SE9904787L - Sulfur reduction in gasoline during catalytic cracking in floating bed - Google Patents

Sulfur reduction in gasoline during catalytic cracking in floating bed

Info

Publication number
SE9904787L
SE9904787L SE9904787A SE9904787A SE9904787L SE 9904787 L SE9904787 L SE 9904787L SE 9904787 A SE9904787 A SE 9904787A SE 9904787 A SE9904787 A SE 9904787A SE 9904787 L SE9904787 L SE 9904787L
Authority
SE
Sweden
Prior art keywords
sulphur
metal
catalytic cracking
floating bed
cerium
Prior art date
Application number
SE9904787A
Other languages
Unknown language ( )
Swedish (sv)
Other versions
SE523251C2 (en
SE9904787D0 (en
Inventor
Wu-Cheng Cheng
Terry G Roberie
Hye Kyung Cho Timken
Scott Kevin Purnell
Xinjin Zhao
Arthur W Chester
Michael S Ziebarth
Original Assignee
Mobil Oil Corp
Grace W R & Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/221,539 external-priority patent/US6846403B2/en
Priority claimed from US09/221,540 external-priority patent/US20020153283A1/en
Application filed by Mobil Oil Corp, Grace W R & Co filed Critical Mobil Oil Corp
Publication of SE9904787D0 publication Critical patent/SE9904787D0/en
Publication of SE9904787L publication Critical patent/SE9904787L/en
Publication of SE523251C2 publication Critical patent/SE523251C2/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166Y-type faujasite
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles

Abstract

The sulphur content of the liquid products from a catalytic cracking process is reduced by the use of a sulphur reduction catalyst comprising a porous molecular sieve which contains, with the interior pore structure of the sieve, (i) a first metal componet which has an oxidation state grater than zero, and (ii) a second metal component which comprises at least one rare earth metal. The molecular sieve is preferably a large-bore size zeolite such as a faujasite, for example, USY. The primary sulphur reduction component is normally a metal of Period 4 of the Periodic Table, preferably vanadium. The preferred rare earth metal is cerium, although lanthanum may be used alone or in combination with cerium. The sulphur reduction catalyst may be used in the form of separate particle additive or as part of a single combined/integrated cracking/sulphur catalyst.
SE9904787A 1998-12-28 1999-12-27 Process for reducing the sulfur content in a liquid catalytic cracked petroleum fraction, method for catalytic cracking in the floating bed and fluidizable catalyst composition SE523251C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/221,539 US6846403B2 (en) 1998-12-28 1998-12-28 Gasoline sulfur reduction in fluid catalytic cracking
US09/221,540 US20020153283A1 (en) 1998-12-28 1998-12-28 Gasoline sulfur reduction in fluid catalytic cracking

Publications (3)

Publication Number Publication Date
SE9904787D0 SE9904787D0 (en) 1999-12-27
SE9904787L true SE9904787L (en) 2000-06-29
SE523251C2 SE523251C2 (en) 2004-04-06

Family

ID=26915876

Family Applications (1)

Application Number Title Priority Date Filing Date
SE9904787A SE523251C2 (en) 1998-12-28 1999-12-27 Process for reducing the sulfur content in a liquid catalytic cracked petroleum fraction, method for catalytic cracking in the floating bed and fluidizable catalyst composition

Country Status (14)

Country Link
JP (1) JP3550065B2 (en)
KR (1) KR100331611B1 (en)
CN (1) CN1244406C (en)
AU (1) AU726990B2 (en)
CA (1) CA2293120C (en)
DE (1) DE19962669B4 (en)
DK (1) DK176408B1 (en)
FR (1) FR2787806B1 (en)
GB (1) GB2345293B (en)
IT (1) IT1315272B1 (en)
NL (1) NL1013966C2 (en)
SE (1) SE523251C2 (en)
SG (1) SG82059A1 (en)
TW (1) TW527413B (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6635169B1 (en) * 1999-09-20 2003-10-21 Mobil Oil Corporation Method for reducing gasoline sulfur in fluid catalytic cracking
CN1156555C (en) 2000-08-10 2004-07-07 中国石油化工集团公司 Assistant for calalytic cracking and its preparing process
EP1517747A1 (en) 2002-06-28 2005-03-30 Albemarle Netherlands B.V. Fcc catalyst for reducing the sulfur content in gasoline and diesel
CN1261216C (en) 2003-05-30 2006-06-28 中国石油化工股份有限公司 Hydrocarbon cracking catalyst with molecular sieve and preparing method thereof
CN1261528C (en) 2003-06-30 2006-06-28 中国石油化工股份有限公司 Cracking catalyst having desulfidation
CN1333044C (en) 2003-09-28 2007-08-22 中国石油化工股份有限公司 Method for cracking hydrocarbon oil
US7347930B2 (en) 2003-10-16 2008-03-25 China Petroleum & Chemical Corporation Process for cracking hydrocarbon oils
US8084383B2 (en) * 2004-03-16 2011-12-27 W.R. Grace & Co.-Conn. Gasoline sulfur reduction catalyst for fluid catalytic cracking process
CN100389172C (en) * 2004-09-28 2008-05-21 中国石油化工股份有限公司 Composition with desulfation function
CN1958730B (en) * 2005-10-31 2010-05-12 中国石油化工股份有限公司 Method for reducing content of sulphur in gasoline
JP4840907B2 (en) * 2005-11-11 2011-12-21 独立行政法人産業技術総合研究所 Method for producing organic sulfur compound adsorbent
CA2645839C (en) * 2006-03-15 2016-08-16 Basf Catalysts Llc Catalyst composition for reducilng gasoline sulfur content in catalytic cracking process
JP4948863B2 (en) * 2006-03-22 2012-06-06 一般財団法人石油エネルギー技術センター Catalytic cracking catalyst, production method thereof, and catalytic cracking method of hydrocarbon oil
EP2045012A4 (en) 2006-06-28 2013-10-23 Idemitsu Kosan Co Fluid catalytic cracking catalyst having desulfurizing functions, process for production of the same, and process for production of low-sulfur catalytically cracked gasoline with the catalyst
US8901026B2 (en) 2007-02-21 2014-12-02 W. R. Grace & Co.-Conn. Gasoline sulfur reduction catalyst for fluid catalytic cracking process
JP4906535B2 (en) * 2007-02-23 2012-03-28 一般財団法人石油エネルギー技術センター Fluid catalytic cracking catalyst, process for producing the same, and process for producing low sulfur catalytic cracked gasoline
CN102093907B (en) * 2009-12-11 2013-11-06 中国石油天然气股份有限公司 Method for desulphurizing gasoline
CN103028432B (en) * 2013-01-11 2018-04-17 华东理工大学 A kind of wear-resistant catalyst for heavy oil catalytic cracking for reducing content of sulfur in gasoline and preparation method thereof
CN104415775B (en) * 2013-08-21 2016-12-28 中国石油化工股份有限公司 A kind of desulphurization catalyst and preparation and application thereof
CN104415782B (en) * 2013-08-21 2017-03-01 中国石油化工股份有限公司 A kind of desulphurization catalyst and its preparation and application
CN104415774B (en) * 2013-08-21 2017-03-01 中国石油化工股份有限公司 A kind of desulphurization catalyst and its preparation and application
CN104549487B (en) * 2013-10-29 2017-03-01 中国石油化工股份有限公司 A kind of desulphurization catalyst and its method for preparation and desulfurization of hydrocarbon oil
CN104549489B (en) * 2013-10-29 2017-07-25 中国石油化工股份有限公司 A kind of desulphurization catalyst and its preparation and the method for desulfurization of hydrocarbon oil
CN104549488B (en) * 2013-10-29 2017-03-29 中国石油化工股份有限公司 A kind of method of desulphurization catalyst and its preparation and desulfurization of hydrocarbon oil
CN104549486B (en) * 2013-10-29 2017-06-30 中国石油化工股份有限公司 A kind of method of desulphurization catalyst and its preparation and desulfurization of hydrocarbon oil
CN112191266A (en) * 2020-07-01 2021-01-08 湖南聚力催化剂股份有限公司 Preparation method of sulfur-reducing catalytic cracking auxiliary agent

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4153535A (en) * 1975-12-19 1979-05-08 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4206039A (en) * 1975-12-19 1980-06-03 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4437978A (en) * 1978-09-26 1984-03-20 Mobil Oil Corporation Cracking catalyst compositions for reduction of sulfur content in coke
US4221677A (en) * 1979-03-19 1980-09-09 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4369130A (en) * 1979-04-11 1983-01-18 Standard Oil Company Composition for removing sulfur oxides from a gas
US4606813A (en) * 1983-02-25 1986-08-19 Engelhard Corporation Fluid catalytic cracking catalyst for cracking sulfur containing petroleum feedstocks and a process for using it
US4589978A (en) * 1985-03-01 1986-05-20 Mobil Oil Corporation Catalyst for reduction of SOx emissions from FCC units
US5482617A (en) * 1993-03-08 1996-01-09 Mobil Oil Corporation Desulfurization of hydrocarbon streams

Also Published As

Publication number Publication date
CA2293120A1 (en) 2000-06-28
TW527413B (en) 2003-04-11
GB2345293B (en) 2003-02-19
CN1244406C (en) 2006-03-08
KR20000048453A (en) 2000-07-25
SG82059A1 (en) 2001-07-24
JP2000198989A (en) 2000-07-18
ITMI992725A1 (en) 2001-06-28
IT1315272B1 (en) 2003-02-03
DK199901844A (en) 2000-06-29
ITMI992725A0 (en) 1999-12-28
AU6549199A (en) 2000-06-29
DK176408B1 (en) 2007-12-17
FR2787806B1 (en) 2003-09-05
CN1261618A (en) 2000-08-02
DE19962669A1 (en) 2000-08-03
KR100331611B1 (en) 2002-04-09
CA2293120C (en) 2004-12-21
NL1013966A1 (en) 2000-06-30
SE523251C2 (en) 2004-04-06
JP3550065B2 (en) 2004-08-04
NL1013966C2 (en) 2001-11-27
DE19962669B4 (en) 2004-07-01
SE9904787D0 (en) 1999-12-27
AU726990B2 (en) 2000-11-30
GB2345293A (en) 2000-07-05
GB9930680D0 (en) 2000-02-16
FR2787806A1 (en) 2000-06-30

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