ATE291043T1 - Wässrige emulsionspolymerisation in gegenwart von ethern als kettenübertragungsmitteln zur herstellung von fluorpolymeren - Google Patents

Wässrige emulsionspolymerisation in gegenwart von ethern als kettenübertragungsmitteln zur herstellung von fluorpolymeren

Info

Publication number
ATE291043T1
ATE291043T1 AT02731593T AT02731593T ATE291043T1 AT E291043 T1 ATE291043 T1 AT E291043T1 AT 02731593 T AT02731593 T AT 02731593T AT 02731593 T AT02731593 T AT 02731593T AT E291043 T1 ATE291043 T1 AT E291043T1
Authority
AT
Austria
Prior art keywords
emulsion polymerization
aqueous emulsion
fluropolymers
ethers
production
Prior art date
Application number
AT02731593T
Other languages
German (de)
English (en)
Inventor
Harald Kaspar
Klaus Hintzer
Karl-Dieter Weilandt
Jost Krichel
Erik Peters
Lisa P Chen
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23106351&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE291043(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Application granted granted Critical
Publication of ATE291043T1 publication Critical patent/ATE291043T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14—Monomers containing only one unsaturated aliphatic radical
    • C08F16/24—Monomers containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C08F214/222—Vinylidene fluoride with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C08F214/225—Vinylidene fluoride with non-fluorinated comonomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C08F214/265—Tetrafluoroethene with non-fluorinated comonomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C08F216/1408—Monomers containing halogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
AT02731593T 2001-05-02 2002-04-30 Wässrige emulsionspolymerisation in gegenwart von ethern als kettenübertragungsmitteln zur herstellung von fluorpolymeren ATE291043T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28824801P 2001-05-02 2001-05-02
PCT/US2002/013689 WO2002088203A2 (en) 2001-05-02 2002-04-30 Aqueous emulsion polymerization in the presence of ethers as chain transfer agents to produce fluoropolymers

Publications (1)

Publication Number Publication Date
ATE291043T1 true ATE291043T1 (de) 2005-04-15

Family

ID=23106351

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02731593T ATE291043T1 (de) 2001-05-02 2002-04-30 Wässrige emulsionspolymerisation in gegenwart von ethern als kettenübertragungsmitteln zur herstellung von fluorpolymeren

Country Status (9)

Country Link
US (2) US6750304B2 (OSRAM)
EP (1) EP1432744B2 (OSRAM)
JP (1) JP4624646B2 (OSRAM)
CN (1) CN1289547C (OSRAM)
AT (1) ATE291043T1 (OSRAM)
AU (1) AU2002303564A1 (OSRAM)
CA (1) CA2446014A1 (OSRAM)
DE (1) DE60203307T3 (OSRAM)
WO (1) WO2002088203A2 (OSRAM)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1289547C (zh) * 2001-05-02 2006-12-13 3M创新有限公司 在醚类链转移剂存在下制备含氟聚合物的水乳液聚合方法
US6756620B2 (en) * 2001-06-29 2004-06-29 Intel Corporation Low-voltage and interface damage-free polymer memory device
US6624457B2 (en) 2001-07-20 2003-09-23 Intel Corporation Stepped structure for a multi-rank, stacked polymer memory device and method of making same
US7279522B2 (en) 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
RU2380384C2 (ru) * 2003-01-29 2010-01-27 Грин, Твид Оф Делавэр, Инк. Вулканизирующие агенты на основе бисаминофенила и вулканизирующие агенты и ускорители вулканизации на основе амидина для перфторэластомерных композиций
WO2004069900A2 (en) 2003-01-29 2004-08-19 Greene, Tweed Of Delaware, Inc. Bisaminophenyl-based curatives and amidine-based curatives and cure accelerators for perfluoroelastomeric compositions
JP2005036189A (ja) * 2003-07-14 2005-02-10 Rohm & Haas Co 水性ポリマー分散体の調製のための水性重合方法
WO2005010896A1 (en) * 2003-07-24 2005-02-03 Union Carbide Chemicals & Plastic Technology Corporation Cable insulation system with flexibility, high temperature deformation resistance, and reduced degree of stickiness
US20050096425A1 (en) * 2003-09-25 2005-05-05 Michael Coates High stability polytetrafluoroethylene dispersions and method for obtaining same
US20050124773A1 (en) * 2003-12-09 2005-06-09 Tang Phan L. Extrudable fluoroelastomer composition
EP1570917B1 (en) * 2004-03-01 2009-06-10 3M Innovative Properties Company Method of coating a substrate with a fluoropolymer dispersion
US7514506B2 (en) 2004-03-31 2009-04-07 Greene, Tweed Of Delaware, Inc. Fast curing fluoroelastomeric compositions, adhesive fluoroelastomeric compositions and methods for bonding fluoroelastomeric compositions
FR2871898B1 (fr) * 2004-06-18 2006-09-08 Alcatel Sa Composant a fibre optique et fibre optique associee
EP1630179B1 (en) * 2004-08-25 2007-10-31 Asahi Glass Company Ltd. Fluorocopolymer
GB2427170A (en) * 2005-06-17 2006-12-20 3M Innovative Properties Co Fluoropolymer film having glass microspheres
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
US20080015304A1 (en) * 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
GB0525978D0 (en) * 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
US7795332B2 (en) * 2005-07-15 2010-09-14 3M Innovative Properties Company Method of removing fluorinated carboxylic acid from aqueous liquid
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB2430437A (en) * 2005-09-27 2007-03-28 3M Innovative Properties Co Method of making a fluoropolymer
US7728087B2 (en) 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US7754795B2 (en) * 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US20070276103A1 (en) * 2006-05-25 2007-11-29 3M Innovative Properties Company Fluorinated Surfactants
US8119750B2 (en) * 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
US7678859B2 (en) * 2006-09-14 2010-03-16 3M Innovative Properties Company Preparation and stabilization of fluoropolymer dispersions
JP5332617B2 (ja) * 2006-12-08 2013-11-06 ダイキン工業株式会社 フルオロモノマーの回収方法
US20100022702A1 (en) * 2006-12-12 2010-01-28 Chen Lisa P Thermally stable fluoropolymers
CN100406480C (zh) * 2006-12-28 2008-07-30 中昊晨光化工研究院 高氟含量的氟弹性体及其制备方法
US7700700B2 (en) * 2007-01-26 2010-04-20 Arkema Inc. Vinylidene fluoride copolymer composition with improved low-temperature impact properties
US20100084343A1 (en) * 2007-02-16 2010-04-08 Mader Brian T System and process for the removal of fluorochemicals from water
US20080264864A1 (en) 2007-04-27 2008-10-30 3M Innovative Properties Company PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT
CN101679790B (zh) * 2007-05-23 2012-09-19 3M创新有限公司 氟化表面活性剂的水性组合物及其使用方法
US8476385B2 (en) * 2007-06-06 2013-07-02 3M Innovative Properties Company Fluorinated ether compositions and methods of using the same
JP5532532B2 (ja) * 2007-06-25 2014-06-25 ダイキン工業株式会社 低分子量ポリテトラフルオロエチレン水性分散液及びその製造方法
US8288492B2 (en) * 2007-10-23 2012-10-16 E I Du Pont De Nemours And Company Difunctional oligomers of perfluoro(methyl vinyl ether)
US10259899B2 (en) * 2008-07-07 2019-04-16 Arkema Inc. Vinylidene fluoride / 2,3,3,3-tetrafluoropropene copolymers
BRPI0915955A2 (pt) * 2008-07-18 2019-02-26 3M Innovative Proferties Company compostos fluorados de éter e métodos para uso dos mesmos
CN102282191A (zh) * 2008-11-25 2011-12-14 3M创新有限公司 氟化醚尿烷及其使用方法
WO2010080473A1 (en) 2008-12-18 2010-07-15 3M Innovative Properties Company Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
US20110152487A1 (en) * 2009-12-17 2011-06-23 3M Innovative Properties Company Peroxide cured partially fluorinated elastomers
JP5969257B2 (ja) * 2012-04-27 2016-08-17 スリーエム イノベイティブ プロパティズ カンパニー フルオロポリマー組成物およびその硬化物
WO2014088804A1 (en) 2012-12-04 2014-06-12 3M Innovative Properties Company Partially fluorinated polymers
JP6356693B2 (ja) 2012-12-04 2018-07-11 スリーエム イノベイティブ プロパティズ カンパニー 高フッ素化ポリマー
WO2014203727A1 (ja) * 2013-06-21 2014-12-24 ダイキン工業株式会社 加工助剤、及び組成物
CN103694398B (zh) * 2013-12-26 2016-03-02 中昊晨光化工研究院有限公司 一种高焊接性能的改性ptfe悬浮树脂及其制备方法
CN103724511B (zh) * 2013-12-30 2016-06-15 山东华夏神舟新材料有限公司 一种油封用氟橡胶的制备方法
JP6876276B2 (ja) * 2016-04-28 2021-05-26 Ａｇｃ株式会社 被覆電線
CN114761442A (zh) * 2019-12-12 2022-07-15 索尔维特殊聚合物意大利有限公司 用于制造氟聚合物的方法
WO2023099974A1 (en) * 2021-12-01 2023-06-08 3M Innovative Properties Company Semi-fluorinated thermoplastic copolymers and passive cooling articles including the same
WO2025143165A1 (ja) * 2023-12-28 2025-07-03 Ａｇｃ株式会社 パーフルオロエラストマー、架橋ゴム物品

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3306879A (en) 1962-06-25 1967-02-28 Du Pont Curable copolymers of tetrafluoroethylene
GB1145445A (en) * 1966-02-16 1969-03-12 Du Pont Fluorinated perfluorovinylethers, their preparation and copolymers thereof
US3642742A (en) 1969-04-22 1972-02-15 Du Pont Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers
US3635926A (en) 1969-10-27 1972-01-18 Du Pont Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers
US3876654A (en) 1970-12-23 1975-04-08 Du Pont Fluoroelastomer composition
US3855191A (en) 1973-04-04 1974-12-17 Du Pont Polytetrafluoroethylene molding powders of tetrafluoroethylene and perfluoro (alkyl vinyl ether) copolymer
US4123602A (en) 1976-05-24 1978-10-31 Asahi Glass Company, Ltd. Terpolymers of tetrafluoroethylene, ethylene and perfluoroalkyl vinyl monomer and process for producing the same
DE2639109A1 (de) * 1976-08-31 1978-03-09 Hoechst Ag Copolymerisate des tetrafluoraethylens und verfahren zu deren herstellung
US4233421A (en) 1979-02-26 1980-11-11 Minnesota Mining And Manufacturing Company Fluoroelastomer composition containing sulfonium curing agents
US4381387A (en) * 1980-06-28 1983-04-26 Hoechst Aktiengesellschaft Quaterpolymers of the tetrafluoroethylene/ethylene type
DE3135598A1 (de) 1981-09-09 1983-03-17 Hoechst Ag, 6000 Frankfurt "kontinuierliches verfahren zur agglomerierung von ptee-pulvern im fluessigen medium und damit gewonnenes modifiziertes ptee-pulver"
JPS58189210A (ja) * 1982-04-30 1983-11-04 Daikin Ind Ltd テトラフルオロエチレン／フルオロ（アルキルビニルエ−テル）共重合体の製法
US4564662A (en) 1984-02-23 1986-01-14 Minnesota Mining And Manufacturing Company Fluorocarbon elastomer
US5086123A (en) 1984-02-27 1992-02-04 Minnesota Mining And Manufacturing Company Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents
US4588796A (en) 1984-04-23 1986-05-13 E. I. Du Pont De Nemours And Company Fluoroolefin polymerization process using fluoroxy compound solution as initiator
CA1244196A (en) * 1984-12-26 1988-11-01 Yoshinori Masuda High molecular weight fluoroelastomer
JPS6289713A (ja) * 1985-10-12 1987-04-24 Daikin Ind Ltd 新規フルオロエラストマー
JPH01129005A (ja) 1987-11-12 1989-05-22 Daikin Ind Ltd フツ化ビニリデンの水性懸濁重合方法
US4861845A (en) 1988-03-10 1989-08-29 E. I. Du Pont De Nemours And Company Polymerization of fluoroolefins
US4912171A (en) 1988-04-01 1990-03-27 Minnesota Mining And Manufacturing Company Fluoroelastomer curing process with phosphonium compound
US4985520A (en) * 1988-07-29 1991-01-15 Asahi Kasei Kogyo Kabushiki Kaisha Fluoroelastomer having excellent processability
US5106911A (en) 1989-10-06 1992-04-21 E. I. Du Pont De Nemours And Company Process and processing aid for extruding a hydrocarbon polymer
US5208305A (en) 1992-04-17 1993-05-04 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
US5453477A (en) 1992-05-01 1995-09-26 Alliedsignal Inc. Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite
US5262490A (en) 1992-08-24 1993-11-16 Minnesota Mining And Manufacturing Company Fluoroelastomer composition with organo-onium compounds
WO1995014719A1 (en) 1992-08-28 1995-06-01 E.I. Du Pont De Nemours And Company Low-melting tetrafluoroethylene copolymer and its uses
US5608022A (en) * 1993-10-12 1997-03-04 Asahi Kasei Kogyo Kabushiki Kaisha Perfluorocarbon copolymer containing functional groups and a method for producing it
DE4335705A1 (de) * 1993-10-20 1995-04-27 Hoechst Ag Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung
IT1265223B1 (it) * 1993-11-25 1996-10-31 Ausimont Spa Processo per la preparazione di polimeri del vinilidenfluoruro
IT1265461B1 (it) 1993-12-29 1996-11-22 Ausimont Spa Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina
IT1269291B (it) † 1994-03-04 1997-03-26 Ausimont Spa Miscele di poli (vinilidene fluoruro) e loro impiego per la formulazione di vernici ad elevata brillantezza
JPH07330833A (ja) * 1994-06-07 1995-12-19 Central Glass Co Ltd 塗料用含フッ素共重合体
CA2168794A1 (en) * 1994-06-09 1995-12-14 Takayuki Araki Fluoroolefin, fluoropolymer, and thermoplastic resin composition containing the polymer
JPH0873534A (ja) * 1994-09-12 1996-03-19 Central Glass Co Ltd 塗料用樹脂および組成物
US5478905A (en) 1995-02-06 1995-12-26 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene/hexafluoropropylene copolymers
JP3223776B2 (ja) 1995-03-31 2001-10-29 日本メクトロン株式会社 含フッ素エラストマー組成物
JP3082626B2 (ja) 1995-07-19 2000-08-28 日本メクトロン株式会社 含フッ素エラストマー組成物
US5710217A (en) 1995-09-15 1998-01-20 Minnesota Mining And Manufacturing Company Extrudable thermoplastic hydrocarbon compositions
IT1276979B1 (it) 1995-10-20 1997-11-03 Ausimont Spa Composizioni fluoroelastomeriche
US5955556A (en) 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5591804A (en) 1995-12-21 1997-01-07 Minnesota Mining And Manufacturing Company Fluorinated onium salts, curable compositions containing same, and method of curing using same
JP3671517B2 (ja) * 1996-04-24 2005-07-13 ユニマテック株式会社 含フッ素共重合体エラストマー、その製造法および組成物
US5677389A (en) 1996-11-25 1997-10-14 E. I. Du Pont De Nemours Perfluoroelastomer composition having enhanced curing performance
US5728773A (en) 1997-02-21 1998-03-17 Minnesota Mining And Manufacturing Company Fluoroelastomer composition with organo-onium and blocked-carbonate compounds
JP3638076B2 (ja) * 1997-10-16 2005-04-13 セントラル硝子株式会社 水性塗料用水性フッ素樹脂組成物
US6103844A (en) 1998-06-08 2000-08-15 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers in carbon dioxide
US6281296B1 (en) 1998-08-10 2001-08-28 Dupont Dow Elastomers L.L.C. Curable perfluoroelastomer composition
JP2003524675A (ja) 1998-11-30 2003-08-19 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フルオロモノマー重合
US6242548B1 (en) 1999-05-13 2001-06-05 Dyneon Llc Fluoroplastic polymers with improved characteristics
US6720360B1 (en) * 2000-02-01 2004-04-13 3M Innovative Properties Company Ultra-clean fluoropolymers
JP2003534416A (ja) * 2000-05-19 2003-11-18 ユニヴァーシティ・オヴ・ノース・キャロライナ・アト・チャペル・ヒル マルチモーダルフルオロポリマーおよびその製造方法
US6310141B1 (en) 2000-06-27 2001-10-30 Dyneon Llc Fluoropolymer-containing compositions
CN1289547C (zh) * 2001-05-02 2006-12-13 3M创新有限公司 在醚类链转移剂存在下制备含氟聚合物的水乳液聚合方法
CA2446016A1 (en) * 2001-05-02 2002-11-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
AU2003291646A1 (en) * 2002-10-31 2004-06-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization to produce copolymers of a fluorinated olefin and hydrocarbon olefin

Also Published As

Publication number Publication date
CA2446014A1 (en) 2002-11-07
EP1432744A2 (en) 2004-06-30
CN1529720A (zh) 2004-09-15
US20030018148A1 (en) 2003-01-23
JP4624646B2 (ja) 2011-02-02
DE60203307T3 (de) 2015-01-29
US6750304B2 (en) 2004-06-15
DE60203307D1 (de) 2005-04-21
AU2002303564A1 (en) 2002-11-11
WO2002088203A2 (en) 2002-11-07
EP1432744B1 (en) 2005-03-16
US6861490B2 (en) 2005-03-01
DE60203307T2 (de) 2006-04-13
WO2002088203A3 (en) 2004-04-29
EP1432744B2 (en) 2014-10-01
JP2004534118A (ja) 2004-11-11
US20040235986A1 (en) 2004-11-25
CN1289547C (zh) 2006-12-13

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