ATE376879T1 - Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren - Google Patents

Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren

Info

Publication number
ATE376879T1
ATE376879T1 AT04758661T AT04758661T ATE376879T1 AT E376879 T1 ATE376879 T1 AT E376879T1 AT 04758661 T AT04758661 T AT 04758661T AT 04758661 T AT04758661 T AT 04758661T AT E376879 T1 ATE376879 T1 AT E376879T1
Authority
AT
Austria
Prior art keywords
catalyst
relative
olefin
mmole
olefin epoxidation
Prior art date
Application number
AT04758661T
Other languages
German (de)
English (en)
Inventor
Ruth Kowaleski
Marek Matusz
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=33159661&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE376879(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Shell Int Research filed Critical Shell Int Research
Application granted granted Critical
Publication of ATE376879T1 publication Critical patent/ATE376879T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/08—Epoxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT04758661T 2003-04-01 2004-03-30 Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren ATE376879T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US45950203P 2003-04-01 2003-04-01

Publications (1)

Publication Number Publication Date
ATE376879T1 true ATE376879T1 (de) 2007-11-15

Family

ID=33159661

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04758661T ATE376879T1 (de) 2003-04-01 2004-03-30 Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren

Country Status (13)

Country Link
US (1) US7932407B2 (enExample)
EP (1) EP1613428B1 (enExample)
JP (1) JP2006522138A (enExample)
KR (1) KR20060002920A (enExample)
CN (1) CN100361984C (enExample)
AT (1) ATE376879T1 (enExample)
CA (1) CA2520776C (enExample)
DE (1) DE602004009776T2 (enExample)
IN (1) IN2005DN04374A (enExample)
MX (1) MXPA05010375A (enExample)
RU (1) RU2328491C2 (enExample)
TW (1) TW200507933A (enExample)
WO (1) WO2004089537A2 (enExample)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10159961B2 (en) 2006-04-18 2018-12-25 Dow Global Technologies Llc Alkylene oxide catalyst and use thereof
CA2649593C (en) * 2006-04-18 2016-08-16 Dow Global Technologies Inc. Alkylene oxide catalyst and use thereof
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
BRPI0811311A2 (pt) * 2007-05-09 2015-01-27 Shell Internationale Res Maaschappij B V Catalisador de epoxidação, um processo para a preparação do catalisador, e um processo para a produção de um óxido de olefina, um 1,2-diol, um éter 1,2-diol, um 1,2-carbonato, ou uma alcanolamina.
KR20100017689A (ko) * 2007-05-09 2010-02-16 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 촉매, 이 촉매의 제조방법, 및 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산 방법
CA2687234C (en) 2007-05-11 2016-04-19 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Start-up of high selectivity catalysts in olefin oxide plants
US7803957B2 (en) * 2007-09-11 2010-09-28 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Ethylene oxide production using fixed moderator concentration
EP2297125B1 (en) * 2008-05-07 2013-07-03 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
KR101745737B1 (ko) 2009-04-21 2017-06-09 다우 테크놀로지 인베스트먼츠 엘엘씨. 고 효율 촉매가 노화될 때 고 효율 촉매를 사용하는 간편화된 알킬렌 옥사이드 생산 방법
JP5756088B2 (ja) * 2009-04-21 2015-07-29 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー エポキシ化反応及びその運転条件
SG175771A1 (en) * 2009-04-21 2011-12-29 Dow Technology Investments Llc Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst
CA2749938C (en) * 2009-12-28 2018-10-16 Dow Technology Investments Llc Method of controlling the production of silver chloride on a silver catalyst in the production of alkylene oxides
US8742146B2 (en) * 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8921587B2 (en) 2011-04-14 2014-12-30 Basf Se Process for producing a catalyst for the oxidation of ethylene to ethylene oxide
US8987482B2 (en) 2011-10-28 2015-03-24 Basf Se Process for producing a supported silver catalyst
US9649621B2 (en) 2011-12-19 2017-05-16 Dow Technology Investments Llc Method of formulating alkylene oxide catalyst in relation to catalyst reference properties
TWI632954B (zh) 2013-05-16 2018-08-21 科學設計股份有限公司 改善環氧乙烷觸媒的催化效能之載體處理
US9714227B2 (en) 2013-12-09 2017-07-25 Basf Se Catalyst for the epoxidation of alkenes
US9221776B2 (en) * 2013-12-23 2015-12-29 Scientific Design Company, Inc. Epoxidation process
WO2018102377A1 (en) 2016-12-02 2018-06-07 Shell Oil Company Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide
WO2019020793A1 (en) 2017-07-28 2019-01-31 Basf Se PROCESS FOR PRODUCING A MOLDED CATALYST BODY COMPRISING SILVER APPLIED TO AN ALUMINUM CARRIER
US20210039074A1 (en) 2018-02-07 2021-02-11 Basf Se Method for preparing a silver impregnation solution
CN110357837B (zh) * 2018-03-26 2021-07-02 中国石油化工股份有限公司 一种乙烯环氧化方法
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3885038A1 (en) 2020-03-27 2021-09-29 Basf Se Process for producing an epoxidation catalyst
WO2021260138A1 (en) 2020-06-26 2021-12-30 Basf Se Shaped catalyst body for the production of ethylene oxide
EP4171800A1 (en) 2020-06-26 2023-05-03 Basf Se Process for producing a porous alpha-alumina catalyst support
US20230256415A1 (en) 2020-06-26 2023-08-17 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
TW202239471A (zh) 2021-01-26 2022-10-16 德商巴斯夫歐洲公司 環氧化催化劑
WO2022268348A1 (en) 2021-06-25 2022-12-29 Basf Se High purity tableted alpha-alumina catalyst support
WO2023049057A1 (en) 2021-09-23 2023-03-30 Dow Global Technologies Llc Process for reducing the aging-related deactivation of high selectivity ethylene oxide catalysts
TW202419443A (zh) 2022-10-04 2024-05-16 美商陶氏全球科技有限責任公司 減少於重啓時對高選擇性環氧乙烷催化劑過度氯化之製程
CN120051334A (zh) 2022-10-12 2025-05-27 巴斯夫欧洲公司 环氧化催化剂

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA488990A (en) 1952-12-23 J. Carlson George Process for forming ethylene oxide
US2279470A (en) 1938-04-12 1942-04-14 Carbide & Carbon Chem Corp Process of making olefin oxides
SE321462B (enExample) 1962-10-10 1970-03-09 Halcon International Inc
BR6795345D0 (pt) 1966-12-09 1973-03-29 Halcon International Inc Processo aperfeicoado para producao de oxido de etileno pela oxidacao controlada do etileno com oxigenio molecular catalisada por prata
BE752859R (fr) 1969-07-10 1971-01-04 Halcon International Inc Oxydation controlee de l'oxyde
US3962285A (en) 1972-06-05 1976-06-08 Exxon Research And Engineering Company Olefin oxidation process
IT971364B (it) 1972-11-30 1974-04-30 Sir Soc Italiana Resine Spa Procedimento per la preparazione di etilene ossido
EP0003642B1 (en) 1978-02-10 1984-07-18 Imperial Chemical Industries Plc Production of olefine oxides
US5387751A (en) 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
EP0057066B1 (en) 1981-01-23 1985-03-13 Imperial Chemical Industries Plc Process for the production of ethylene oxide
US4845296A (en) 1983-12-13 1989-07-04 Union Carbide Corporation Process for preparing alkanolamines
JPS6110570A (ja) 1984-06-25 1986-01-18 Mitsui Toatsu Chem Inc エチレンオキシドの製造方法
GB8423044D0 (en) 1984-09-12 1984-10-17 Ici Plc Production of ethylene oxide
GB8613818D0 (en) 1986-06-06 1986-07-09 Ici Plc Catalysts
CA1286687C (en) 1985-08-13 1991-07-23 Michael Paul Habenschuss Process for manufacture of alkene oxide
IL84232A (en) * 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4766105A (en) 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4833261A (en) 1986-10-31 1989-05-23 Shell Oil Company Ethylene oxide process
US4820675A (en) 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
GB8626687D0 (en) 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4950773A (en) 1988-01-28 1990-08-21 Eastman Kodak Company Selective epoxidation of olefins
US4874879A (en) 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
EP0357292A1 (en) 1988-08-30 1990-03-07 Imperial Chemical Industries Plc Production of ethylene oxide and catalysts therefor
CA1337722C (en) 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
US5187140A (en) 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5102848A (en) 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
EP0480537A1 (en) 1990-10-12 1992-04-15 Union Carbide Chemicals And Plastics Company, Inc. Stable alkylene oxide catalysts
AU656537B2 (en) 1990-10-12 1995-02-09 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts having enhanced activity and/or stability
US5145824A (en) * 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
US5100859A (en) 1991-01-22 1992-03-31 Norton Company Catalyst carrier
US5155242A (en) 1991-12-05 1992-10-13 Shell Oil Company Process for starting-up an ethylene oxide reactor
CA2078480A1 (en) 1992-04-20 1993-10-21 Bennie Albert Horrell Jr. Improved process for ethylene epoxidation
US5262551A (en) 1992-04-20 1993-11-16 Texaco Chemical Company Process for ethylene expoxidation
US5447897A (en) 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
US5418202A (en) 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
US5573339A (en) * 1994-01-14 1996-11-12 Electro-Pyrolysis, Inc. Active radiometer for self-calibrated furnace temperature measurements
US5515242A (en) * 1994-10-03 1996-05-07 Ford Motor Company Double confocal fiber optic light collector
US5545603A (en) * 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
US5504052A (en) 1994-12-02 1996-04-02 Scientific Design Company, Inc. Silver catalyst preparation
US5908942A (en) 1995-09-15 1999-06-01 Eastman Chemical Company Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions
US5739075A (en) 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
US5625084A (en) 1996-01-31 1997-04-29 Arco Chemical Technology, L.P. Vapor phase oxidation of propylene to propylene oxide
US5801259A (en) * 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process
US5864047A (en) * 1997-04-10 1999-01-26 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing rhenium and potassium promoters
US5770746A (en) 1997-06-23 1998-06-23 Arco Chemical Technology, L.P. Epoxidation process using supported silver catalysts pretreated with organic chloride
TR200100749T2 (tr) 1998-09-14 2001-10-22 Shell Internationale Research Maatschappij B.V. Epoksitleme katalizörü taşıyıcı, bunun hazırlanması ve kullanılması
DE69938503T2 (de) 1998-09-14 2009-06-10 Shell Internationale Research Maatschappij B.V. Verfahren zur herstellung von katalysatoren mit verbesserten katalytischen eigenschaften
CA2343783C (en) 1998-09-14 2008-02-12 Shell Internationale Research Maatschappij B.V. Process for removing ionizable species from catalyst surface to improve catalytic properties
US6011163A (en) 1999-05-20 2000-01-04 Eastman Chemical Company Use of fluorinated hydrocarbons as reaction media for selective epoxidation of olefins
US6372925B1 (en) 2000-06-09 2002-04-16 Shell Oil Company Process for operating the epoxidation of ethylene
JP4042332B2 (ja) 2001-02-27 2008-02-06 三菱化学株式会社 レニウム含有触媒を用いるオレフィンオキシドの製造方法
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
AU2002356973B2 (en) 2001-11-20 2008-11-06 Shell Internationale Research Maatschappij B.V. A process and systems for the epoxidation of an olefin

Also Published As

Publication number Publication date
RU2005133637A (ru) 2006-04-20
WO2004089537A2 (en) 2004-10-21
CN1809419A (zh) 2006-07-26
US7932407B2 (en) 2011-04-26
US20040198993A1 (en) 2004-10-07
DE602004009776D1 (de) 2007-12-13
RU2328491C2 (ru) 2008-07-10
IN2005DN04374A (enExample) 2010-01-15
WO2004089537A3 (en) 2004-11-25
EP1613428A2 (en) 2006-01-11
CA2520776A1 (en) 2004-10-21
CN100361984C (zh) 2008-01-16
MXPA05010375A (es) 2005-11-17
KR20060002920A (ko) 2006-01-09
JP2006522138A (ja) 2006-09-28
CA2520776C (en) 2012-05-08
TW200507933A (en) 2005-03-01
EP1613428B1 (en) 2007-10-31
DE602004009776T2 (de) 2008-08-28

Similar Documents

Publication Publication Date Title
ATE376879T1 (de) Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren
ATE357434T1 (de) Disubstituierte thiazolylcarboxanilide und ihre verwendung als mikrobizide
WO2004002954A3 (en) A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
DE60109704D1 (de) Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator
MY127285A (en) Ruthenium complexes as (pre)catalysts for metathesis reactions
MY135031A (en) A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin
DE60208384D1 (de) Katalysator und dessen verwendung zur herstellung von wasserstoffperoxid
MY152291A (en) Catalyst for oligomerization of ethylene, method for preparation thereof and process for oligomerization using it
BR0016380B1 (pt) complexo metálico, processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica.
EP2261269A3 (en) Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
EA200970636A1 (ru) Способ получения полиолефинов, полиолефины и 1-гексен, используемые в качестве сырья для получения линейного полиэтилена низкой плотности
TW200519066A (en) Preparation of ethylenamines
MY130628A (en) Phosphorus containing ligands for metathesis catalysts
ATE475654T1 (de) Verfahren zur epoxidierung von olefinen
DE502004004897D1 (de) Verfahren zur herstellung von chlor
ATE318802T1 (de) Epoxidierungssystem mit festbettreaktor
EP2070593A8 (en) Catalyst composition and process for preparing linear alpha-olefins
MY140112A (en) Hydrogenation of methylolalkanals
DE60013297D1 (de) Metallocen trägerkatalysator und olefinpolymerisation unter verwendung desselben
ATE247702T1 (de) Hydrierungskatalysatoren
WO2004039497A3 (en) Silver-based olefin oxide catalysts
AU2003287975A1 (en) Method for the production of compounds containing palladium (0)
EP4083046A3 (en) Method for preparing halosilane compounds
Yamanoi et al. Alkylzirconation of alkynes catalyzed by triphenylcarbenium tetrakis (pentafluorophenyl) borate
MXPA05011692A (es) Reaccion de un compuesto organico con un hidroperoxido.

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties