ATE388252T1 - Beschichtetes cermet-schneidwerkzeug mit harter überzugsschicht, welche eine hervorragende schlagbeständigkeit bei taktweiser hochgeschwindigkeitsschneidarbeit aufweist - Google Patents
Beschichtetes cermet-schneidwerkzeug mit harter überzugsschicht, welche eine hervorragende schlagbeständigkeit bei taktweiser hochgeschwindigkeitsschneidarbeit aufweistInfo
- Publication number
- ATE388252T1 ATE388252T1 AT06100058T AT06100058T ATE388252T1 AT E388252 T1 ATE388252 T1 AT E388252T1 AT 06100058 T AT06100058 T AT 06100058T AT 06100058 T AT06100058 T AT 06100058T AT E388252 T1 ATE388252 T1 AT E388252T1
- Authority
- AT
- Austria
- Prior art keywords
- layer
- lattice points
- constituent atoms
- constituent
- covalent
- Prior art date
Links
- 239000011195 cermet Substances 0.000 title abstract 3
- 239000011248 coating agent Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 230000002452 interceptive effect Effects 0.000 title 1
- 239000010410 layer Substances 0.000 abstract 14
- 239000000470 constituent Substances 0.000 abstract 8
- 239000013078 crystal Substances 0.000 abstract 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000011247 coating layer Substances 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical group O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/34—Nitrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
- B23P15/28—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass cutting tools
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/36—Carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/40—Oxides
- C23C16/403—Oxides of aluminium, magnesium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Chemical Vapour Deposition (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005013767A JP4518260B2 (ja) | 2005-01-21 | 2005-01-21 | 硬質被覆層が高速断続切削加工ですぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE388252T1 true ATE388252T1 (de) | 2008-03-15 |
Family
ID=36123309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT06100058T ATE388252T1 (de) | 2005-01-21 | 2006-01-04 | Beschichtetes cermet-schneidwerkzeug mit harter überzugsschicht, welche eine hervorragende schlagbeständigkeit bei taktweiser hochgeschwindigkeitsschneidarbeit aufweist |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7442433B2 (de) |
| EP (1) | EP1683893B1 (de) |
| JP (1) | JP4518260B2 (de) |
| KR (1) | KR101186792B1 (de) |
| CN (1) | CN100537087C (de) |
| AT (1) | ATE388252T1 (de) |
| DE (1) | DE602006000601T2 (de) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4716251B2 (ja) * | 2005-03-24 | 2011-07-06 | 三菱マテリアル株式会社 | 高硬度鋼の高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
| JP4645983B2 (ja) * | 2005-04-12 | 2011-03-09 | 三菱マテリアル株式会社 | 硬質被覆層が高速断続切削加工ですぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
| JP4716253B2 (ja) * | 2005-05-24 | 2011-07-06 | 三菱マテリアル株式会社 | 厚膜化α型酸化アルミニウム層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
| JP4716252B2 (ja) * | 2005-05-24 | 2011-07-06 | 三菱マテリアル株式会社 | 厚膜化α型酸化アルミニウム層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
| CN1966264B (zh) | 2005-11-18 | 2012-07-04 | 三菱麻铁里亚尔株式会社 | 表面包覆金属陶瓷制切削工具 |
| JP4853120B2 (ja) * | 2006-06-12 | 2012-01-11 | 三菱マテリアル株式会社 | 硬質被覆層が高速断続切削加工ですぐれた耐チッピング性および耐摩耗性を発揮する表面被覆サーメット製切削工具 |
| JP4853121B2 (ja) * | 2006-06-12 | 2012-01-11 | 三菱マテリアル株式会社 | 硬質被覆層が高速断続切削加工ですぐれた耐チッピング性および耐摩耗性を発揮する表面被覆サーメット製切削工具 |
| US20080049400A1 (en) * | 2006-08-25 | 2008-02-28 | Philip Pecorino | Cover for a flat panel display |
| JP5187570B2 (ja) * | 2007-12-28 | 2013-04-24 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆切削工具 |
| US7597511B2 (en) | 2007-12-28 | 2009-10-06 | Mitsubishi Materials Corporation | Surface-coated cutting tool with hard coating layer having excellent abrasion resistance |
| JP5187571B2 (ja) * | 2008-06-20 | 2013-04-24 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐摩耗性を発揮する表面被覆切削工具 |
| JP5176797B2 (ja) * | 2008-09-08 | 2013-04-03 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆切削工具 |
| WO2010106811A1 (ja) | 2009-03-18 | 2010-09-23 | 三菱マテリアル株式会社 | 表面被覆切削工具 |
| US20110016946A1 (en) * | 2009-07-21 | 2011-01-27 | Sudhir Brahmandam | Coated Tooling |
| JP5440268B2 (ja) * | 2010-03-05 | 2014-03-12 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆切削工具 |
| JP5440267B2 (ja) * | 2010-03-05 | 2014-03-12 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆切削工具 |
| CN102380629B (zh) * | 2010-09-01 | 2016-08-03 | 三菱综合材料株式会社 | 硬质包覆层发挥优异的耐削性、耐磨性的表面包覆切削工具 |
| CN102398050B (zh) * | 2010-09-09 | 2015-09-30 | 三菱综合材料株式会社 | 耐崩刀的表面包覆切削工具 |
| JP5818159B2 (ja) * | 2011-02-03 | 2015-11-18 | 三菱マテリアル株式会社 | 硬質被覆層がすぐれた耐チッピング性、耐欠損性を備える表面被覆切削工具 |
| JP5739189B2 (ja) * | 2011-02-24 | 2015-06-24 | 三菱マテリアル株式会社 | 耐摩耗性に優れた表面被覆切削工具の製造方法 |
| ES2567039T5 (es) | 2011-09-16 | 2019-07-03 | Walter Ag | Herramienta de corte revestida con alúmina alfa que contiene azufre |
| ES2728705T3 (es) * | 2011-09-16 | 2019-10-28 | Walter Ag | Herramienta de corte recubierta con alfa-alúmina diseñada con límites de grano |
| JP5907406B2 (ja) * | 2011-11-30 | 2016-04-26 | 三菱マテリアル株式会社 | 硬質被覆層が高速断続切削ですぐれた耐チッピング性を発揮する表面被覆切削工具 |
| JP5850404B2 (ja) * | 2012-03-14 | 2016-02-03 | 三菱マテリアル株式会社 | Wc基超硬合金製切削工具インサート |
| JP5892380B2 (ja) * | 2012-06-29 | 2016-03-23 | 三菱マテリアル株式会社 | 高速断続切削加工で硬質被覆層がすぐれた耐チッピング性、耐摩耗性を発揮する表面被覆切削工具 |
| US9371580B2 (en) | 2013-03-21 | 2016-06-21 | Kennametal Inc. | Coated body wherein the coating scheme includes a coating layer of TiAl2O3 and method of making the same |
| CN105051248B (zh) | 2013-03-21 | 2018-03-20 | 钴碳化钨硬质合金公司 | 用于切削工具的涂层 |
| CN105102673B (zh) | 2013-03-21 | 2017-11-17 | 钴碳化钨硬质合金公司 | 用于切削工具的涂层 |
| CN103741117A (zh) * | 2013-12-24 | 2014-04-23 | 成都工具研究所有限公司 | 用于低速重载车削钢、不锈钢的刀具涂层 |
| JP6206686B2 (ja) * | 2014-01-27 | 2017-10-04 | 株式会社タンガロイ | 被覆切削工具 |
| JP6657594B2 (ja) | 2014-05-16 | 2020-03-04 | 三菱マテリアル株式会社 | 表面被覆切削工具 |
| JP6548072B2 (ja) * | 2014-05-30 | 2019-07-24 | 三菱マテリアル株式会社 | 表面被覆切削工具 |
| JP6315197B2 (ja) * | 2014-09-26 | 2018-04-25 | 三菱マテリアル株式会社 | 複合焼結体切削工具 |
| US9719175B2 (en) | 2014-09-30 | 2017-08-01 | Kennametal Inc. | Multilayer structured coatings for cutting tools |
| US9650714B2 (en) | 2014-12-08 | 2017-05-16 | Kennametal Inc. | Nanocomposite refractory coatings and applications thereof |
| US9650712B2 (en) | 2014-12-08 | 2017-05-16 | Kennametal Inc. | Inter-anchored multilayer refractory coatings |
| RU2704949C2 (ru) | 2014-12-19 | 2019-10-31 | Сандвик Интеллекчуал Проперти Аб | Режущий инструмент с хогф-покрытием |
| WO2016208663A1 (ja) * | 2015-06-26 | 2016-12-29 | 三菱マテリアル株式会社 | 表面被覆切削工具 |
| JP6738556B2 (ja) * | 2015-06-26 | 2020-08-12 | 三菱マテリアル株式会社 | 表面被覆切削工具 |
| JP5871353B1 (ja) | 2015-07-13 | 2016-03-01 | 住友電工ハードメタル株式会社 | 表面被覆切削工具 |
| US9879350B2 (en) | 2015-07-13 | 2018-01-30 | Sumitomo Electric Hardmetal Corp. | Surface-coated cutting tool |
| US9878373B2 (en) | 2015-07-13 | 2018-01-30 | Sumitomo Electric Hardmetal Corp. | Surface-coated cutting tool |
| WO2017037797A1 (ja) * | 2015-08-28 | 2017-03-09 | 住友電工ハードメタル株式会社 | 表面被覆切削工具 |
| JP6044861B1 (ja) * | 2016-04-08 | 2016-12-14 | 住友電工ハードメタル株式会社 | 表面被覆切削工具およびその製造方法 |
| CN105965043B (zh) * | 2016-05-27 | 2019-05-21 | 常州市迈瑞廷涂层科技有限公司 | 一种涂覆切削工具及其制备方法 |
| JP7142098B2 (ja) * | 2018-10-03 | 2022-09-26 | 京セラ株式会社 | 被覆工具及び切削工具 |
| JP7167966B2 (ja) * | 2020-07-08 | 2022-11-09 | 株式会社タンガロイ | 被覆切削工具 |
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| SE526526C3 (sv) * | 2003-04-01 | 2005-10-26 | Sandvik Intellectual Property | Sätt att belägga skär med A1203 samt ett med A1203 belagt skärverktyg |
| JP4205546B2 (ja) * | 2003-09-16 | 2009-01-07 | 株式会社神戸製鋼所 | 耐摩耗性、耐熱性および基材との密着性に優れた積層皮膜の製造方法 |
| EP1536041B1 (de) * | 2003-11-25 | 2008-05-21 | Mitsubishi Materials Corporation | Beschichteter Cermet Schneideinsatz mit harter, gegen Abschiefern beständiger Beschichtung |
| JP4466841B2 (ja) * | 2004-06-30 | 2010-05-26 | 三菱マテリアル株式会社 | 高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
| JP4518258B2 (ja) * | 2004-08-11 | 2010-08-04 | 三菱マテリアル株式会社 | 高速断続切削加工で硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
-
2005
- 2005-01-21 JP JP2005013767A patent/JP4518260B2/ja not_active Expired - Lifetime
- 2005-12-29 KR KR1020050132793A patent/KR101186792B1/ko active Active
-
2006
- 2006-01-04 AT AT06100058T patent/ATE388252T1/de active
- 2006-01-04 DE DE602006000601T patent/DE602006000601T2/de active Active
- 2006-01-04 EP EP06100058A patent/EP1683893B1/de active Active
- 2006-01-06 US US11/327,168 patent/US7442433B2/en active Active
- 2006-01-23 CN CNB2006100066663A patent/CN100537087C/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP1683893A1 (de) | 2006-07-26 |
| CN1840267A (zh) | 2006-10-04 |
| DE602006000601T2 (de) | 2008-06-19 |
| KR20060085167A (ko) | 2006-07-26 |
| DE602006000601D1 (de) | 2008-04-17 |
| KR101186792B1 (ko) | 2012-09-27 |
| US20060188747A1 (en) | 2006-08-24 |
| JP4518260B2 (ja) | 2010-08-04 |
| US7442433B2 (en) | 2008-10-28 |
| CN100537087C (zh) | 2009-09-09 |
| EP1683893B1 (de) | 2008-03-05 |
| JP2006198735A (ja) | 2006-08-03 |
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