ATE496928T1 - Bisacylphosphane und ihre verwendung als photoinitiatoren, verfahren zur herstellung von acylphosphanen - Google Patents
Bisacylphosphane und ihre verwendung als photoinitiatoren, verfahren zur herstellung von acylphosphanenInfo
- Publication number
- ATE496928T1 ATE496928T1 AT05817544T AT05817544T ATE496928T1 AT E496928 T1 ATE496928 T1 AT E496928T1 AT 05817544 T AT05817544 T AT 05817544T AT 05817544 T AT05817544 T AT 05817544T AT E496928 T1 ATE496928 T1 AT E496928T1
- Authority
- AT
- Austria
- Prior art keywords
- formula
- metal
- optionally
- c18alkenyl
- c18alkyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 2
- 239000012190 activator Substances 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- UQRONKZLYKUEMO-UHFFFAOYSA-N 4-methyl-1-(2,4,6-trimethylphenyl)pent-4-en-2-one Chemical group CC(=C)CC(=O)Cc1c(C)cc(C)cc1C UQRONKZLYKUEMO-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005917 acylation reaction Methods 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- SAWKFRBJGLMMES-UHFFFAOYSA-N methylphosphine Chemical compound PC SAWKFRBJGLMMES-UHFFFAOYSA-N 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5036—Phosphines containing the structure -C(=X)-P or NC-P
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/5537—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom the heteroring containing the structure -C(=O)-N-C(=O)- (both carbon atoms belong to the heteroring)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/6552—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a six-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04105987 | 2004-11-23 | ||
| PCT/EP2005/055935 WO2006056541A1 (en) | 2004-11-23 | 2005-11-14 | Process for preparing acylphosphanes and derivatives thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE496928T1 true ATE496928T1 (de) | 2011-02-15 |
Family
ID=34929912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT05817544T ATE496928T1 (de) | 2004-11-23 | 2005-11-14 | Bisacylphosphane und ihre verwendung als photoinitiatoren, verfahren zur herstellung von acylphosphanen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7687657B2 (de) |
| EP (1) | EP1814891B1 (de) |
| JP (1) | JP5148283B2 (de) |
| KR (1) | KR101230940B1 (de) |
| CN (1) | CN101065388B (de) |
| AT (1) | ATE496928T1 (de) |
| DE (1) | DE602005026156D1 (de) |
| TW (1) | TW200630376A (de) |
| WO (1) | WO2006056541A1 (de) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5234912B2 (ja) | 2005-01-17 | 2013-07-10 | チバ ホールディング インコーポレーテッド | アシルホスファン、並びにこれらの酸化物及び硫化物の製造方法 |
| EP2199273B1 (de) | 2008-12-18 | 2018-02-21 | Agfa Nv | Polymerisierbare Fotoinitiatoren und strahlungshärtbare Zusammensetzungen |
| WO2010121387A1 (en) | 2009-04-20 | 2010-10-28 | ETH Zürich | Polymer nanoparticles |
| WO2010133381A1 (en) | 2009-05-18 | 2010-11-25 | Agfa Graphics Nv | Polymerizable polymeric photoinitiators and radiation curable compositions |
| EP2451847B1 (de) | 2009-07-06 | 2021-11-24 | IGM Group B.V. | Polymergebundene bisacylphosphinoxide |
| JP5515070B2 (ja) | 2010-06-30 | 2014-06-11 | ディーエスエム アイピー アセッツ ビー．ブイ． | Ｄ１４９２液体ｂａｐｏ光開始剤および放射線硬化性組成物におけるその使用 |
| BR112012029161B1 (pt) * | 2010-06-30 | 2019-09-24 | Dsm Ip Assets B.V. | Composição curável por radiação para fibra ótica, composição de revestimento de fibra ótica e composição curável por radiação |
| US8921442B2 (en) | 2010-10-19 | 2014-12-30 | Max-Planck-Gesellschaft Zur Foerderung Der Wissenschaften E. V. | Ultra fast process for the preparation of polymer nanoparticles |
| WO2012052147A1 (en) | 2010-10-19 | 2012-04-26 | MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. | Process for the modification of polymers, in particular polymer nanoparticles |
| CN102924509A (zh) * | 2011-08-09 | 2013-02-13 | 陈婷 | 双膦酰膦酸酯化合物 |
| CN103073658A (zh) * | 2011-10-26 | 2013-05-01 | 深圳市有为化学技术有限公司 | 新型芳香羟基酮和膦酰氧化物的光引发剂混合物及其与光吸收剂的复合体系 |
| CN103130831A (zh) * | 2011-12-01 | 2013-06-05 | 深圳市有为化学技术有限公司 | 巯基取代的酰基膦氧化合物及含有该化合物的光引发剂 |
| EP2902456B1 (de) * | 2012-09-27 | 2020-10-21 | FUJIFILM Corporation | Tintenzusammensetzung, tintenstrahlaufzeichnungsverfahren, bedrucktes material, bisacylphosphinoxidverbindung und monoacylphosphinoxidverbindung |
| ES2720760T3 (es) | 2012-10-01 | 2019-07-24 | Eth Zuerich | Un procedimiento para la preparación de acilofosfanos |
| JP6161089B2 (ja) | 2012-12-18 | 2017-07-12 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ナフタレンジイミド−ビニレン−オリゴチオフェン−ビニレンポリマーに基づく半導体材料 |
| CN110172073A (zh) * | 2012-12-19 | 2019-08-27 | Igm集团公司 | 双酰基次膦酸的衍生物、其制备及其作为光敏引发剂的用途 |
| CN105339375A (zh) * | 2013-07-08 | 2016-02-17 | 巴斯夫欧洲公司 | 液态双酰基氧化膦光引发剂 |
| CN107001400B (zh) * | 2014-05-30 | 2019-08-27 | 意大利艾坚蒙树脂有限公司 | 多官能酰基氧化膦光引发剂 |
| CN105884824A (zh) * | 2014-10-16 | 2016-08-24 | 郑成 | 酰基膦(氧)或磺酰膦(氧)类化合物的制备方法 |
| EP3031798B1 (de) | 2014-12-10 | 2017-09-27 | Belenos Clean Power Holding AG | Neuartiger Vernetzer zur Herstellung einer neuen Familie einzelner Ionenleitungspolymere für elektrochemische Vorrichtungen und diese Polymere |
| CN104592298B (zh) * | 2014-12-31 | 2016-07-06 | 湖北固润科技股份有限公司 | 一种酰基膦高效光引发剂及其制备方法 |
| CN104910207B (zh) * | 2015-02-12 | 2019-03-05 | 天津墨森科技有限公司 | 双苯甲酰基苯基氧化膦和苯甲酰基二苯基氧化膦的制备方法 |
| EP3296301A1 (de) | 2016-09-19 | 2018-03-21 | ETH Zürich | Vielseitiges verfahren zur herstellung von acylphosphinen |
| CA3043849A1 (en) | 2016-11-16 | 2018-05-24 | Ecole Polytechnique Federale De Lausanne (Epfl) | Photopolymerizable bone filler material |
| US10858380B2 (en) | 2017-04-03 | 2020-12-08 | Hewlett-Packard Development Company, L.P. | Photo active agents |
| EP3409680B1 (de) * | 2017-05-30 | 2021-01-06 | IGM Group B.V. | Synthese von bis(acyl)phosphinen durch aktivierung von nicht-reaktiven metallphosphiden |
| CN107400144B (zh) * | 2017-08-03 | 2020-04-14 | 深圳有为技术控股集团有限公司 | 酰基膦(氧)化合物及其制备方法和应用 |
| EP3665232A4 (de) | 2017-08-10 | 2021-04-07 | Sun Chemical Corporation | Uv-härtbare zusammensetzungen mit acylphosphinoxid-photoinitiatoren |
| EP3539924A1 (de) | 2018-03-14 | 2019-09-18 | ETH Zurich | Neuartige vinylphosphine und daraus erhältliche photoinitiatoren |
| US20210222038A1 (en) | 2018-04-30 | 2021-07-22 | Basf Se | High molar mass polymers from a continuous process |
| ES2925576T3 (es) | 2018-06-19 | 2022-10-18 | Agfa Nv | Iniciadores de óxido de acilfosfina |
| EP3847179A1 (de) | 2018-09-07 | 2021-07-14 | IGM Resins Italia S.r.l. | Multifunktionelle bisacylphosphinoxid-fotoinitiatoren |
| CN115697278A (zh) | 2020-05-29 | 2023-02-03 | 卢门多股份公司 | 用于化学稳定的聚合物凝胶的可交联的预聚物 |
| US11964425B2 (en) | 2021-05-12 | 2024-04-23 | Elkem Silicones USA Corp. | Method for producing a three-dimensional printed article |
| US20220380549A1 (en) | 2021-05-12 | 2022-12-01 | Elkem Silicones USA Corp. | Method for producing a three-dimensional printed article |
| CN115612112B (zh) * | 2021-07-16 | 2023-11-10 | 常州强力先端电子材料有限公司 | 有机磷类大分子类引发剂及其制备方法、光固化组合物 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3397039A (en) * | 1967-05-17 | 1968-08-13 | Procter & Gamble | Preparation of alkali metal phosphides |
| JPS4741114Y1 (de) * | 1968-02-14 | 1972-12-12 | ||
| DE2007535C3 (de) * | 1970-02-19 | 1974-12-12 | Basf Ag, 6700 Ludsigshafen | Verfahren zur Herstellung von Triarylphosphinen |
| US3668093A (en) * | 1971-05-06 | 1972-06-06 | Du Pont | Photoinitiation of vinyl polymerization by triaroylphosphines |
| DE3020092A1 (de) * | 1980-05-27 | 1981-12-10 | Basf Ag, 6700 Ludwigshafen | Acylphosphinverbindungen und ihre verwendung |
| DE3443221A1 (de) * | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
| US5218009A (en) * | 1989-08-04 | 1993-06-08 | Ciba-Geigy Corporation | Mono- and di-acylphosphine oxides |
| EP0495751A1 (de) * | 1991-01-14 | 1992-07-22 | Ciba-Geigy Ag | Bisacylphosphine |
| US6888031B1 (en) * | 1998-11-30 | 2005-05-03 | Ciba Specialty Chemicals Corporation | Process for the preparation of acylphosphines, acyl oxides and acyl sulfides |
| GB2360283B (en) * | 2000-02-08 | 2002-08-21 | Ciba Sc Holding Ag | Monoacylarylphosphines and acylphosphine oxides and sulphides |
| GB2365430B (en) * | 2000-06-08 | 2002-08-28 | Ciba Sc Holding Ag | Acylphosphine photoinitiators and intermediates |
| US7148382B2 (en) * | 2001-08-21 | 2006-12-12 | Ciba Specialty Chemicals Corporation | Bathochromic mono- and bis-acylphosphine oxides and sulfides and their use as photoinitiators |
| MXPA04004729A (es) * | 2001-11-20 | 2004-07-30 | Ciba Sc Holding Ag | Formas multimericas de acilfosfinas y sus derivados. |
| JP4599169B2 (ja) * | 2002-12-04 | 2010-12-15 | チバ ホールディング インコーポレーテッド | シクロオルガニルホスファンおよびジ（アルカリ金属／アルカリ土類金属）オリゴホスファンジイドの合成方法 |
| WO2005014605A1 (en) * | 2003-07-18 | 2005-02-17 | Ciba Specialty Chemicals Holding Inc. | Process for preparing acylphosphanes and derivatives thereof |
| TW200523265A (en) * | 2003-07-31 | 2005-07-16 | Basf Ag | A process for the preparation of acylphosphines |
| US7608639B2 (en) * | 2003-10-14 | 2009-10-27 | Eli Lilly And Company | Phenoxyether derivatives as PPAR modulators |
-
2005
- 2005-11-14 AT AT05817544T patent/ATE496928T1/de not_active IP Right Cessation
- 2005-11-14 JP JP2007541935A patent/JP5148283B2/ja active Active
- 2005-11-14 KR KR1020077014374A patent/KR101230940B1/ko active IP Right Grant
- 2005-11-14 WO PCT/EP2005/055935 patent/WO2006056541A1/en active Application Filing
- 2005-11-14 CN CN2005800401612A patent/CN101065388B/zh active Active
- 2005-11-14 US US11/667,780 patent/US7687657B2/en active Active
- 2005-11-14 DE DE602005026156T patent/DE602005026156D1/de active Active
- 2005-11-14 EP EP05817544A patent/EP1814891B1/de active Active
- 2005-11-22 TW TW094140925A patent/TW200630376A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE602005026156D1 (de) | 2011-03-10 |
| TW200630376A (en) | 2006-09-01 |
| JP5148283B2 (ja) | 2013-02-20 |
| EP1814891A1 (de) | 2007-08-08 |
| CN101065388A (zh) | 2007-10-31 |
| JP2008520623A (ja) | 2008-06-19 |
| KR20070086609A (ko) | 2007-08-27 |
| US7687657B2 (en) | 2010-03-30 |
| EP1814891B1 (de) | 2011-01-26 |
| KR101230940B1 (ko) | 2013-02-08 |
| US20080004464A1 (en) | 2008-01-03 |
| WO2006056541A1 (en) | 2006-06-01 |
| CN101065388B (zh) | 2011-12-21 |
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