIC CRACKING
JP4948863B2 (en) 2006-03-22 2012-06-06 一般財団法人石油エネルギー技術センター Catalytic cracking catalyst, production method thereof, and catalytic cracking method of hydrocarbon oil
US20090230023A1 (en) 2006-06-28 2009-09-17 Idemitsu Kosan Co., Ltd. Fluid catalytic cracking catalyst having desulfurizing functions, process for production of the same, and process for production of low-sulfur catalytically cracked gasoline with the catalyst
CN101678339B (en) 2007-02-21 2013-01-02 格雷斯公司 Gasoline sulfur reduction catalyst for fluid catalytic cracking process
JP4906535B2 (en) * 2007-02-23 2012-03-28 一般財団法人石油エネルギー技術センター Fluid catalytic cracking catalyst, process for producing the same, and process for producing low sulfur catalytic cracked gasoline
CN102093907B (en) * 2009-12-11 2013-11-06 中国石油天然气股份有限公司 Gasoline desulfurization method
CN103028432B (en) * 2013-01-11 2018-04-17 华东理工大学 A kind of wear-resistant catalyst for heavy oil catalytic cracking for reducing content of sulfur in gasoline and preparation method thereof
CN104415774B (en) * 2013-08-21 2017-03-01 中国石油化工股份有限公司 A kind of desulphurization catalyst and its preparation and application
CN104415782B (en) * 2013-08-21 2017-03-01 中国石油化工股份有限公司 A kind of desulphurization catalyst and its preparation and application
CN104415775B (en) * 2013-08-21 2016-12-28 中国石油化工股份有限公司 A kind of desulphurization catalyst and preparation and application thereof
CN104549488B (en) * 2013-10-29 2017-03-29 中国石油化工股份有限公司 A kind of method of desulphurization catalyst and its preparation and desulfurization of hydrocarbon oil
CN104549486B (en) * 2013-10-29 2017-06-30 中国石油化工股份有限公司 A kind of method of desulphurization catalyst and its preparation and desulfurization of hydrocarbon oil
CN104549487B (en) * 2013-10-29 2017-03-01 中国石油化工股份有限公司 A kind of desulphurization catalyst and its method for preparation and desulfurization of hydrocarbon oil
CN104549489B (en) * 2013-10-29 2017-07-25 中国石油化工股份有限公司 A kind of desulphurization catalyst and its preparation and the method for desulfurization of hydrocarbon oil
CN112191266A (en) * 2020-07-01 2021-01-08 湖南聚力催化剂股份有限公司 Preparation method of sulfur-reducing catalytic cracking auxiliary agent

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4153535A (en) * 1975-12-19 1979-05-08 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4206039A (en) * 1975-12-19 1980-06-03 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4437978A (en) * 1978-09-26 1984-03-20 Mobil Oil Corporation Cracking catalyst compositions for reduction of sulfur content in coke
US4221677A (en) * 1979-03-19 1980-09-09 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4369130A (en) * 1979-04-11 1983-01-18 Standard Oil Company Composition for removing sulfur oxides from a gas
US4606813A (en) * 1983-02-25 1986-08-19 Engelhard Corporation Fluid catalytic cracking catalyst for cracking sulfur containing petroleum feedstocks and a process for using it
US4589978A (en) * 1985-03-01 1986-05-20 Mobil Oil Corporation Catalyst for reduction of SOx emissions from FCC units
US5482617A (en) * 1993-03-08 1996-01-09 Mobil Oil Corporation Desulfurization of hydrocarbon streams

Also Published As

Publication number Publication date
KR20000048453A (en) 2000-07-25
JP3550065B2 (en) 2004-08-04
CA2293120C (en) 2004-12-21
KR100331611B1 (en) 2002-04-09
ITMI992725A0 (en) 1999-12-28
GB2345293B (en) 2003-02-19
IT1315272B1 (en) 2003-02-03
AU6549199A (en) 2000-06-29
NL1013966C2 (en) 2001-11-27
JP2000198989A (en) 2000-07-18
GB2345293A (en) 2000-07-05
DK176408B1 (en) 2007-12-17
DK199901844A (en) 2000-06-29
FR2787806B1 (en) 2003-09-05
DE19962669B4 (en) 2004-07-01
SG82059A1 (en) 2001-07-24
SE9904787D0 (en) 1999-12-27
SE9904787L (en) 2000-06-29
CN1244406C (en) 2006-03-08
CN1261618A (en) 2000-08-02
DE19962669A1 (en) 2000-08-03
GB9930680D0 (en) 2000-02-16
SE523251C2 (en) 2004-04-06
AU726990B2 (en) 2000-11-30
ITMI992725A1 (en) 2001-06-28
NL1013966A1 (en) 2000-06-30
FR2787806A1 (en) 2000-06-30
TW527413B (en) 2003-04-11

Similar Documents

Publication Publication Date Title
CA2293120A1 (en) Gasoline sulfur reduction in fluid catalytic cracking
CA2281445A1 (en) Gasoline sulfur reduction in fluid catalytic cracking
DE60021593D1 (en) REDUCTION OF THE GASOLIN SULFUR CONTENT IN A CATALYTIC FLUID COATING PROCESS
JPS56115638A (en) Hydrogenation of heavy-duty hydrocarbon oil containing asphaltene
EP1262234A3 (en) Hydrogenation catalyst for aromatic hydrocarbons contained in hydrocarbon oils
CA2224491A1 (en) A highly purified biogenic silica product
CA2392923A1 (en) A catalytic cracking process using a modified mesoporous aluminophosphate material
CA2322185A1 (en) Iron-based catalyst for hydrogenating alpha-, omega-dinitriles
IL174876A0 (en) FERRIERITE COMPOSITIONS FOR REDUCING NOx EMISSIONS DURING FLUID CATALYTIC CRACKING
CA2140863A1 (en) Catalysts and their use in oxidation of saturated hydrocarbons
CA2220496A1 (en) La/nd-spinel compositions for metals passivation in fcc processes
TWI266647B (en) Catalyst and process for removing organohalogen compounds
EP0884371A3 (en) Catalyst for cracking heavy oil
WO2002066163A3 (en) Cracking catalyst composition
ZA200204491B (en) A thermally stable, high surface area, modified mesoporous aluminophosphate.
GC0000065A (en) Hydrocracking catalyst, producing method threof, and hydrocracking method.
DE3366929D1 (en) Use of vanadium, niobium and tantalum peroxidic complexes as reagents and catalysts in the hydroxylation of aromatic hydrocarbons
EP1013332A3 (en) Combustion catalysts and processes for removing organic compounds
CA2444488A1 (en) Zeolite based catalyst of ultra-high kinetic conversion activity
AU584424B2 (en) Composition for scavenging vanadium and catalytic cracking catalyst containing same
WO2003006578A3 (en) Gasoline sulfur reduction in fluid catalytic cracking
EP0201152A3 (en) Fluidizable cracking catalyst composition
JPS572224A (en) Oxyhalogenation
JPS57204231A (en) Catalyst for hydrocracking heavy oil
WO2005002726A8 (en) Catalyst and process for the preparation of middle distillates and lube bases starting from hydrocarbon feedstocks

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20191224